Skip to main content
SpringerLink
Log in

Synthesis and Structural Analysis of a 3D Semi-Rigid Cd Coordination Polymer

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

A three dimensional semi-rigid coordination polymer {Cd3(OH){cpta}2(bpe)2(H2O)·xSolvents}n (1) was solvothermal synthesized with a V-shaped semi-rigid carboxylic acid, H3cpta = 3-(3-carboxyphenoxy)phthalic acid (H3cpta) and auxiliary ligand, 1,2-di(pyridin-4-yl)ethene (bpe). Single crystal X-ray analysis shows that 1 features a P-1 space group with three crystal independent Cd(II) ions, which are connected by carboxylate ligands and auxiliary ligand. There is a porous metal–organic layer subunit constructed by carboxylate ligands and Cd ions, which shows porous coordination polymers could be synthesized by this type of semi-rigid organic spacers. However, reactions without auxiliary ligands were also investigated, but no product was obtained, which shows N-contained auxiliary ligands show important templates in the solvothermal synthesis condition of the semi-rigid coordination polymers. Besides, the luminescent and thermal properties were also studied. The CCDC number of 1 is 1894883.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. S. R. Batten, S. M. Neville, and D. R. Turner Coordination Polymers Design, Analysis and Application (Royal Society of Chemistry, London, 2009).

    Google Scholar 

  2. J. R. Li, Y. G. Ma, M. C. McCarthy, J. Sculley, J. M. Yu, H. K. Jeong, P. B. Balburena, and H. C. Zhou (2011). Coord. Chem. Rev.255, 1791.

    Article  CAS  Google Scholar 

  3. J. B. Decoste and G. W. Peterson (2014). Chem. Rev.114, 5695.

    Article  CAS  Google Scholar 

  4. M. T. Zhao, K. Yuan, Y. Wang, G. D. Li, J. Guo, L. Gu, W. P. Hu, H. J. Zhao, and Z. Y. Tang (2016). Nature539, 76.

    Article  CAS  Google Scholar 

  5. C. P. Li and M. Du (2011). Chem. Commun.47, 5958.

    Article  CAS  Google Scholar 

  6. Z. J. Zhang and M. Zaworotko (2014). Chem. Soc. Rev.43, 5444.

    Article  CAS  Google Scholar 

  7. W. H. Zhang, Z. Dong, Y. Y. Wang, L. Hou, J. C. Jin, W. H. Huang, and Q. Z. Shi (2011). Dalton Trans.40, 2509.

    Article  CAS  Google Scholar 

  8. Y. L. Hu, M. L. Ding, X. Q. Liu, L. B. Sun, and H. L. Jiang (2016). Chem. Commun.52, 5734.

    Article  CAS  Google Scholar 

  9. W. Y. Gao, S. Palakurty, L. Wojtas, Y. S. Chen, and S. Q. Ma (2015). Inorg Chem. Front.2, 369.

    Article  CAS  Google Scholar 

  10. L. W. Han, J. Lü, Z. J. Lin, and R. Cao (2014). CrystEngComm16, 1749.

    Article  CAS  Google Scholar 

  11. Z. H. Zhou, M. L. Han, Y. P. Wu, W. W. Dong, D. S. Li, and J. Y. Lu (2016). J. Solid State Chem.242, 207.

    Article  CAS  Google Scholar 

  12. L. Cui, Q. H. Wang, J. W. Duan, K. Wang, and Y. Y. Wang (2018). J Coord. Chem.71, 421.

    Article  CAS  Google Scholar 

  13. J. Z. Gu, Y. H. Cui, X. X. Liang, J. Wu, D. Y. Lv, and A. M. Kirillov (2016). Cryst. Growth Des.16, 4658.

    Article  CAS  Google Scholar 

  14. S. A. Sotnik, R. A. Polunin, M. A. Kiskin, A. M. Kirillov, V. N. Dorofeeva, K. S. Gavrilenko, I. L. Eremenko, V. M. Novotortsev, and S. V. Kolotilov (2015). Inorg. Chem.54, 5169.

    Article  CAS  Google Scholar 

  15. W. Huang, F. F. Pan, Y. Liu, S. D. Huang, Y. J. Li, J. Yong, Y. Li, A. M. Kirillov, and D. Y. Wu (2017). Inorg. Chem.56, 6362.

    Article  CAS  Google Scholar 

  16. Q. S. Zhang, J. Wang, A. M. Kirillov, W. Dou, C. Xu, C. L. Xu, L. Z. Yang, R. Fang, and W. S. Liu (2018). ACS Appl. Mater. Interfaces10, 23976.

    Article  CAS  Google Scholar 

  17. G. M. Sheldrick SHELXL-97, Program for Refinement of Crystal Structures (University of Göttingen, Göttingen, 1997).

    Google Scholar 

  18. G. M. Sheldrick SADABS, Program for Area Detector Adsorption Correction (Institute for Inorganic Chemistry, University of Göttingen, Göttingen, 1996).

    Google Scholar 

  19. A. L. Spek (2009). Acta Crystallogr. D65, 148.

    Article  CAS  Google Scholar 

  20. L. Y. Pang, G. P. Yang, J. C. Jin, M. Kang, A. Y. Fu, Y. Y. Wang, and Q. Z. Shi (2014). Cryst. Growth Des.14, 2954.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work is supported by Natural Science Foundation of Shaanxi Province (No. 2019JQ-477) and the Fundamental Research Funds for the Central Universities, CHD (NO. 300102129013).

Author information

Authors and Affiliations

  1. Department of Chemistry and Material Science, School of Science, Chang’an University, Xi’an, Shaanxi, People’s Republic of China

    Lin Cui, Jinwei Duan, Huayu Zheng, Ying Wang & Kang Wang

Authors
  1. Lin Cui
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jinwei Duan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Huayu Zheng
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ying Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Kang Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Lin Cui.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 291 kb)

Supplementary material 2 (CIF 29 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Cui, L., Duan, J., Zheng, H. et al. Synthesis and Structural Analysis of a 3D Semi-Rigid Cd Coordination Polymer. J Clust Sci 31, 207–211 (2020). https://doi.org/10.1007/s10876-019-01637-1

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-019-01637-1

Keywords

Search

Navigation