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Fabrication of high-performance graphene oxide/CuO/Cu2O film-coated copper foam for interfacial solar-driven water evaporation

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Abstract

Interfacial solar-driven water evaporation (ISDWE) technology has received tremendous attention for its potential application in clean water production. However, its practical application requires more robust, efficient and multifunctional photothermal materials. For this case, growth of CuO/Cu2O film and graphene oxide assembly were successively conducted on the surface of Cu foam in this study, making positive contribution to the ISDWE performance. By the growth of CuO/Cu2O film, solar light utilization ability and surface wettability of Cu foam were enhanced, and the ISDWE performance was increased. It was also found that the pores per inch (PPI) value and thickness of Cu foam have a double-edged sword effect on the ISDWE performance. This could originate from the synergetic effect of surface area for evaporation, water pumping and vapor diffusion abilities. Among various PPI values and thicknesses, Cu@CuO/Cu2O foam with PPI value of 60 and 3 mm thickness demonstrated optimal ISDWE performance. By subsequent graphene oxide modification, the solar light utilization ability and surface wettability were further enhanced, the water evaporation rate reached 1.539 kg m−2 h−1, and the water evaporation efficiency was 96.64%. Moreover, the combination of CuO/Cu2O film and graphene oxide resulted in superior photocatalytic property on degrading Rhodamine B solution. The obtained results could provide important theoretical and practical reference value for the design of advanced photothermal materials.

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References

  1. Li Y, Cui X, Zhao M, Xu Y, Chen L, Cao Z, Yang S, Wang Y (2019) Facile preparation of a robust porous photothermal membrane with antibacterial activity for efficient solar-driven interfacial water evaporation. J Mater Chem A 7:704–710

    Article  CAS  Google Scholar 

  2. Zhang Y, Zhao D, Yu F, Yang C, Lou J, Liu Y, Chen Y, Wang Z, Tao P, Shang W, Wu J, Song C, Deng T (2017) Floating rGO-based black membranes for solar driven sterilization. Nanoscale 9:19384–19389

    Article  CAS  Google Scholar 

  3. Xie Z, Duo Y, Lin Z, Fan T, Xing C, Yu L, Wang R, Qiu M, Zhang Y, Zhao Y, Yan X, Zhang H (2020) The Rise of 2D Photothermal Materials beyond Graphene for Clean Water Production. Adv Sci 7:1902236

    Article  CAS  Google Scholar 

  4. Chen S, Sun Z, Xiang W, Shen C, Wang Z, Jia X, Sun J, Liu CJ (2020) Plasmonic wooden flower for highly efficient solar vapor generation. Nano Energy 76:104998

    Article  CAS  Google Scholar 

  5. Dao VD, Vu NH, Yun S (2020) Recent advances and challenges for solar-driven water evaporation system toward applications. Nano Energy 68:104324

    Article  CAS  Google Scholar 

  6. Cai T, Liu B, Pang E, Ren W, Li S, Hu S (2020) A review on the preparation and application of coal-based fluorescent carbon dots. New Carbon Mater 35:646–666

    Article  Google Scholar 

  7. Zhou L, Tan Y, Ji D, Zhu B, Zhang P, Xu J, Gan Q, Zhu J (2016) 3D Self-assembly of highly efficient, broadband plasmonic absorbers for solar steam generation. Sci Adv 2:e1501227

    Article  Google Scholar 

  8. Zhao F, Zhou X, Shi Y, Qian X, Alexander M, Zhao X, Mendez S, Yang R, Qu L, Yu G (2018) Highly efficient solar vapour generation via hierarchically nanostructured gels. Nat Nanotechnol 13:489–495

    Article  CAS  Google Scholar 

  9. Jin Y, Chang J, Shi Y, Shi L, Hong S, Wang P (2018) A highly flexible and washable nonwoven photothermal cloth for efficient and practical solar steam generation. J Mater Chem A 6:7942–7949

    Article  CAS  Google Scholar 

  10. Liu Y, Lou J, Ni M, Song C, Wu J, Dasgupta NP, Tao P, Shang W, Deng T (2016) Bioinspired bifunctional membrane for efficient clean water generation. ACS Appl Mater Interfaces 8:772–779

    Article  CAS  Google Scholar 

  11. Huang W, Su P, Cao Y, Li C, Chen D, Tian X, Su Y, Qiao B, Tu J, Wang X (2020) Three-dimensional hierarchical CuxS-based evaporator for high-efficiency multifunctional solar distillation. Nano Energy 69:104465

    Article  CAS  Google Scholar 

  12. Guo Y, Sui Y, Zhang J, Cai Z, Xu B (2020) An all-day solar-driven vapor generator via photothermal and joule-heating effects. J Mater Chem A 8:25178–25186

    Article  CAS  Google Scholar 

  13. Xu H, Wang W, Zhu W, Zhou L, Ruan M (2007) Hierarchical-oriented attachment: from one-dimensional Cu(OH)2 nanowires to two-dimensional CuO nanoleaves. Cryst Growth Des 7:2720–2724

    Article  CAS  Google Scholar 

  14. Lee S, Park S, Jeong H, Kim CW, Lee D, Jin C (2015) Effects of post-annealing treatment on the microstructural evolution and quality of Cu(OH)2 nanowires. J Alloy Compd 652:153–157

    Article  CAS  Google Scholar 

  15. Zhang Q, Huang L, Kang S, Yin C, Ma Z, Cui L, Wang Y (2017) CuO/Cu2O nanowire arrays grafted by reduced graphene oxide: synthesis, characterization, and application in photocatalytic reduction of CO2. RSC Adv 7:43642–43647

    Article  CAS  Google Scholar 

  16. Zhang Z, Sun L, Wu Z, Liu Y, Li S (2020) Facile hydrothermal synthesis of CuO–Cu2O/GO nanocomposites for the photocatalytic degradation of organic dye and tetracycline pollutants. New J Chem 44:6420–6427

    Article  CAS  Google Scholar 

  17. Liang X, Chen X, Xiang Z, Yan R, Xi H, Bian T, Zhang J, Zhao J, Cai Q, Wang H (2018) Design and synthesis of surface-controlled CuOx/rGO nanocomposites with unusually high efficiency in catalytic conversion of organic reactants in the presence of NaBH4. Appl Surf Sci 459:716–722

    Article  CAS  Google Scholar 

  18. Khanderi J, Contiu C, Engstler J, Hoffmann RC, Schneider JJ, Drochner A, Vogel H (2011) Binary [Cu2O/MWCNT] and ternary [Cu2O/ZnO/MWCNT] nanocomposites: formation, characterization and catalytic performance in partial ethanol oxidation. Nanoscale 3:1102–1112

    Article  CAS  Google Scholar 

  19. Huang Q, Kang F, Liu H, Li Q, Xiao X (2013) Highly aligned Cu2O/CuO/TiO2 core/shell nanowire arrays as photocathodes for water photoelectrolysis. J Mater Chem A 1:2418–2425

    Article  CAS  Google Scholar 

  20. Pang Y, Zhang J, Ma R, Qu Z, Lee E, Luo T (2020) Solar–thermal water evaporation: a review. ACS Energy Lett 5:437–456

    Article  CAS  Google Scholar 

  21. Wu X, Chen GY, Owens G, Chu D, Xu H (2019) Photothermal materials: A key platform enabling highly efficient water evaporation driven by solar energy. Mater Today Energy 12:277–296

    Article  Google Scholar 

  22. Zhu L, Gao M, Peh CKN, Ho GW (2019) Recent progress in solar-driven interfacial water evaporation: Advanced designs and applications. Nano Energy 57:507–518

    Article  CAS  Google Scholar 

  23. Zhang D, Yang J, Wang J, Yang J, Qiao G (2020) Construction of Cu2O-reduced graphene oxide composites with enhanced photoelectric and photocatalytic properties. Opt Mater 100:109612

    Article  CAS  Google Scholar 

  24. Chen D, Zhang X, Lee AF (2015) Synthetic strategies to nanostructured photocatalysts for CO2 reduction to solar fuels and chemicals. J Mater Chem A 3:14487–14516

    Article  CAS  Google Scholar 

  25. Khan F, Khan MS, Kamal S, Arshad M, Ahmad SI, Nami SAA (2020) Recent advances in graphene oxide and reduced graphene oxide based nanocomposites for the photodegradation of dyes. J Mater Chem C 8:15940–15955

    Article  CAS  Google Scholar 

  26. Liu G, Xu J, Wang K (2017) Solar water evaporation by black photothermal sheets. Nano Energy 41:269–284

    Article  CAS  Google Scholar 

  27. Popa C, Okayasu Y, Katsumata K, Isobe T, Matsushita N, Nakajima A, Kurata T, Okada K (2013) Capillary rise properties of porous mullite ceramics prepared by an extrusion method with various diameters of fiber pore formers. J Mater Sci 48:941–947. https://doi.org/10.1007/s10853-012-6819-y

    Article  CAS  Google Scholar 

  28. Jiang H, Geng X, Li S, Tu H, Wang J, Bao L, Yang P, Wan Y (2020) Multi-3D hierarchical biomass-based carbon particles absorber for solar desalination and thermoelectric power generator. J Mater Sci Technol 59:180–188

    Article  Google Scholar 

  29. Wu T, Liu G, Zhao J, Hidaka H, Serpone N (1998) Photoassisted degradation of dye pollutants. V. Self-photosensitized oxidative transformation of Rhodamine B under visible light irradiation in aqueous TiO2 dispersions. J Phys Chem B 102:5845–5851

    Article  CAS  Google Scholar 

  30. McFarland EW, Metiu H (2013) Catalysis by doped oxides. Chem Rev 113:4391–4427

    Article  CAS  Google Scholar 

  31. Singh J, Juneja S, Soni R-K, Bhattacharya J (2021) Sunlight mediated enhanced photocatalytic activity of TiO2 nanoparticles functionalized CuO–Cu2O nanorods for removal of methylene blue and oxytetracycline hydrochloride. J Colloid Interf Sci 590:60–71

    Article  CAS  Google Scholar 

  32. Weng S, Pei Z, Zheng Z, Hu JL, P, (2013) Exciton-free, nonsensitized degradation of 2-Naphthol by facet-dependent BiOCl under visible light: novel evidence of surface-state photocatalysis. ACS Appl Mater Interfaces 5:12380–12386

    Article  CAS  Google Scholar 

  33. Jabeen M, Ishaq M, Song W, Xu L, Maqsood I, Deng Q (2017) UV-Assisted Photocatalytic synthesis of ZnO-reduced graphene oxide nanocomposites with enhanced photocatalytic performance in degradation of methylene blue. ECS J Solid State Sci Technol 6:M36–M43

    Article  CAS  Google Scholar 

  34. Sahu K, Satpati B, Singhal R, Mohapatra S (2020) Enhanced catalytic activity of CuO/Cu2O hybrid nanowires for reduction of 4-nitrophenol in water. J Phys Chem Solids 136:109143

    Article  CAS  Google Scholar 

  35. Dai W, Xiong W, Yu J, Zhang S, Li B, Yang L, Wang T, Luo X, Zou J, Luo S (2020) Bi2MoO6 quantum dots in situ grown on reduced graphene oxide layers: a novel electron-rich interface for efficient CO2 reduction. ACS Appl Mater Interfaces 12:25861–25874

    Article  CAS  Google Scholar 

  36. Diao F, Tian F, Liang W, Feng H, Wang Y (2016) Mechanistical investigation on the self-enhanced photocatalytic activity of CuO/Cu2O hybrid nanostructures by density functional theory calculations. Phys Chem Chem Phys 18:27967–27975

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant No. 51602292), Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi (Grant No. 2019L0589), Natural Science Foundation of Shanxi Province (Grant Nos. 201903D421082, 201901D111170, 201901D211225) and the Natural Science Foundation of Shanxi Province for International Cooperation (Grant Nos. 201903D421082, 201901D111170).

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Correspondence to Chaorui Xue or Shengliang Hu.

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Xue, C., Li, P., Zhang, Q. et al. Fabrication of high-performance graphene oxide/CuO/Cu2O film-coated copper foam for interfacial solar-driven water evaporation. J Mater Sci 57, 3322–3336 (2022). https://doi.org/10.1007/s10853-021-06754-9

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