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Defective MIL-125 Nanocrystals with Enhanced Catalytic Performance for Oxidative Denitrogenation

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Abstract

The Ti-based metal-organic framework (Ti-MOF) MIL-125 nanocrystals with structural defects were synthesized by coordination modulation method. Compared to the pristine microporous MIL-125, the defective MIL-125 nanocrystals obtained hierarchically micro-meso-macroporous structure. Furthermore, the missing-linker defects provide rich coordinatively unsaturated sites (CUSs) that greatly promote the intrinsic catalytic activity. It is demonstrated for the first time that the defective hierarchically porous MIL-125 nanocrystals possess highly efficient catalytic performance towards the oxidative denitrogenation (ODN).

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Acknowledgements

We gratefully acknowledge the financial by the National Natural Science Foundation of China (U1804120).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang, 464000, China

    Hai-Ting Lv, Pei Yang, Na Li & Yang Fan

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  1. Hai-Ting Lv
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  2. Pei Yang
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Lv, HT., Yang, P., Li, N. et al. Defective MIL-125 Nanocrystals with Enhanced Catalytic Performance for Oxidative Denitrogenation. J Clust Sci 34, 1445–1451 (2023). https://doi.org/10.1007/s10876-022-02316-4

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