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Synthesis, Structure and Photocatalytic Dye Degradation Ability of Co(II)-Based Coordination Polymers

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Abstract

Two Co(II)-based coordination polymers: {Co(L1)(bimb)·H2O·OH}n (1) and [Co(L2)(bidpe)]n (2) (H2L1 = 4-mercaptobenzoic acid, H2L2 = 4,4′-bis(thiomethylene) dibenzoic acid, bimb = 1,4-bis(imidazol-1-ylmethyl)benzene), bidpe = 4,4′-bis(imidazolyl)diphenyl ether), were synthesized under the condition of solvothermal and characterized by X-ray single-crystal diffraction, elemental analysis, IR spectra and thermogravimetric analysis (TGA). X-ray single-crystal diffraction analysis exhibits that 1 and 2 belong to the monoclinic crystal system, space group P21 and Cc. Complex 1 adopts a tetrahedron {CoN2O2} coordination geometry and complex 2 possesses a distorted trigonal bipyramid {CoN2O3} coordination geometry. Topology analysis results show that complex 1 and 2 possess a uninodal 4-connected 2D (two-dimensional) sql topology framework with the Schläfli symbol (44·62). Furthermore, the photocatalytic degradation property and mechanism of 1 and 2 for methylene blue (MB) were investigated. The results show that the band gap (Eg) of 1–2 is 2.69 eV and 2.60 eV, and the equipotential point (pHpzc) of 1–2 is 4.47 and 4.40. Complex 1–2 show excellent photocatalytic degradation for MB. ·OH is the main active substance causing MB degradation.

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References

  1. C.C. Wang, J. Zhang, P. Wang, H. Wang, H. Yan, Desalin. Water Treat. (2014). https://doi.org/10.1080/19443994.19442013.19873881

    Article  Google Scholar 

  2. N.M. Mahmoodi, R. Salehi, M. Arami, Desalination 272, 187 (2011)

    Article  CAS  Google Scholar 

  3. X.J. Li, F.Y. Qian, M. Li, Environ. Chem. 3, 396 (2012)

    Google Scholar 

  4. N. Peng, K.F. Wang, C.Q. Tu, Environ. Prot. Chem. Ind. 5, 464 (2011)

    Google Scholar 

  5. L.L. Fan, R.W. Lu, W.P. Chen, Environ. Sci. Technol. S1, 19 (2009)

    Google Scholar 

  6. C. Chen, P. Gunawan, R. Xu, J. Mater. Chem. 21, 1218 (2011)

    Article  CAS  Google Scholar 

  7. M. Fang, F. Mishima, Y. Akiyama, Physica C 470, 1827 (2010)

    Article  CAS  Google Scholar 

  8. M. Zhou, H. Sarkka, M. Sillanpaa, Sep. Purif. Technol. 78, 290 (2011)

    Article  CAS  Google Scholar 

  9. Y. Yao, K. Li, S. Chen, Chem. Eng. J. 187, 29 (2012)

    Article  CAS  Google Scholar 

  10. S.I. Lim, W.I. Chu, S.M. Phang, Bioresour. Technol. 101, 7314 (2010)

    Article  CAS  Google Scholar 

  11. B. Liang, Q. Yao, H. Cheng, Environ. Sci. Pollut. R. 19, 1385 (2012)

    Article  CAS  Google Scholar 

  12. L.S. Cui, J.R. Meng, Y.L. Gan, Y.C. Li, Inorg. Nano-Metal Chem. 47, 1537 (2017)

    Article  CAS  Google Scholar 

  13. L.S. Cui, X.M. Meng, Y.H. Fan, X. Li, C.F. Bi, J. Inorg. Organomet. Polym. 25, 1490 (2015)

    Article  CAS  Google Scholar 

  14. X.M. Meng, Y.C. Li, K.R. Huang, J.Q. Long, L.S. Cui, Inorg. Chim. Acta 482, 284 (2018)

    Article  CAS  Google Scholar 

  15. D.S. Liu, W.T. Chen, G.M. Ye, J.Q. Liu, Y. Sui, Inorg. Chim. Acta 477, 84 (2018)

    Article  CAS  Google Scholar 

  16. L.S. Cui, X.M. Meng, Y.G. Li, K.R. Huang, Y.C. Li, J.Q. Long, P.F. Yao, CrystEngComm 21, 3798 (2019)

    Article  CAS  Google Scholar 

  17. R. Bagade, R.G. Chaudhary, A. Potbhare, A. Mondal, M. Desimone, K. Dadure, R. Mishra, H. Juneja, ChemistrySelect 4, 6233 (2019)

    Article  CAS  Google Scholar 

  18. R.G. Chaudhary, H.D. Juneja, M.P. Gharpure, J. Therm. Anal. Calorim. 112, 637 (2013)

    Article  CAS  Google Scholar 

  19. R.G. Chaudhary, H.D. Juneja, M.P. Gharpure, J. Chin. Adv. Mater. Soc. 1, 121 (2013)

    Article  CAS  Google Scholar 

  20. Y.B. He, W. Zhou, G. Qian, Chem. Soc. Rev. 43, 5657 (2014)

    Article  CAS  Google Scholar 

  21. J.A. Mason, M. Veenstra, J.R. Long, Chem. Sci. 5, 32 (2014)

    Article  CAS  Google Scholar 

  22. W. Zhou, D.D. Huang, Y.P. Wu, J. Zhao, T. Wu, J. Zhang, D.S. Li, C.H. Sun, P.Y. Peng, X.H. Bu, Angew. Chem. Int. Ed. 58, 4227 (2019)

    Article  CAS  Google Scholar 

  23. J.W. Tian, Y.P. Wu, Y.S. Li, J.H. Wei, J.W. Yi, S. Li, J. Zhao, D.S. Li, Inorg. Chem. 58, 5837 (2019)

    Article  CAS  Google Scholar 

  24. D.D. Huang, S. Li, Y.P. Wu, J.H. Wei, J.W. Yi, H.M. Ma, Q.C. Zhang, Y.L. Liu, D.S. Li, Chem. Commun. 55, 4570 (2019)

    Article  CAS  Google Scholar 

  25. J. Ye, L. Zhao, R.F. Bogale, Chem. A Eur. J. 21, 2029 (2015)

    Article  CAS  Google Scholar 

  26. W.P. Lustig, S. Mukherjee, N.D. Rudd, Chem. Soc. Rev. 46, 3242 (2017)

    Article  CAS  Google Scholar 

  27. T. Yamada, M. Sadakiyo, A. Shigematsu, Bull. Chem. Soc. Jpn. 89, 1 (2015)

    Article  Google Scholar 

  28. S.S. Bao, G.K.H. Shimizu, L.M. Zheng, Coordin. Chem. Rev. 378, 577 (2017)

    Google Scholar 

  29. V.A. Blatov, IUCrCompComm Newsletter 7, 4 (2006)

    Google Scholar 

  30. O.D. Friedrichs, Program SYSTRE 1.14 beta (2007)

  31. G.M. Sheldrick, SHELXTL NT, version 5.1, Program for Solution, Refinement of Crystal Structures, University of GÖttingen, GÖttingen, Germany (1997).

  32. Bruker, SMART, version 5.0, SAINT-plus version 6, SHELXTL, version 6.1, SADABS version 2.03, Bruker AXS Inc.: Madison, WI (2000).

  33. J. Lü, J.X. Lin, X.L. Zhao, R. Cao, Chem. Commun. 48, 669 (2012)

    Article  Google Scholar 

  34. X.L. Wang, C.H. Gong, J.W. Zhang, G.C. Liu, X.M. Kan, N. Xu, CrystEngComm 17, 4179 (2015)

    Article  CAS  Google Scholar 

  35. R.G. Chaudhary, P. Ali, N.V. Gandhare, J.A. Tanna, H.D. Juneja, Arab. J. Chem. (2016). https://doi.org/10.1016/j.arabjc.2016.03.008

    Article  Google Scholar 

  36. Y. Gong, T. Wu, J. Lin, CrystEngComm 14, 3727 (2012)

    Article  CAS  Google Scholar 

  37. H.S. Liu, Y.Q. Lan, S.L. Li, Cryst. Growth Des. 10, 5221 (2010)

    Article  CAS  Google Scholar 

  38. J. Guo, J.F. Ma, B. Liu, W.Q. Kan, J. Yang, Cryst. Growth Des. 11, 3609 (2011)

    Article  CAS  Google Scholar 

  39. N. Zaghbani, A. Hahiane, M. Dhahbi, Sep. Purif. Technol. 55, 117 (2007)

    Article  CAS  Google Scholar 

  40. J.L. Gong, B. Wang, G.M. Zeng, C.P. Yang, C.G. Niu, Q.Y. Niu, W.J. Zhou, Y. Liang, J. Hazard. Mater. 164, 1517 (2009)

    Article  CAS  Google Scholar 

  41. T.T. Li, Y.M. He, H.J. Lin, J. Cai, L.Z. Dong, X.X. Wang, M.F. Luo, L.H. Zhao, X.D. Yi, W.Z. Weng, Appl. Catal. B 138, 95 (2013)

    Article  Google Scholar 

  42. Y.H. Liang, S.L. Lin, L. Liu, J.S. Hu, W.Q. Cui, Appl. Catal. B 164, 192 (2015)

    Article  CAS  Google Scholar 

  43. H.X. Yang, T.F. Liu, M.N. Cao, H.F. Li, S.Y. Gao, R. Cao, Chem. Commun. 46, 2429 (2010)

    Article  CAS  Google Scholar 

  44. X.M. Meng, C.B. Fan, C.F. Bi, Z.A. Zong, X. Zhang, Y.H. Fan, CrystEngComm 18, 2901 (2016)

    Article  CAS  Google Scholar 

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Acknowledgements

This research was supported by the Guangxi Natural Science Foundation to P. F. Yao (2018GXNSFBA281197, 2018GXNSFAA294060) and the university-level scientific research project of Baise University in 2018 to L. S. Cui (2018KN17).

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  1. Guangxi Colleges and Universities Key Laboratory of Regional Ecological, Environment Analysis and Pollution Control of West Guangxi, College of Chemistry and Environmental Engineering, Baise University, Baise, 533000, Guangxi, China

    Weiyuan Zuo, Yongfeng Fan, Lijin Yang & Liansheng Cui

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  1. Weiyuan Zuo
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  2. Yongfeng Fan
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Zuo, W., Fan, Y., Yang, L. et al. Synthesis, Structure and Photocatalytic Dye Degradation Ability of Co(II)-Based Coordination Polymers. J Inorg Organomet Polym 30, 2105–2113 (2020). https://doi.org/10.1007/s10904-019-01356-0

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