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Bi0.5Na0.5TiO3-based ceramics with high energy storage density and good thermal stability

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Abstract

Ceramic capacitors with large energy storage density, high energy storage efficiency, and good temperature stability are the focus of current research. In this study, the structure, dielectric properties, and energy storage properties of (1−x)Bi0.5Na0.5TiO3−xSrTi0.8Sn0.2O3 ((1−x)BNT−xSTS) ceramics were systematically studied. Increasing the STS content resulted in the crystal structure changing from a rhombohedral to a pseudo-cubic phase. Additionally, the average grain size decreased from 3.79 μm for the BNT ceramic to 1.27 μm for the 0.5BNT−0.5STS ceramic. As the STS content increased, the relaxation properties of the ceramics were enhanced, in particular, the 0.6BNT−0.4STS ceramic exhibit excellent temperature stability from 43 to 243 °C. Furthermore, a large recoverable energy storage density (Wrec) of 2.47 J/cm3 and a high energy storage efficiency (η) of 83.2% were achieved in the ceramic of 0.6BNT−0.4STS. These results indicate that the ceramic of 0.6BNT−0.4STS is a potential energy storage material that can be used in pulse power systems within a wide temperature range.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant Nos. 51872177 and 201020015), the Fundamental Research Funds for the Central Universities (Program Nos. GK202002014 and KY2019YB013), and the Natural Science Basis Research Plan in Shaanxi Province of China (Program Nos. 202040027).

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Authors and Affiliations

  1. School of Science, Xi’an University of Posts and Telecommunications, Xi’an, 710121, Shaanxi, China

    Xiaoshuang Qiao

  2. Key Laboratory for Macromolecular Science of Shaanxi Province, Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Laboratory for Advanced Energy Technology, School of Materials Science and Engineering, Shaanxi Normal University, Xi’an, 710062, Shaanxi, China

    Xiaoshuang Qiao, Xiaolian Chao & Zupei Yang

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  1. Xiaoshuang Qiao
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Qiao, X., Chao, X. & Yang, Z. Bi0.5Na0.5TiO3-based ceramics with high energy storage density and good thermal stability. J Mater Sci: Mater Electron 33, 2012–2019 (2022). https://doi.org/10.1007/s10854-021-07404-1

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