Overview of transient liquid phase and partial transient liquid phase bonding

Transient liquid phase (TLP) bonding is a relatively new bonding process that joins materials using an interlayer. On heating, the interlayer melts and the interlayer element (or a constituent of an alloy interlayer) diffuses into the substrate materials, causing isothermal solidification. The result of this process is a bond that has a higher melting point than the bonding temperature. This bonding process has found many applications, most notably the joining and repair of Ni-based superalloy components. This article reviews important aspects of TLP bonding, such as kinetics of the process, experimental details (bonding time, interlayer thickness and format, and optimal bonding temperature), and advantages and disadvantages of the process. A wide range of materials that TLP bonding has been applied to is also presented. Partial transient liquid phase (PTLP) bonding is a variant of TLP bonding that is typically used to join ceramics. PTLP bonding requires an interlayer composed of multiple layers; the most common bond setup consists of a thick refractory core sandwiched by thin, lower-melting layers on each side. This article explains how the experimental details and bonding kinetics of PTLP bonding differ from TLP bonding. Also, a range of materials that have been joined by PTLP bonding is presented.

Abstract Transient liquid phase (TLP) bonding is a relatively new bonding process that joins materials using an interlayer. On heating, the interlayer melts and the interlayer element (or a constituent of an alloy interlayer) diffuses into the substrate materials, causing isothermal solidification. The result of this process is a bond that has a higher melting point than the bonding temperature. This bonding process has found many applications, most notably the joining and repair of Ni-based superalloy components. This article reviews important aspects of TLP bonding, such as kinetics of the process, experimental details (bonding time, interlayer thickness and format, and optimal bonding temperature), and advantages and disadvantages of the process. A wide range of materials that TLP bonding has been applied to is also presented. Partial transient liquid phase (PTLP) bonding is a variant of TLP bonding that is typically used to join ceramics. PTLP bonding requires an interlayer composed of multiple layers; the most common bond setup consists of a thick refractory core sandwiched by thin, lower-melting layers on each side. This article explains how the experimental details and bonding kinetics of PTLP bonding differ from TLP bonding. Also, a range of materials that have been joined by PTLP bonding is presented.

Transient liquid phase (TLP) bonding
Transient liquid phase (TLP) bonding is a joining process that was developed to improve upon existing bonding technologies. Specifically, this process was patented by Paulonis et al. in 1971 [1] to overcome deficiencies of then current bonding techniques in joining Ni-based superalloys [2][3][4][5][6]. TLP bonding's main advantage is that resulting bonds have a higher melting point than the bonding temperature. This bonding process characteristically lies between diffusion bonding and brazing-for this reason, it is commonly called diffusion brazing. The process is also referred to by names such as transient insert liquid metal bonding [7] and is sometimes mistakenly referred to as diffusion bonding (which by definition relies solely on solid-state diffusion). See reference [8] for a detailed history of TLP bonding and its many names.

TLP bonding process
The TLP bonding process involves the following steps: • setting up the bond • heating to the specified bonding temperature to produce a liquid in the bond region • holding the assembly at the bonding temperature until the liquid has isothermally solidified due to diffusion • homogenizing the bond at a suitable heat-treating temperature.
A pressure is usually applied to the bonding assembly to keep the substrates aligned and to promote bonding; specific pressures are categorized in Table 1  Occasionally, the substrates are held a fixed distance apart rather than applying a pressure, but this tends to cause porosity in the final bond [6,19,43].
The bonding process is usually confined in a vacuum [3-5, 7, 12, 14-17, 20-30, 35, 38-40, 46-58, 61-63, 65, 66, 68-72, 76-83, 86-88, 93-100, 103-105, 108, 110, 112-115, 117, 119, 122-127, 130, 132-138, 140-157], although an inert atmosphere, such as argon, can be used [6,11,14,32,33,43,45,60,67,74,75,90,111,121,134,158,159]. On rare occasions, TLP bonding is performed under a different atmosphere, such as nitrogen [44], hydrogen [160], nitrogen and hydrogen [18], or open air [129]. The vacuum pressures used in the experiments referenced above are normally distributed about 0.1 lmHg (millitorr) with minimum and maximum values of 0.00015 and 34 lmHg, respectively. TLP bonding kinetics TLP bonding kinetics are generally divided into the following discrete stages [2,8,25,56,62,86,90,99,105,138,141,157,161,162] for ease of comprehending and modeling the process: • melting of the interlayer • dissolution of the substrate material • isothermal solidification • homogenization of the bond region. Figure 1 is a schematic of TLP bonding kinetics for a binary system with complete solid solubility. 1 The concentration profiles in the lower part of the figure are numbered according to the current temperature of the bond, which is shown in the phase diagram above them. The following analysis assumes that (1) the interlayer and substrate materials are pure elements (2) the bond region has a uniform temperature as it is being heated (3) the diffusion rates of liquid metals are infinite, and (4) the substrate melts back and solidifies as a plane. The second assumption is likely true since the interlayer is quite thin and generally composed of metallic elements that characteristically have moderate to high thermal conductivities. The third assumption is based on liquid diffusivity data often being orders of magnitude greater than solid diffusivity data [163]. The fourth assumption is necessary to characterize the process in one dimension.
As the bond assembly is heated, the interlayer begins to diffuse into the substrate materials (CP2). The amount of diffusion that occurs is dependent upon the interdiffusion coefficient between the substrate and interlayer materials as well as the heating rate.

Melting
Upon reaching the interlayer element's melting point (CP3), the pure portion of the interlayer liquefies (L). Heating of the bond region continues until the bonding temperature has been reached. The bonding temperature is usually well above the interlayer's melting point to ensure complete melting of the interlayer and to increase the rate of diffusion (see Optimal bonding temperature). . This causes the liquid region to melt back, or dissolve, the substrate material to conserve mass. The movement of the solid-liquid interface continues until the bonding temperature has been reached (CP5a); at this point the liquid has attained its maximum width and has consumed some of the diffused solute. The amount of melt-back is dependent upon the solidus (c 5,S ) and liquidus (c 5,L ) compositions for the given material system at the bonding temperature (see Optimal bonding temperature). The main two effects that lower melt-back distance are (1) significant diffusion of the interlayer material into the substrate before melting (see Critical interlayer thickness) and (2) loss of liquid due to wetting of the substrate's sides [44] or a high bonding pressure that squeezes liquid out [22,44,62,134,165]. Many materials that are joined by TLP bonding have carefully designed microstructures to achieve certain mechanical properties. Too much melt-back of the substrate by the liquid interlayer can have detrimental effects on the final bond in addition to lengthening the isothermal solidification time (see Critical interlayer thickness). And, in some systems melt-back can reach five to fifteen times the original interlayer thickness [43,121,146]. To prevent drastic melt-back that can adversely affect the microstructure, the interlayer should be thin [57,62], of a eutectic composition [85], or of a composition similar to the substrate material [19].

Solidification
After the liquid interlayer has reached its maximum width, the interlayer material diffuses into the substrates at a rate somewhere between the diffusivity of the liquid and solid [25,43,85,163]. As this diffusion occurs isothermally, the liquid region contracts (CP5b) to conserve mass as the solidus and liquidus concentrations are now fixed. Isothermal solidification occurs until all of the liquid has disappeared (CP5c). At this point, the TLP bonding process can be stopped if desired [71]. The bond already has an elevated remelting temperature (T 5 ) compared to the melting temperature of the interlayer (T 3 ).

Homogenization
In most cases TLP bonding is continued in order to homogenize the bond. This can be an extended time in the same heating apparatus or a post-bond heat treatment applied at some other time [14]. Furthermore, if the substrate material's microstructure is extremely sensitive, this stage can be conducted at a lower temperature [2,9]. In either case, the bond undergoes homogenization for some predetermined time which causes smoothing of the solute peak (CP5d) that remained at the end of isothermal solidification (CP5c). The resulting remelting temperature of the bond in this case is T R,P . If the peak concentration (c 5,P ) is within the room-temperature solid-solubility limit of the binary system, the precipitation of strength-reducing intermetallic compounds upon cooling will be avoided [12,110,147,150,160].
If the bond is homogenized for a sufficient amount of time, there is no gradient in the concentration profile (CP5e) and the bond's remelting temperature is even higher (T R,F ). However, despite the increases in bond remelting temperature that can be achieved by complete homogenization, an adequate homogenization time is usually determined by a sufficiently high bond strength [2,24,26,42,83,103,122,123,146,150] or economic considerations that limit furnace time [77,125,173]. Nonetheless, the bond's remelting temperature is often hundreds of degrees (°C) above the melting point of the interlayer and can be about 1000°C higher if refractory metals such as Ir, Mo, Nb, Os, Re, Ta, or W are used as the

Time frame of TLP bonding
The time frame of TLP bonding is highly dependent on the material system (e.g., phase diagram particulars, diffusion coefficients, grain size [18,25,142]) and the experimental parameters (e.g., interlayer thickness, bonding pressure, bonding temperature). The duration of each discrete stage of TLP bonding lies within the following ranges: • Heating to the bonding temperature, CP1-5a: less than a minute to about an hour; dependent on the method of heating, the heating rate of the heating apparatus, and the substrate material's thermal properties • Melting of the interlayer, CP3: less than a second [121,124,138] [73,161] or take more than a day [12] • Homogenization, CP5c-5e: hours [33,43,88,109,121] to days [88,175] or, in a few cases, minutes [73].
The general trend is that initial melting of the interlayer occurs an order of magnitude faster than melting back of the substrate, which occurs an order of magnitude faster than isothermal solidification, which occurs an order of magnitude faster than complete homogenization. Isothermal solidification ends up being the limiting, or controlling, time in producing a successful TLP bond [12,36,104,125,135,138,166,167]. While the homogenization stage takes longer if carried to completion, it rarely is. As previously stated, homogenization can be performed during a subsequent heat treatment or skipped in some cases; it can even occur once the part is in service.
The foregoing explanation of TLP bonding kinetics also applies to eutectic systems when the interlayer is a eutectic composition alloy. The kinetics are slightly different (and more importantly, TLP bonding takes much longer) for a eutectic system when pure elements are used. (See references [19,44] for particulars of eutectic system kinetics). Tuah-Poku et al. [43] reported a drastic decrease in time to isothermally solidify by changing the interlayer: 200 h when using the pure element as compared to 8 h when using the eutectic composition. This occurs because (1) the interlayer has to undergo a certain amount of solid-state diffusion with the substrate at the bonding temperature before any liquid appears and (2) melt-back of the substrate is then greater.

Critical interlayer thickness
During initial heating, the interlayer element diffuses into the substrates. The magnitude of diffusion depends upon the specific material combination, but all solid-state diffusion rates increase as the temperature rises. Depending on the heating rate and the thickness of the interlayer, the amount of diffusion can significantly decrease the interlayer's width. In fact, for a combination of high diffusion rate, slow heating, and/or thin interlayer, it is possible to diffuse all of the interlayer material into the substrate before reaching the interlayer melting point [114,173], although this is a rare occurrence. Because TLP bonding requires the formation of a bulk liquid phase [9,109,114] to create a consolidated, void-free bond while also increasing diffusion rates, the interlayer must exceed a minimum, or critical, thickness [105,114].
In addition to the parameters listed above, the critical interlayer thickness has been shown to depend on other variables such as applied clamping force, solid/liquid surface tension, surface roughness of the substrate, and intermetallic formation [18,94,114]. In short, experiments must be conducted for each material combination to empirically reveal its critical interlayer thickness.

Optimal bonding temperature
The bonding temperature is sometimes completely limited by the microstructural stability of the substrate material [7,9,87,125]. If, however, the substrate material allows flexibility in selecting an optimized bonding temperature, a minimum isothermal solidification time (and therefore bonding time) can be achieved at a certain temperature.
If phase diagram and diffusion data are available for the material system in question, the isothermal solidification time can be characterized with respect to temperature. However, it is usually the case that experiments are the only way to discover this relationship. In general, the relationship is parabolic, yielding a minimum isothermal solidification time at a given intermediate temperature (between the melting points of the interlayer and substrate materials) [9,18,43,50,78,79,159,162]. And yet, in J Mater Sci (2011) 46:5305-5323 5309 some cases the variables of the system yield either (1) a monotonically increasing time, in which case the optimal bonding temperature is just above the interlayer's melting point, [6,9,43,114,158,162] or (2) a monotonically decreasing time, in which case the optimal bonding temperature is as high as the substrate material allows [4,104,114,135,141]. The behavior of this trend is highly system dependent and results in part from the interplay of the diffusion rate and the phase diagram of the system [19,43,50]. As the temperature is increased, the rate of diffusion increases exponentially. In addition, intermetallic regions, which tend to slow down the rate of diffusion [60,110], can often be avoided by raising the temperature. As shown in Fig. 2, Pb diffusing into Pd at 400°C (T 1 ) would pass through five intermetallic regions. T 2 and T 3 are ideal temperatures for passing through just two and one intermetallic regions, respectively. T 4 completely avoids the intermetallic regions while still providing a wide solubility range for the liquid to solidify.
In addition to intermetallics, the shape of the solidus and liquidus lines plays an important role in TLP bonding kinetics and the optimal bonding temperature. Figure 3 demonstrates extremes of solidus and liquidus lines in a binary system with complete solid solubility. The composition profiles below each set of phase diagrams demonstrate the initial melting and isothermal solidification behavior of the interlayer for each case. It is assumed that all four systems (1) have the same diffusion coefficient and (2) are heated instantaneously. The latter assumption is accurate for many material systems since complete meltback often consumes much of the solute that has diffused into the substrate (see CP5a in Fig. 1). The top concentration profiles illustrate initial melt-back of a pure interlayer-the dotted line is the initial interlayer and the solid line is the molten interlayer. The bottom concentration profiles illustrate isothermal solidification for all four systems after a set time.
The partition coefficient (k) is included in the diagram and is defined as: where c S and c L are the solidus and liquidus compositions of the interlayer element. Systems a and b in Fig. 3 have the same convex-shaped liquidus line and therefore experience the same amount of melt-back (see the top concentration profiles). The same is true for the concave-shaped liquidus line in systems c and d. Systems a and c have the same partition coefficient (0.9). The same is true for systems b and d (0.4).
A few principles of TLP bonding kinetics can be gleaned from this figure. First, the convex-shaped liquidus line (a and b) prevents melt-back from occurring to a large extent, whereas the concave-shaped liquidus line (c and d) causes much more melt-back. Second, isothermal Fig. 2 Pb-Pd binary system [177] illustrating bonding temperatures (dotted lines) that avoid intermetallic regions solidification occurs faster in systems with a higher partition coefficient (a and c). To conserve mass, the volume of solidified liquid is equal to the change in the concentration profile of the solid region. The width of isothermal solidification in an arbitrary time period is equal to the ratio of this volume to the difference between the liquidus and solidus compositions, or, written another way: Although systems a and c have the same partition coefficient, because the liquidus and solidus compositions of system c are closer to zero, they are also closer to each other, causing isothermal solidification to occur slightly faster (see Fig. 3). If the substrate material has a sensitive microstructure that could be damaged by significant melt-back, then phase diagrams such as systems c and d should be avoided. Systems b and d will take much longer to isothermally solidify, raising operating costs.
Systems a and c are quite similar in rate of isothermal solidification. Because the solidus composition of system c is closer to the completely homogenized composition (shown as an x on the gray line), homogenization of the solute peak after isothermal solidification will likely proceed more rapidly than in system a. However, because the solidus line of system a has a convex shape, increases in bond remelting temperature due to homogenization will likely occur faster and be larger in this system.

Modeling of TLP bonding
Analytical models have been developed by many researchers for the four stages of TLP bonding to provide quick estimates or general trends, such as those illustrated in the previous section. Equations for and descriptions of TLP bonding analytical models are included in references [8,19,162,178]. Assumptions made for these models are similar to those made in this article (see TLP bonding kinetics). In some cases these equations provide good results, but for many systems these simplified, binarysystem approaches do not supply accurate estimates [5,8,38,78,79,86]. This is due in part to the diffusion coefficients being assumed independent of composition.
Some complexities of TLP bonding are quite difficult to model. For example, grain boundaries can cause isothermal solidification to occur at a different rate than that predicted by analytical models using a bulk diffusion coefficient [25,36,37]. Indeed, grain boundary diffusion is faster than bulk diffusion in a certain temperature range (based on the alloy's melting point) [173]. Grain boundary diffusion rates also increase as the substrate material's grain size decreases [179]. Further, grain boundaries can be penetrated by the liquid to cause a non-planar solidification front, thereby increasing the area over which diffusion occurs [5,11,18,138]. See references [180,181] for more information on the effect of grain boundaries in TLP bonding. Another interesting deviation is that isothermal solidification can occur in two different ''regimes'' [38,50,138]. The faster solute element of a multi-component interlayer controls the rate of solidification for the first regime. Then, a second solute element controls the rate of solidification during the second regime, resulting in complex concentration-time profiles.
Numerical models can account for some of the complexities of TLP bonding to accurately predict bonding kinetics [7,8,161,162,168,173,176,179,182,183] and can even be extended to multi-component systems [174,184]. Despite the complexities and extra time required in numerical modeling, especially for multi-component systems, the limiting factor is most often the lack of necessary diffusion data [7,8,178]. But, when the necessary data is available, modeling of TLP bonding can drastically reduce the number of experiments required to determine optimal bonding parameters [37,162,166].

Advantages and disadvantages of TLP bonding
The most distinctive advantage of TLP bonding is that the resulting bond can operate at the bonding temperature or higher temperatures. In other words, materials can be bonded at a temperature equal to or lower than what the assembled part will experience in service. This is especially important for temperature-sensitive materials whose microstructures can be damaged by too much thermal energy input [117] and therefore need to be joined at lower temperatures.
For some material systems, bond properties and performance capabilities that are difficult or impractical to achieve using conventional joining methods are more accessible [189].
However, TLP bonding is a specialized bonding technique that can be time-consuming and expensive compared to other joining methods-the time required for isothermal solidification and sufficient bond homogenization can be unfeasibly long and/or uneconomical [36,37,104,141]. TLP bonding is not always suitable, specifically in the following cases: • significant melt-back of a material with a specifically designed microstructure [7,62,141] • the formation of a thick layer of intermetallic compounds in the bond that tend to lower its strength and ductility [9,36,87,110,141,146,157,158,167] • the segregation of particles in metal matrix composites at the joint centerline, leaving a distinct weakened band in the joint microstructure [19,33,39,42,54,105].
See reference [7] for examples of specific difficulties that occur in TLP bonding applications. Although many disadvantages of TLP bonding can be overcome by optimized bonding parameters, the optimization process often requires much experimentation.

Variants of TLP bonding
A few variants of TLP bonding also exist: • Temperature gradient TLP bonding: the application of a temperature gradient causes a non-planar bond interface which tends to result in stronger bonds [8,21,164,186,194] • Wide-gap TLP bonding: gaps of 100-500 lm can be bonded or repaired by the use of a melting and a nonmelting constituent (multiple layers or mixed powders) [7, 16, 57, 92, 94-96, 100, 101, 136, 149, 173, 195]. This technique can also be used in conventional TLP bonding to accelerate isothermal solidification [13,99,140] • Active TLP bonding: a ceramic and metal can be joined by a multi-component interlayer; at least one constituent reacts with the ceramic while another diffuses into the metal to cause isothermal solidification [28,42,52,54,116,132,196] • Partial TLP bonding (see next section).
Bonds made using temperature gradient, wide-gap, and active TLP bonding have been included in Table 3.

Partial transient liquid phase (PTLP) bonding
Partial transient liquid phase (PTLP) bonding is a variant of TLP bonding mainly used to join ceramics. PTLP bonding overlaps both wide-gap and active TLP bonding, although articles defining PTLP bonding predate the other two techniques by a few years. Many advantages of conventional TLP bonding carry over to PTLP bonding [188]. The ensuing sections focus on how PTLP bonding differs from TLP bonding.

PTLP bonding process
In PTLP bonding, the interlayer consists of thin layers of low-melting-point metals or alloys on each side of a much thicker refractory metal or alloy layer [188,[200][201][202][203]. Figure 4 presents a general, three-layer PTLP bond setup. (In some cases, there can be multiple thin layers on each side of the refractory core (see Table 4), but the general principles of the process remain the same.) Upon heating to the bonding temperature, a liquid is formed (through melting or a eutectic reaction with the refractory core [202][203][204][205][206]) by each thin layer. The liquid that is formed wets each ceramic substrate while concomitantly diffusing into the solid refractory core. As in TLP bonding, the liquid regions solidify isothermally and homogenization of the entire bond region leads to a refractory bond.

PTLP bonding kinetics
Figures 5 and 6 depict the two ends of the PTLP bonding process. The following additional assumptions are made in this analysis: (1) thin layer A (tl A ), the refractory core (rc), and thin layer B (tl B ) are different pure elements (2) there is no diffusion into the ceramic substrates (3) the ternary system (tl A -rc-tl B ) can be approximated by the two associated binary systems (tl A -rc and rc-tl B ), and (4) the interlayers wet the substrate with a thin layer of intermetallic formation that conserves the amount of liquid and results in a refractory intermetallic.
The PTLP bonding setup at room temperature is shown in Figs. 5 and 6 as concentration profiles 1 A and 1 B , CP1 A and CP1 B , respectively. Both binary systems exhibit complete solid solubility. As the temperature of the bond is raised to the melting points of each thin layer (T 4 for tl A  . Despite the small amount of liquid that initially forms from tl B due to its high diffusivity (CP3 B ), the liquid drastically melts back the rc on further heating (CP4 B ) due to the concave shape of the liquidus. This melt-back continues until the assembly is heated to the bonding temperature (T 5 ) shown in CP5a B .
On the other hand, the liquid formed from tl A (CP4 A ) widens slightly to be about the same width as the original thin layer (CP5a A ) due to that system's convex liquidus. At this point, isothermal solidification occurs on both sides of the multi-layer interlayer. It proceeds much faster for tl B due to its high partition coefficient and diffusivity. In fact, isothermal solidification is complete for tl B (CP5b B ) when the other liquid region has only solidified about halfway (CP5b A ), despite the considerable melt-back of the rc.
The liquid formed from tl A eventually solidifies isothermally (CP5c A ). On the other side of the bond, the solute peak has been smoothed due to homogenization (CP5c B ), and the remelting temperature on that side has increased to T R,P .
Further homogenization causes the remaining gradient in the tl B element to disappear (CP5d B ), thereby raising the  remelting temperature of the bond next to substrate B to its final value, T R,F . A similar melting temperature increase (to T R,P1 ) simultaneously occurs on the other side of the bond due to smoothing of its solute peak (CP5d A ). Prolonging the homogenization process continues to raise the remelting temperature of the left side of the bond. However, once its remelting temperature has reached T R,P2 (CP5e A ), which is higher than T R,F for the right side of the bond, further homogenization will have little effect on raising the bond's remelting temperature. From an optimization standpoint, homogenization should be stopped at this time. However, real-world considerations usually determine the homogenization time, which can be less than-or greater than-the optimized time due to various factors, such as cost, microstructural considerations, or resulting bond strength.
The time frame of PTLP bonding is very similar to that of TLP bonding. Isothermal solidification and homogenization times for TLP bonding depend on high-diffusivity elements diffusing into ''infinite'' substrate materials. In PTLP bonding, the elements tend to have lower diffusivities, but the maximum diffusion path is on the order of 100 lm, resulting in similar bonding times.

Advantages and disadvantages of PTLP bonding
The ''self-contained'' [215] nature of the PTLP bonding multi-layer interlayer provides benefits and impediments. Specific advantages include the following: • the dual nature of the multi-layer interlayer combines some beneficial properties of brazing and diffusion  bonding [117,188,204,206,208,215] and provides some flexibility in joint design • lower bonding temperatures can mitigate thermally induced stresses [188,214] and limit or avoid deleterious intermetallic reactions [188,207] • because diffusion occurs on a smaller scale (on the order of 100 lm), bonding using slow-diffusing elements occurs in a reasonable amount of time.
Major disadvantages are: • the liquid interlayer must wet the ceramic [117,143,215] • matching the thermal expansion coefficients of the ceramic substrates and metallic interlayer elements is sometimes necessary to prevent thermally induced stresses and cracking [117,143,188,196,203,215] • intermetallic formation is necessary, but a thick reaction layer tends to be brittle and can degrade joint strength [143,200,202,203,210,215].
However, most disadvantages of PTLP bonding can be overcome by proper design. In the end, the limiting factor is wettability on the specific ceramic material.
Applications of PTLP bonding PTLP bonding has been used to successfully join some ceramic and composite materials. Table 4 presents a spectrum of PTLP bonds as of now, including bonds of dissimilar materials. The interlayer combination of the general PTLP bond setup shown in Fig. 4 would be notated tl A | rc | tl B . Summary TLP bonding is a relatively new bonding process that results in a bond with a higher melting temperature than that used to join the materials. Specific details of this process, including experimental details, process kinetics, and optimal bonding temperature, have been outlined in this article. Also, the broad range of materials that have been joined by TLP bonding was presented. PTLP bonding, a more recent variant of TLP bonding used to bond hard-to-join materials, was also outlined. PTLP bonding has been successful in joining a smaller range of materials, most notably, ceramics.
Both TLP and PTLP bonding are specialized joining processes that require more resources to implement compared to typical bonding processes. However, in some cases these bonding processes are the best-or only-way to join materials for specialized applications.