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Structural, mechanical, thermal, electro-optical studies on diprotonated adipate salt of para-anisidine for intensity tunable optical limiting applications

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Abstract

Diprotonated salt of bis(4-methoxyanilinium) adipate [2(C7H10NO) +·(C6H8O2)−] has been synthesized and its crystal has grown by solvent evaporation technique. Good quality of the grown crystal is subjected to single-crystal XRD and powder XRD analyses; it revealed the molecular arrangements, formation of hydrogen bonds, and crystalline nature. The grown crystal crystallizes in a triclinic crystal system, \(P\bar{1}\) space group with Z = 2. Decomposition and thermal behavior have been analyzed by TG–DTA measurements. The mechanical properties and dielectric behavior have been investigated from Vickers microhardness analysis and LCR meter. Optical transmittance spectrum was recorded and the optical bandgap has been calculated by Tauc plot. Furthermore, grown crystal has been characterized for third-harmonic generation by Z-Scan technique. The calculated nonlinear refractive index (n2), nonlinear absorption coefficient (β), and nonlinear optical susceptibility (χ3) values of the grown single crystal were 7.10 × 10−8 cm2/W, 0.05 × 10−4 cm/W, and 10.09 × 10−6 esu, respectively. The self-defocusing behavior is performed by the positive value of the nonlinear refractive index. The nonlinear absorption coefficient value indicates that 4MAA crystal is an efficient optical limiter.

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Acknowledgement

This research work was funded by the CSIR [grant No. 03(1276)/13/EMR-ll) New Delhi-110012, India.

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Authors and Affiliations

  1. Department of Physics, School of Advanced Sciences, Kalasalingam Academy of Research and Education, Krishnankoil, 626 126, India

    V. Siva, A. Shameem, A. Murugan, M. Anandha Jothi & S. Asath Bahadur

  2. Condensed Matter Physics Laboratory, International Research Centre, Kalasalingam Academy of Research and Education, Krishnankoil, 626 126, India

    V. Siva, A. Shameem, A. Murugan, M. Anandha Jothi & S. Asath Bahadur

  3. Department of Physics, Er. Perumal Manimekalai College of Engineering, Hosur, 635117, India

    M. Suresh

  4. Department of Physics, University College of Engineering Nagercoil, Nagercoil, 629 004, India

    S. Athimoolam

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  1. V. Siva
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Siva, V., Shameem, A., Murugan, A. et al. Structural, mechanical, thermal, electro-optical studies on diprotonated adipate salt of para-anisidine for intensity tunable optical limiting applications. J Mater Sci: Mater Electron 31, 17921–17930 (2020). https://doi.org/10.1007/s10854-020-04344-0

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