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A novel bio-based benzoxazine resin with outstanding thermal and superhigh-frequency dielectric properties

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Abstract

A novel bio-based benzoxazine was synthesized from diphenolic acid and furfurylamine through the facile one-pot formulation method. In comparison with other bio-based thermosetting resins and bio-based benzoxazine resins, the prepared benzoxazine resin had the advantages of accelerated curing behavior, relatively good thermal properties (Tg, 303 °C; char yield (800 °C), 54%), and relatively low superhigh-frequency dielectric constants (2.97 ± 0.01, 5 GHz; 2.95 ± 0.01, 10 GHz; 2.90 ± 0.01, 15 GHz), resulting from the introduction of acidic groups and furan rings. Therefore, this work not only provides a new strategy for the preparation of biomass-based benzoxazine resin with superhigh-frequency low dielectric constants, but also gives some insight into the effects of pentanoic acid and furan rings on the curing behavior, cross-linking structure, and thermal and superhigh-frequency dielectric properties of benzoxazine resin. Furthermore, the potential application of this approach in the advanced superhigh-frequency communication field might make progress towards the sustainable development of high-tech polymeric industry.

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Acknowledgements

This research has been supported by “555” Innovation Team Program (Huaibei) (2019), Anhui Province, PR China, the SRF for ROCS, State Education Ministry (SEM1341), PR China, Hubei Provincial Department of Education (XD2010037), and Engineering Research Center of Nano-Geomaterials of Ministry of Education (CUG2015).

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Authors and Affiliations

  1. Engineering Research Center of Nano-Geomaterials of Ministry of Education, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan, 430074, People’s Republic of China

    Zijian Feng, Ming Zeng & Dawei Meng

  2. Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan, 430074, People’s Republic of China

    Zijian Feng, Ming Zeng, Jiangbing Chen, Wanlin Zhu, Qingyu Xu & Junxia Wang

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  1. Zijian Feng
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10854_2020_2995_MOESM1_ESM.docx

Digital photos of cured films (Fig. S1); full FTIR spectra of BA, DA, and DF (Fig. S2); full non-isothermal DSC curves of BA, DA, and DF (Fig. S3); FESEM photographs of fracture surfaces of cured films (Fig. S4); TMA curves of PBA, PDA, and PDF (Fig. S5); rough comparison of DF based benzoxazine resin with other bio-based thermosetting resins (Table S1); and rough comparison of DF based benzoxazine with some bio-based benzoxazines (Table S2). Supplementary file1 (DOCX 1388 kb)

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Feng, Z., Zeng, M., Meng, D. et al. A novel bio-based benzoxazine resin with outstanding thermal and superhigh-frequency dielectric properties. J Mater Sci: Mater Electron 31, 4364–4376 (2020). https://doi.org/10.1007/s10854-020-02995-7

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