Abstract
Owing to the merits of environmental friendliness and sustainability, aqueous zinc ion battery (AZIB) is considered as a promising energy storage system. Nevertheless, the further application of AZIB is largely limited by the growth of zinc dendrite and hydrogen evolution reaction of Zn anode. Here, a β-polyvinylidene fluoride (β-PVDF) nanofiber modified by 1-butyl-3-methyl imidazolium trifluoromethane sulfonate coating layer was prepared to tackle the problem of Zn anode. The artificial β-PVDF can restrict HER and provide driving force to accelerate the migration of Zn2+ at electrolyte/Zn interface, which enables uniform and compact Zn deposition. And the symmetric cell with polymer-coating-layer-modified Zn anode demonstrates a long cycle for 1000 h at 2 mA cm−2. Moreover, the artificial β-PVDF nanofiber layer achieves a very low polarization voltage of about 50 mV even if the current density gradually increases to 10 mA cm−2. Consequently, the β-PVDF/BMI@Zn||MnO2 full cell reaches a high specific capacity of 186 mAh g−1 after 1600 cycles at 1 A g−1. This work provides a new possibility for the realization of high performance Zn anode.
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Acknowledgements
The authors would like to thank the financial supports from “the National Natural Science Foundation of China” (Grant no. 51673154) and “the Fundamental Research Funds for the Central Universities” (WUT: 2019IVA003).
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XY conception, methodology, experimental design, carrying out measurements and manuscript composition. JY and CL conception, methodology, and writing, reviewing, and editing. ZZ and CX methodology, supervision, formal analysis, visualization, writing, reviewing, and editing, and funding acquisition.
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Yuan, X., Yi, J., Li, C. et al. An artificial β-PVDF nanofiber layer for dendrite-free zinc anode in rechargeable aqueous batteries. J Mater Sci 58, 1708–1720 (2023). https://doi.org/10.1007/s10853-023-08139-6
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DOI: https://doi.org/10.1007/s10853-023-08139-6