Development of Cotton Fabrics via EVA/SiO2/Al2O3 Nanocomposite Prepared by γ-Irradiation for Waterproof and Fire Retardant Applications

Development of cotton fabric (CF) properties using nanocomposites via coating method was of considerable interest for wide applications. This article aims at developing CF properties by coating treatment using ethylene–vinyl-acetate (EVA), silicon dioxide (SiO2), aluminum oxide (Al2O3) nanoparticles and γ-irradiation widely used in waterproof and flame retardant applications. EVA-based nanocomposites, EVA/SiO2, EVA/Al2O3, and EVA/SiO2/Al2O3, were synthesized by γ-irradiation and the highest gel content of 81.2–95.3% was achieved at 30 kGy. The physicochemical properties of EVA-based nanocomposites were characterized by FT-IR, XRD, DSC and SEM techniques. Usage of irradiated EVA and EVA-based nanocomposites for treatment of CF by coating technique was successfully achieved. This technique provides a simple and versatile method leading to excellent uniform and smooth surface morphology without aggregation. The weight gain, mechanical properties, thermal properties, water vapor permeability and flame-retardant properties of the modified CF were evaluated. Moreover, compared with control CF, the resistivity of water absorptivity and hydrophobic property and the thermal stability were gained. The flame retardant properties of CF samples were performed using limited oxygen index (LOI) and vertical burning flame tests. LOI percentages of CF/EVA/SiO2, CF/EVA/Al2O3 and CF/EVA/SiO2/Al2O3 increased to 25.3, 27.5, and 29.3%, respectively. Untreated CF ignited and burned rapidly after 5 s. Meanwhile, the treated CF hold flame resistance properties and the burning time prolonged to 25 s. The results of the treated CF providing revealed hydrophobic and protective capability of the fabrics from being destroyed by burning, and support their further use in waterproof and flame retardant applications of fabrics.


Introduction
Ethylene vinyl acetate (EVA) is a versatile commercial polymer material composed of nonpolar crystalline polyethylene and polar polyvinyl acetate segments that can vary greatly in their chemical and physical properties by the variation of the vinyl acetate content usually varies from 10 to 40%.
The variation of the vinyl acetate content in EVA could alter many properties of EVA, such as degree of crystallization, glass transition temperature, thermal stability, and mechanical strength [1]. EVA is an elastomeric polymer that produces rubber-like materials. The material has gloss and good clarity, hot-melt adhesive waterproof properties, resistance to UV radiation, stress-crack resistance, and low-temperature toughness. Hence, EVA copolymers have a broad range of applications early in hot melt adhesives [2] coatings [3] wire and cable applications [4], footwear industry [5], controlled release drug systems [6], packaging applications [7], wearable electronic devices for human health monitoring [8]. Despite the promising aspects of EVA for coating applications, it has some disadvantages such as low tensile strength and highly flammable and produces large amounts of toxic smoke during combustion. In order to solve these 1 3 problems, one of the investigated methods commits to incorporate flame retardants into the EVA composite materials to improve its properties.
Recently, metal oxide nanoparticles embedded within the polymer matrix, metal oxide-based polymeric nanocomposites, have attracted the growing interest in nanostructured materials due to the unique properties and combine the properties of the polymer as well as the metal oxide. Different types of metal oxide-based polymeric nanocomposites could be synthesized by different polymerization methods including suspension polymerization [9], emulsion polymerization [10], and γ-irradiation polymerization [11][12][13][14][15]. The properties of the produced nanocomposites depend on numerous aspects such as the morphological structure, the procedure of preparation, the nature of metal oxide nanoparticles that incorporated in, the structural features of the polymer used, and the chemical properties of both metal oxide and polymer molecules. The physicochemical properties of the nanosized particles within the hybrid material differ markedly from those of molecular and bulk materials.
Silicon dioxide is one of the reinforced filling materials that are widely utilized as an improving agent in thermoplastic polymers that improves the mechanical properties [16] and has synergistic flame retardant property [17,18]. SiO 2 is known as a potential and safe flame retardant additive for polymer systems due to its high heat resistance, inert and non-toxic features [19]. SiO 2 consists of silanol groups (Si-OH) which play a basic role in forming interaction with polar groups of polymers [20]. It is usually used as an enhancing agent in thermoplastic polymers to enhance the mechanical properties [16].
Alumina or aluminum oxide (Al 2 O 3 ) nanoparticles are nano-sized particles from an alumina bulk. Al 2 O 3 nanoparticles can be acquired by numerous methods including, sol-gel, pyrolysis, laser ablation, and sputtering [21]. Al 2 O 3 has many inherent characteristics such as high melting temperature, low thermal expansion coefficient, toughness, hardness, non-toxicity, chemical inertness, transparency, and excellent insulating properties which make it advantageous as a nano-filler for polymer nanocomposites. Lately, several industrial applications of Al 2 O 3 nanoparticles have been disseminated for example; drilling fluids agents [22], separators for lithium batteries [23], biosensors for vitamin E [24], enhancement of the thermal and mechanical properties of wood fibers [25]. Al 2 O 3 has been extensively considered to serve as flame retardants, absorbents, catalysts, composite materials, and surface protective coatings [26]. Additionally, Al 2 O 3 shows a good wear resistance and has a large surface area, so it is generally used as a filter for polymers to improve mechanical properties, catalyst, and catalyst support [27].
In this regard, γ-irradiation remains one of the most common processes that are capable of modifying the polymer-metal nanocomposites' physical properties, which amplifies their utility in several applications [28,29]. Notably, these alterations are attributed to the crosslinking or chemical bond scissions caused by high energetic radiation. This is because the ionization and excitation of the material's molecules occurring during the interaction of ionization radiation with a polymeric material [30]. The radiation processing technique has numerous advantageous features including easy process control, simultaneous crosslinking of polymers and sterilization at the same time, and the technology is environmentally-friendly and no residue or pollutant in the surrounding environment, no additional chemical initiators or crosslinkers [31,32].
Nowadays, functional materials, mainly flame-retardant textiles, have attracted much consideration besides an increase in the public awareness of safety. Worldwide, a large number of people die and lose fortunes in fire accidents due to the easy ignition of textiles every year [33]. Therefore, it is urgent to impart textiles with less flammability or non-flammability. In the last decades, numerous researchers have focused on the investigation of flame-retardant textiles and various preparation methods have been reported [34]. Cellulosic textiles, such as cotton fabric (CF), have been commonly utilized to produce industrial products, home furnishings, and apparel as a result of their advantages of pollution-free, vast quantities, strong biodegradability, and excellent mechanical properties [35].
There are countless combinations of coatings and fabrications methods for cotton fabrics to achieve different specifications for a wide spectrum of applications such as fabrication of reduced graphene oxide/silver nanoparticles onto cotton fabric for high electrical conductivity and superior electromagnetic shielding efficiency [36], the fabrication of highly durable electronic fabric for flexible electromagnetic performance via a facile dipping and drying method. which can address long term exposure towards the extreme environmental conditions both wet and dry media [37], fabrication of alkyl ammonium functional silsesquioxane /phytic acid complex as flame-retardant layer and hierarchicalstructured titanium oxide@polydimethylsiloxane composite as superhydrophobic layer were deposited and coated onto cotton fabrics was achieved for water-oil separation application [38], fabrication of superhydrophobic flame retardant coating using depositing method of diammonium phosphate solution, and H-ZrO 2 for good wear resistance, acid and alkali resistance and UV resistance excellent and flameretardant performance [39], fabrication of cotton fabric with fluoroalkylated oligomeric silica/triazine derivative nanocomposites for use in the separation membranes for the separation of oil/water [40], fabrication of superhydrophobic fabric by modifying the pristine fabric with silica nanoparticles prepared from tetraethoxysilane followed by amino-modified polydimethylsiloxane (PDMS) and through a dip-coating process for superhydrophobic and breathable textile applications [41], fabrication of a super-hydrophobic coating on cotton fabric via sol-gel process using super-hydrophobic glycidoxypropyltrimethoxysilane and 1,1,1,3,3,3-hexamethyl disilazane modified TiO 2 /SiO 2 coated cotton fabrics for oil-water separation [42], fabrication of textile with silver chloride nanoparticles under ultrasound irradiation was achieved for antibacterial activity [43].
CF is widely used to produce various industrial products due to its softness, low cost, breathability, and ability to absorb moisture and is a useful starting material for new product development. However, the major drawbacks of cotton are being highly flammable, affected by microbes, and insects, needing chemical modification for wide applications. It is generally more flammable than most of the synthetic fibers. Flame retardants represent one of the most important industrial uses of textile materials and are widely used to make cotton textiles flame resistant for application fields of human safety. One drawback of CF is their flammability with low limited oxygen (LOI = 18.4% only) and their application in firefighters' protective clothing, military, and airline industry has been restricted [44]. Therefore, the improvement of the thermal stability of the CF (or cottonbased material) becomes one of the important issues.
There are many ways to improve the fire-retardant properties of cotton-based materials such as using flame retardants in polymers or using flame retardant coatings and surface modification. Various flame retardants additives have been applied to modify the combustion characteristics of cottonbased fabrics mainly include inorganic flame retardants such as aluminum hydroxide [45] and magnesium hydroxide [46], nitrogen and phosphorus flame retardants [47,48].
Recently, the coating onto fabrics using nanocomposite material of flame-retardant properties by the layer-bylayer assembly has attracted attention as a simple and costeffective process. Cotton and textile materials are properly treated by coating treatments to become waterproof surface and fire-resistant which are useful and necessary for humans in sailing, military endeavors, agricultural greenhouses, and ventures outdoors. The coating processing includes solution immersion, institutional draperies, spray coating, layer-bylayer deposition, sol-gel method, in-situ polymerization, and pad-dry-cure-method [49].
In this work, EVA/SiO 2 , EVA/Al 2 O 3 , and EVA/SiO 2 / Al 2 O 3 nanocomposites were synthesized via γ-irradiation and used as coating materials to prepare waterproof and flame-retardant CF. The main hypothesis of this study is the conversion of CF from hydrophilic and flammable fabrics to a promising waterproof and flame-retardant ones by utilizing the irradiated EVA and nano SiO 2 /Al 2 O 3 nanoparticles as coating materials. The physicochemical properties of EVA-based nanocomposites were investigated by estimating the gel content (%) and characterized by Fourier transform infrared (FT-IR), X-ray diffraction (XRD), differential scanning calorimetry (DSC), and Scanning Electron Microscopy (SEM). The effects of as-prepared EVA-based nanocomposites on CF for use in water resistance and fire retardant applications have been studied. The waterproof, flame-retardant properties and thermal stability of treated CF were investigated by mechanical test, thermal gravimetric analysis (TGA), water vapor transmission test, contact angle measurements, and Limiting oxygen index (LOI) and vertical burning flame tests.

Materials
Ethylene vinyl acetate copolymer (EVA) containing 10 wt% vinyl acetate, density of 0.935 g/cm 3 , and melt flow index of 1.3 g/10 min (at 190 °C/2.16 kg) was purchased from Hanhwa Co., South Korea. The silicon dioxide nano-powder (SiO 2 ) with the average particle size of 10-20 nm was purchased from Sigma-Aldrich Co. (

Preparation of Al 2 O 3 Nanoparticles
The Al 2 O 3 nanoparticles were prepared by co-precipitation method using aluminum sulfate hexadecahydrate (Al 2 (SO 4 ) 3 .16H 2 O) and sodium hydroxide according to the previously described method [50]. Firstly, 0.1 M of Al 2 (SO 4 ) 3 .16H 2 O was prepared in distilled water using a magnetic stirrer at room temperature. Then, 0.2 M of NaOH was added. A white creamy solution was produced from aluminum hydroxide, separated utilizing a centrifuge. Then, the precipitate was washed several times with distilled water, dried at 80 °C overnight. After that, the dried precipitate was completely converted to Al 2 O 3 nanoparticles by were subsequently annealed at 600 °C for 4 h, then cooled to room temperature and used.

Preparation of EVA/SiO 2 , EVA/Al 2 O 3, and EVA/ SiO 2 /Al 2 O 3 Nanocomposites
EVA/SiO 2 , EVA/Al 2 O 3 , and EVA/SiO 2 /Al 2 O 3 nanocomposites were prepared as follows: Firstly, EVA (10 wt%) was dissolved in chloroform at 70 °C for 30 min with continuous stirring until complete dissolution. Secondly, to prepare EVA/SiO 2 , 10% SiO 2 nanoparticles was dispersed in EVA copolymer solution. To prepare EVA/Al 2 O 3 was prepared by mixing 10% Al 2 O 3 nanoparticles to EVA copolymer solution. EVA/SiO 2 /Al 2 O 3 nanocomposite was prepared by mixing 5% SiO 2 and 5% Al 2 O 3 nanoparticles with EVA copolymer solution. The ratio of SiO 2 or Al 2 O 3 nanoparticles was relatively to the concentration of EVA copolymer solution. The EVA mixture solutions with stirred for 3 h at 50 °C until homogeneity, then stirred for another 2 h under sonication to obtain reactant mixture. Thirdly, the reactant mixtures of EVA/10% SiO 2 , EVA/10% Al 2 O 3 and EVA/5% SiO 2 /5% Al 2 O 3 as well as pure EVA copolymer were sealed and then exposed to γ-irradiation at different doses of 10, 20, 30, 40, and 50 kGy (dose rate 1.05 kGy/h) using the 60 Co Canadian γ-irradiation facility established at the National Center for Radiation Research and Technology, Egyptian Atomic Energy Authority, Cairo, Egypt. Finally, the obtained irradiated mixture solutions (EVA, EVA/SiO 2 , EVA/Al 2 O 3 , and EVA/SiO 2 / Al 2 O 3 ) were casted into Petri-dishes and allowed to dry in air at room temperature for further characterization.

The Gel Content (%)
The gel content of dried samples of EVA, EVA/SiO 2 , EVA/ Al 2 O 3 , and EVA/SiO 2 /Al 2 O 3 nanocomposites prepared at different irradiation doses of 10-50 kGy were soaked in boiling toluene for 8 h to remove the (uncross-linked) soluble part. Then, the samples were removed, dried to a constant weight, and the insoluble residue was weighed. The gel content (%) was determined according to the following Eq. (1): where M 1 is the sample initial mass and M 2 is the residual mass of dried samples after extraction from toluene.

Treatment of CF
Before processing, CF (15 cm × 15 cm) were washed with tap water to remove some adsorbed impurities then dried at 70 °C for 2 h and the dry weight of CF was measured (W 0 ). After that, the CF were immersed for 30 min in the coating solutions of EVA, EVA/SiO 2 , EVA/Al 2 O 3 , and EVA/ SiO 2 /Al 2 O 3 that prepared by irradiation at 30 kGy. Then the treated CF allowed to dry at 50 °C, furthermore, washed several times with ethanol/distilled water, and dried again at 50 °C. Finally, after deposition and complete evaporation of chloroform (as a solvent), the treated CF weighed (W g ). The weight gain (%) was calculated according to the following Eq. (2):

Water Absorption (%)
Water absorption was measured on coated CF samples of 5 cm × 5 cm which were dried to constant weight before immersion in distilled water at room temperature for 30 min, then weighted gain with time after absorption. The average water absorption value for three samples was calculated according to the following Eq. (3): W d and W w are the weights of samples dry and wet, respectively.

Water Vapor Transmission Rate (WVTR)
The WVTR was measured gravimetrically at 40 °C according to the European Pharmacopoeia standard (EP) [51,52]. WVTR was identified as the amount of water vapor in one gram able to permit through a material, generally within 24 h. Briefly, for this measurement samples of untreated and treated CF were cut into circular pieces with a diameter of 5 cm and put on the mouth of a glass bottle containing 50 mL of distilled water and then the mouth of bottles was secured with Teflon tape. The initial weight was recorded as W 1 . Then, the bottles were placed in an oven at 40 °C for 24 h. Then the bottles were taken out and weighted (W 2 ). The open bottle served as the negative control. The weight loss (%) of the system reveals an index of WVTR and the WVTR was calculated according to the following Eq. (4): A (m 2 ) is the area of films covered the area of bottle mouth.

Characterization Analysis
XRD patterns were obtained with Shimadzu Scientific Instruments (SSI) XRD-6000 series-Kyoto, Japan using Ni-filter and Cu-Kα radiation target (λ = 1.54056 A o ). The pattern was recorded at a scanning rate of 4 steps/min within the range of (2θ) 4° -90°.
The size of and morphology of SiO 2 and Al 2 O 3 nanoparticles were studied utilizing a Transmission Electron Microscopy (TEM), JEOL JSM-100 CX, Japan, with an acceleration voltage of 80 kV. For TEM investigation, the particle size of SiO 2 and Al 2 O 3 samples were set up by making a suspension from the nanoparticles in acetone using an ultrasonic water bath. The suspension was centrifuged to isolate the large size particles. After that, a drop of each suspension (10 µL) was dropped into the carbon-coated copper grid and left to dry at room temperature for further investigatin.
The surface morphology of EVA-based nanocomposites was investigated utilizing Scanning Electron Microscopy (SEM), JEOL JSM-5400, Japan. The surface of the composites was sputter-coated with gold for 3 min.
The tensile strength and elongation at break (%) were measured using dumbbell-shaped pieces of 50 mm long and 4 mm neck width at a crosshead speed of 500 mm/min at room temperature with a tension speed of 25 mm/min, using a tensile testing machine Qchida computerized testing machine, Dongguan Haida Equipment Co. Ltd. China. The ISO 527-2 standards and ASTM D 412a-98 were followed to measure tensile strength and an elongation at break, respectively. The average value of the mechanical parameters was calculated as a mean of three samples.
The thermal analysis of the samples were investigated utilizing the DSC Shimadzu type DSC-50 system in a nitrogen atmosphere at 20 mL/min within the temperature range from ambient to 350 o C at a heating rate of 10 o C/min.Thermogravimetric analysis (TGA) was performed with a Shimadzu TGA-50 framework (Kyoto, Japan) in the temperature range 25−600 °C at a heating rate of 10 o C/min under controlled nitrogen flow of 20 mL/min.
The contact angle between water and treated CF was determined using Biolin Scientific theta lite optical tensiometer by sessile drop test.
The Limiting Oxygen Index (LOI) percentages of the untreated and treated CF were measured using LOI instrument (Rheometric Scientific, UK) according to ASTM D 2863. The analysis was made at the National Institute of Standards, Giza, Egypt. The LOI is the least oxygen (O 2 ) concentration in the oxygen/nitrogen mixture [O 2 /N 2 ] that either a dimension of 5 cm × 13 cm sample is consumed or flame combustion of the material for 3 min is preserved, with the sample vertically placed (the top of the test sample is inflamed with a burner). The vertical flame tests were conducted on vertical flammability kindle model with strips (1.5 cm × 7.0 cm) of CF and CF treated with EVA and EVA based nanocomposites were subjected directly to the flame at the left bottom according to American Society for Standards and Testing (ASTM D-6413-08) Standard Test Method for Flame Resistance of Textiles (Vertical Flame Test, 2008). Figure 1A (curve a) shows the XRD of SiO 2 with a broad peak at 2θ = 22.7° of amorphous silica [53]. The XRD of the prepared Al 2 O 3 nanoparticles Fig. 1A ( 440) and (444), respectively. These peaks are in a good agreement with the data of JCPDS cards values corresponding exactly to cubic structure (JCPDS No. 10-0425, 29-0063, and 29-1486) [55]. The average crystallite dimension of Al 2 O 3 nanoparticles from the XRD data of peaks details was determined by applying Debeys-Scherrer Eq. (5) where D is particle diameter size, k is the so-called shape or geometry factor which equals 0.9, λ is the x-ray wavelength (λ = 0.1541 nm), β is the full width at half maximum (FWHM) of diffraction peak and θ is the diffraction angle. The calculated average crystallite dimension (D) was 31 nm. Figure 1B (curve a) shows the FT-IR spectrum of the SiO 2 . The absorption peak at 3424 cm −1 is assigned to the stretching vibration of the hydroxyl group (OH) of the adsorbed water. The peak at 1091 cm −1 is assigned to the Si-O-Si asymmetric stretching vibration. The peak at 814 cm −1 is ascribed to the asymmetric bending and stretching vibration of Si-OH. The peaks at 480 and 652 cm −1 are attributed to the Si-O vibration and O-Si-O bending, respectively [56,57]. Figure 1B (curve b) shows the FT-IR spectrum of the synthesized Al 2 O 3 nanoparticles. The absorption peak at 3388 cm −1 is due to the stretching mode of bending and stretching hydroxyl groups from the adsorbed water molecules. The peaks at 663-711 cm −1 and 1078 cm −1 are related to Al-O stretching and symmetric bending of Al-O-H, respectively [58][59][60]. Figure 1C presents the TEM micrographs of SiO 2 and Al 2 O 3 nanoparticles. The TEM micrograph of SiO 2 nanoparticles ( Fig. 1C image a) are high dispersion with some aggregation appeared and the particles size in the range of

Effect of γ-Irradiation on Gel Content (%)
EVA can be used for various applications but it suffers some disadvantages such as low tensile strength and high flammability. To improve its properties and crosslinking density, it is necessary to modify EVA using additives, fillers, irradiation, or blending with other polymers. The effect of γ-irradiation on either EVA alone or incorporated with conventional nanoparticles such as SiO 2 and/or Al 2 O 3 was studied as a function of gel content using hot toluene as a solvent was represented in Fig. 2 With an increase in the absorbed dose, more total radicals are produced, which leads to greater entanglement of the polymeric chains thus raising the interconnected crosslinking efficiency. The gel content percentage of EVA copolymer was enhanced via γ-irradiation and by incorporation of SiO 2 and Al 2 O 3 nanoparticles. It has been stated that the addition of nanosilica could enhance the properties of EVA copolymer [17,63]. As a result, the gel content percentage of the EVA copolymer was developed by γ-irradiation and was enhanced directly by the incorporation of SiO 2 and Al 2 O 3 nanoparticles. Figure 3 shows the XRD spectra of EVA, EVA/SiO 2 , EVA/ Al 2 O 3 , and EVA/SiO 2 /Al 2 O 3 nanocomposites. The neat EVA sample (Fig. 3a) shows a sharp crystalline peak at 2θ = 20.8°, resulting generally from the crystalline region of EVA caused by the inter-chain hydrogen bonding [64,65]. The XRD spectra of EVA/SiO 2 (Fig. 3b) shows a sharp crystalline peak corresponding to EVA at 2θ = 21.3° and a small peak at 2θ = 23.2° due to the diffraction peak of Sio 2 . Figure 3c shows the XRD spectra of EVA/Al 2 O 3 that includes a combination of the XRD diffraction peak of EVA copolymer at 2θ = 20.6° as well as the characteristic XRD diffraction peaks of

FTIR Results of EVA-Based Nanocomposites
The FTIR spectrum of EVA (Fig. 4a) shows the characteristic peaks attributed to the vinyl acetate groups. The sharp peak at 1735 cm −1 was attributed to the C=O stretching of carbonyl groups. The peak at 1238 cm −1 assigned to C-O-C stretching. The peak at 1021 cm −1 was related to O-C=O out of plane bending of the ester group. The peak at 1371 cm −1 was due to the stretching of the methylene CH 2 group. The peak at 1462 cm −1 was due to the bending vibration of the methylene -CH 2 group. The peaks at 2850-2917 cm −1 were attributed to the symmetric and asymmetric stretching vibration of methylene [64]. The FTIR results of EVA/ SiO 2 (Fig. 4b) (Fig. 4c) represents the same characteristic peaks of EVA in addition to the peak of Al-O stretching that appeared at 713 cm −1 and 1097 cm −1 . The interaction between EVA and Al 2 O 3 leads to a significant shift in the C=O stretching of EVA to 1719 cm −1 due to the inter-molecular hydrogen bonding formed between the C=O of acetate groups of EVA and OH groups on the surface of Al 2 O 3 particles. Figure 4d shows the FTIR spectrum of EVA/SiO 2 /Al 2 O 3 nanocomposite, the C=O stretching of EVA appeared at 1706 cm −1 and this shift was attributed to the incorporation of SiO 2 and Al 2 O 3 and inter-molecular hydrogen bonding formed. In addition, the peaks at 1099, 811, 713, and 471 cm −1 are corresponding to Si-O-Si, Si-OH, Al-O, and Si-O, respectively. These results confirmed that SiO 2 and Al 2 O 3 were fully incorporated with EVA copolymer.

DSC Results
The thermal behavior and the variations in melting temperature (T m ) of unirradiated EVA, irradiated EVA and EVA/ SiO 2 , EVA/Al 2 O 3 and EVA/SiO 2 /Al 2 O 3 nanocomposites were investigated using DSC measurements as presented in   Figure 6a presented that the surface of EVA is dense, tabular, and smooth, and no sign of porous structure. While Fig. 6b shows the SEM image of the EVA/SiO 2 nanocomposite, the SiO 2 particles were dispersed uniformly in the EVA matrix. The SiO 2 particles were embedded in the EVA matrix without aggregation and without phase separation between them. Furthermore, Fig. 6c shows the SEM image of EVA/Al 2 O 3 nanocomposite, where the Al 2 O 3 nanoparticles are easily observed in the microscopic image because of their bigger size compared with the SiO 2 particles. EVA/Al 2 O 3 nanocomposite image had a rock-shape surface, rough, and revealed some agglomeration. Additionally, the Al 2 O 3 nanoparticles were dispersed in the EVA matrix with white stone-like and irregular shapes. The SEM image of EVA/ Al 2 O 3 showed that Al 2 O 3 nanoparticles are more agglomerated than SiO 2 nanoparticles in SEM image of EVA/ SiO 2 . However after addition of SiO 2 to EVA/Al 2 O 3 , the surface became relative homogeneous and good dispersion was observed as well as the dispersion of both nanoparticles was significantly improved as presented in Fig. 6d for SEM image of EVA/SiO 2 /Al 2 O 3 nanocomposite, The improved morphology of EVA/SiO 2 /Al 2 O 3 nanocomposite might be due to the trapping of smaller size of SiO 2 , which reduces the chance of particle-particle interaction of both nanoparticles; as result dispersion is improved [66]. The SEM images reveal that the homogeneity of nanocomposites increased with the increase of dispersion of the SiO 2 nanoparticles.

Evaluation of Weight Gain (%)
The weight gain percentage onto CF after treatment by irradiated EVA, EVA/ SiO 2 , EVA/Al 2 O 3 , and EVA/SiO 2 /Al 2 O 3 nanocomposites is presented in Fig. 7 Figure 8 presents the change in the tensile strength and elongation at break percentage of the untreated CF and CF treated with EVA, EVA/SiO 2 , EVA/Al 2 O 3, and EVA/SiO 2 /Al 2 O 3 nanocomposites. Compared with control the CF, it was found that treatment of the CF with EVA based nanocomposites enhanced the mechanical properties. The tensile strength of CF with EVA based nanocomposites was higher than both of pure CF and CF treated with EVA alone (CF/EVA). It was found that the tensile strength of pure CF was 10 MPa and the tensile strength of CF/EVA, CF/EVA/SiO 2 , CF/ EVA/Al 2 O 3 , and CF/EVA/SiO 2 /Al 2 O 3 was improved to 17.9, 19.9, 25.4, and 26.5 MPa, respectively. The increase in the tensile strength of treated CF by EVA based nanocomposites as compared to CF and CF/EVA was enhanced via an ascending trend by the presence and interfacial interaction of SiO 2 and/or Al 2 O 3 nanoparticles within the EVA matrix. SiO 2 is commonly utilized as an improving agent in thermoplastic polymers to improve the mechanical properties, especially the tensile strength [68,69]. Moreover, Al 2 O 3 nanoparticles and EVA matrix interactions minimize the free movement of CF segments and thus enhance the increase in the tensile strength. This shows that introducing the SiO 2 and Al 2 O 3 with EVA was effective and leads to the formation of interactive matrix structures. In contrast, the elongation at break percentage of the treated CF decreased due to the reduction of interweaved interspaces between CF derived from the coating by EVA or EVA based nanocomposites films formed on the surface of fibers. These results produce a wide potential application in the industry of coatings of CF.

Thermal Properties of Treated CF
The thermal stability of CF/EVA, CF/EVA/SiO 2 , CF/EVA/Al 2 O 3 , and CF/ EVA/SiO 2 /Al 2 O 3 was investigated by TGA as shown in Fig. 9. The treated CF with EVA (CF/EVA) decomposed in three stages of weight loss percentages, where the first stage is up to 179 °C with weight loss of 5.3% is due to the elimination of water vaporization and elimination of volatile products, the second decomposition stage starts from 180 to 350 °C with weight loss of 30% is attributed to the loss of acetic acid due to the decomposition of vinyl acetate groups,

Fig. 8
Mechanical properties (tensile strength and elongation at break %) of the treated CF samples and the third stage starts from between 351 °C and 465 °C with complete decomposition and continuous losing weight which corresponds to the degradation of the polyethylene chains and thermal decomposition of crosslinked backbone and leads to the production of combustible gases and a small amount of char that is finally degraded at higher temperatures. The thermal degradation curves of treated fabrics with CF/EVA/SiO 2 , CF/EVA/Al 2 O 3 start decomposition in the first stage up to 234 °C and 246 °C with a weight loss of 4.8 and 3.3% respectively. the second decomposition stage starts from 369 °C with a weight loss of 29.6% and the third stage starts from 408 °C and ends at 497 °C leaving 2.6 and 13.8% as a residue of SiO 2 and Al 2 O 3 , respectively. Meanwhile, the thermal degradation curve of CF/EVA/SiO 2 / Al 2 O 3 was stable up to 252 °C without any weight loss then start their first stage from 252 to 364 °C with a weight loss of 24%, the second decomposition stage starts from 418 °C leaving 15.7% as a residue of SiO 2 /Al 2 O 3 . Therefore, the TGA results illustrated that the treatment of CF by EVA based nanocomposites, (CF/EVA/SiO 2 , CF/EVA/Al 2 O 3 , and CF/EVA/SiO 2 /Al 2 O 3 ), able to advance the thermal stability and had a significant impact on flammability of CF.

Water Absorption of Treated CF
The hydrophobic surface property of CF was developed by modification utilizing EVA based nanocomposites. The water absorption percentage for control and treated CF was measured as a function of the time up to 30 min as presented in Fig. 10A. It was found that the treated CF had a lower water absorbency. The capability of a material to absorb water is an indirect measure of its hydrophilicity. The water absorption (%) of control CF increases rapidly with the first 5 min., then increases gradually with time until reaches the maximum value after 15 min of 202.4%. However, the coating of CF with EVA lowers the water absorption (%) to 32.6% after 15 min. EVA played an important role in reducing the water absorption of CF about 6.3 folds. In addition the treatment of CF with EVA based nanocomposites played a crucial role in reducing the water absorption percentage of CF to a negligible value of 6-8% after 15 min. within 25 folds in reduction of their ability for water absorptivity. Therefore, the surfaces of the CF were converted from hydrophilic to hydrophobic. The surface morphologies of the CF coated by EVA, EVA/SiO 2 , EVA/Al 2 O 3 , and EVA/SiO 2 /Al 2 O 3 at low magnification (200X), are presented in Fig. 10B. The surface of pristine CF (Fig. 10B image a) appeared in characteristic parallel texture fibers. After treatment of CF, a thin layer of EVA has fully covered the spaces between texture fibers, even after it was coated with a smooth texture surface without aggregation as presented in Fig. 10B (images  b). On the other hand, a dense and stable layer of film is formed on the surface of CF after the modified treatment by EVA/SiO 2 , EVA/Al 2 O 3 , and EVA/SiO 2 /Al 2 O 3 as illustrated in Fig. 10B images c-e. Moreover, the CF surface became fully covered compared with the control CF. The fibers in the treated CF held together more tightly and did not easily fall off and separate, because of the crosslinking between fibers and EVA, SiO 2 and Al 2 O 3 compounds and a dense layer of film blocked the interstices between fibers. The stable building layer adhered onto the surface of CF by EVA, EVA/SiO 2 , EVA/Al 2 O 3 , and EVA/SiO 2 /Al 2 O 3 formed over CF may be due to (1) strong van der Waals forces existing between a between EVA, SiO 2 , Al 2 O 3 and textile fiber of the CF, (2) the formation of waterproof surface and (3) flexible EVA allow conformal adhered to the surface of textile fibers, which maximized the surface contact area between SiO 2 and Al 2 O 3 and CF.

Contact Angle
The surface wettability of treated CF was examined by contact angle measurements as depicted in Fig. 11. It was noticed that the modification of CF by EVA-based nanocomposites has an important impact on the resulting contact angle of treated CF. It is well known that the contact angle for pristine CF is zero degree because the pristine CF were easily wetted by water drops and spread instantly. Also, this is due to the capillary effect and the abundant hydrophilic hydroxyl groups of CF, that make fabric superhydrophilic [70]. On the other hand, the treatment of CF by EVA (CF/EVA) raised the contact angle to 65° and the net contact angle of EVA is 63.3° [71] which is closest to our results. EVA exhibits superhydrophobic behavior and has a less pronounced hydrophilic nature; therefore, coating of CF with EVA leads to an increase in the contact angle value. Upon treatment of CF by CF/EVA/SiO 2 , the contact angle was increased to 93° indicating that the addition of SiO 2 beside EVA produces a strong water resistance and increased the surface roughness at which the hydrophobicity of treated CF increased. Also, the increase in contact angles of CF/EVA/SiO 2 than CF/EVA is due to the increase in surface polarity and this is because the SiO 2 surface fully consists of various types of silanol groups (Si-OH) [72]. Moreover, the contact angles of the CF/EVA/Al 2 O 3 and CF/ EVA/SiO 2 /Al 2 O 3 are increased to 98° and 107° indicating hydrophobic surfaces. The increase in the contact angles for all treated CF indicates their affinity towards water decreases and reveals an increase in their hydrophobicity. The results showed that the coated CF has a strong hydrophobic ability. In similar results, it was found that the silk fabric treated with silica composite coatings possessed a good hydrophobic property with an increase in the contact angles [73].

Water Vapor Permeability
The WVTR was measured gravimetrically and was expressed as an amount of water vapor in gram able to pass through material within 24 h. Air permeability is an important factor in determining the performance of a textile, and therefore, the water vapor permeability of treated CF were determined by means of WVTR. The measured WVPR values of untreated and treated CF compared to open bottle (negative control) as a function of time up to 24 h are plotted in Fig. 12. Generally, the rate at which water vapor passes through CF depends on the nature of the fiber. With hydrophobic fibers, the rate is very slow, whereas, with hydrophilic fibers the rate is relatively fast. After 9 h the WVTR for negative control was 196 g/m 2 and initially falls by pure CF to 128 g/m 2 . The treatment of CF provides a linear decrease in the WVTR. After 9 h time, the WVTR of CF/EVA, CF/ EVA/SiO 2 , CF/EVA/Al 2 O 3 , and CF/EVA/SiO 2 /Al 2 O 3 was 75, 64, 60, and 38 g/m 2 , respectively. Finally after 24 h, the WVTR became 154. 97, 78, and 55 g/m 2 , and the pristine CF became 356 g/m 2 . Analyzing the results of WVTR as shown in Fig. 12 (inset), after 24 h the decrease in WVTR (%) of CF/EVA, CF/EVA/SiO 2 , CF/EVA/Al 2 O 3 , and CF/ EVA/SiO 2 /Al 2 O 3 was 56.7, 72.8, 77.9, and 84.4%, respectively and it is therefore considered particularly significant. The pristine CF displays higher WVTR ability owing to a large number of hydrophilic hydroxyl groups on the cellulose molecules which can form strong hydrogen bonds with the water molecules. After CF was subjected to weight gain by EVA-based nanocomposites, the thickness of the surface increased and the pore size decreased. Therefore, a weak attraction between water molecules and the surface of the treated CF leads to changing the hydrophilic surface of the CF to hydrophobic nature with waterproofing properties. This result is in consistence with previous studies, where the WVTR value decreases after the CF was treated with waterproofing finish [74].

Flame Retardant Application of Treated CF
The flame-retardant properties of the pure CF and treated CF were investigated by the limiting oxygen index (LOI) test and by vertical burning flame as presented in Figs. 13 and 14, respectively. The LOI is a widely utilized method as a simple and precise method to evaluate the flame retardant properties of materials. The LOI values denote the minimum level of oxygen needed to sustain a candle-like flame when a sample is burned in an atmosphere of oxygen and nitrogen. LOI is an indicator of the flammability of material under small flame conditions. The higher the LOI of the material indicate lower tendency to burn. Textiles are considered to   [75]. Figure 13 presents the LOI percentages of pure CF and treated CF samples. The LOI value of the pure CF are between 17 and 19% [76]. In this study, the untreated CF and CF treated with EVA (CF/EVA) showed similar LOI values of 18.8% and 19% respectively indicating that the CF and CF/EVA ignited easily in air. It was reported that the LOI value of EVA was 19.2% [17]. It can be seen that the LOI values of treated CF/EVA increased rapidly by the addition of SiO 2 and/or Al 2 O 3 from 19 to 29.3% and suggesting a synergistic effect and developing the flame resistance properties which is helpful to the LOI test. The LOI value of CF/EVA/SiO 2 , CF/EVA/Al 2 O 3 , and CF/EVA/SiO 2 / Al 2 O 3 was increased to 25.3%, 27.5%, and 29.3%, respectively. The results confirmed that treated CF samples afford flame resistance properties especially CF/EVA/SiO 2 /Al 2 O 3 . In a similar results, SiO 2 improved the LOI and enhanced the flame retardant of polypropylene [77] and EVA/magnesium hydroxide blends [78].
The flame retardant of the coated CF was examined using a vertical burning flame test, and the photographs of the different samples upon exposure to flame at different times up to 25 s are shown in Fig. 14. The pure CF was ignited immediately after 5 s, burned rapidly after 10 s, and emitted a lot of flame and smoke after 15 s. The same results were observed for CF/EVA; it was ignited and burned rapidly after 15 s without flame and smoke. On the other hand, the treated CF samples by EVA-based nanocomposites showed satisfying results providing a protective and coating layer on the surface of CF, keeping them from being destroyed by further burning. SiO 2 and Al 2 O 3 are usually considered to be inert additives in flame-retardant systems by prolonging the burning time. The samples of CF/EVA/SiO 2 and CF/EVA/ Al 2 O 3 were not ignited until 15 s. Furthermore, the burning time was prolonged and only about 10% of the CF samples ignited after 25 s with the addition of SiO 2 or Al 2 O 3 . The CF/EVA/SiO 2 /Al 2 O 3 sample provides the best result even after 25 s there is no ignition. The utilization of SiO 2 in conjunction with Al 2 O 3 as flame retardant systems provide an efficient charred layer in resisting a firing in EVA during burning. The modification of the CF with EVA/SiO 2 / Al 2 O 3 provides a synergistic retardant and contributes to decreasing the flammability and reduces the burning rate at the same time. Jiao and Chen (2011) indicated that the flame-retardant performances of the EVA composites were enhanced by SiO 2 [16]. From the results of the LOI and vertical flammability test, it was confirmed that the effectiveness and the stability of CF/EVA/SiO 2 /Al 2 O 3 against the effect of the flame even after 25 s of exposure and thus it could be used as flame retardant fabrics.

Conclusion
In this study, successful modification of cotton fabrics with EVA-based nanocomposites by coating method was achieved to improve the waterproof and fire retardant applications. The coating solution of EVA/SiO 2 , EVA/Al 2 O 3, and EVA/ SiO 2 /Al 2 O 3 , was synthesized by γ-irradiation. The thermal and physicochemical characteristic of EVA copolymer was developed by SiO 2 , Al 2 O 3 nanoparticles and γ-irradiation. An effective coating of the CF by EVA, EVA /SiO 2, EVA/ Al 2 O 3, and EVA /SiO 2 /Al 2 O 3 was carried out. The weight gain percentages of the CF after treatment with EVA, EVA/ SiO 2 , EVA/Al 2 O 3 , and EVA/SiO 2 /Al 2 O 3 nanocomposites were 36.8, 47.2, 58.4 and 53.8%, respectively. After treatment of the CF, enhanced properties were attained, namely, the surface became uniform, smooth and the spaces between fabrics were fully covered without aggregation. This is in addition to improved hydrophobic, thermal and mechanical properties. The flame retardant of the treated CF was tested using limited oxygen index (LOI) and the vertical burning flame tests. The LOI values of the CF, CF/EVA, CF/ EVA/SiO 2 , CF/EVA/Al 2 O 3 and CF/EVA/SiO 2 /Al 2 O 3 were increased to 18.8, 19.0, 25.3, 27.5, and 29.3%, respectively. The novel aspect and hypothesis of the present study was confirmed by the conversion of the CF from hydrophilic and flammable fabrics to hydrophobic and flame resistant via surface coating with EVA/SiO 2 /Al 2 O 3 nanocomposite prepared by γ-irradiation. The enhancement in the thermal, mechanical properties, LOI, permeability, contact angle, and water vapor characteristics of CF gives a promising aspect for the utilizing of the CF coated with EVA/SiO 2 /Al 2 O 3 as