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Explore the electrochemical performance of a novel metal copper–sodium battery

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Abstract

Exploring novel metal-metal batteries with a facile manufacturing process and low production cost is crucial for the development of next-generation energy storage systems. In this work, the electrochemical performance of a novel Cu–Na battery with Cu foil as a cathode and Na foil as an anode is explored for the first time. The Cu–Na battery exhibits good electrochemical reaction reversibility and cycling stability, which delivers a Coulombic efficiency of 61.5% under a charge capacity limitation of 0.02 mA h cm− 2 with a current density of 0.01 mA cm− 2 after 50 cycles. EIS analysis reveals that the Cu–Na battery maintains a stable electrochemical reaction resistance upon repeated cycles. The present work demonstrates that this Cu–Na battery could be a promising candidate for the next-generation energy storage system.

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References

  1. H. Wang, Y. Sun, M. Li, G. Li, K. Xue, Z. Chen, D. Yu (2020) Engineering solvation complex-membrane interaction to suppress cation crossover in 3 V Cu-Al battery. Small. 16: e2003438. https://doi.org/10.1002/smll.202003438

    Article  CAS  PubMed  Google Scholar 

  2. J. Yao, Y. Li, R.C. Massé, E. Uchaker, G. Cao (2018) Revitalized interest in vanadium pentoxide as cathode material for lithium-ion batteries and beyond. Energy Storage. Mater. 11 205–259. https://doi.org/10.1016/j.ensm.2017.10.014

    Article  Google Scholar 

  3. H. Wang, K. Xue, B. Su, D. Yu (2021) Achieving reversible Cu-Al batteries by reducing self-discharge and side reactions. Electrochim. Acta. 388: 138595. https://doi.org/10.1016/j.electacta.2021.138595

    Article  CAS  Google Scholar 

  4. H. Wang, D. Yu (2019) 3 V Cu-Al rechargeable battery enabled by highly concentrated aprotic electrolyte. ACS Appl. Energy Mater. 2: 4936–4942. https://doi.org/10.1021/acsaem.9b00627

    Article  CAS  Google Scholar 

  5. K. Xue, Y. Zhao, P. Lee, D. Yu (2022) Poly(ionic liquid) as an anion exchan-ge membrane for a 3.3 V copper-lithium battery. Energy Environ. Mater. https://doi.org/10.1002/eem2.12395

    Article  Google Scholar 

  6. H. Wang, C. Wang, M. Zheng, J. Liang, M. Yang, X. Feng, X. Ren, D. Yu, Y. Li, X. Sun (2023) A shuttle-free solid-state Cu-Li battery based on a sandwich- structured electrolyte. Angew. Chem., Int. Ed. 135: e202214117 https://doi.org/10.1002/anie.202214117

    Article  CAS  Google Scholar 

  7. C. Vaalma, D. Buchholz, M. Weil, S. Passerini (2018) A cost and resource analysis of sodium-ion batteries. Nat. Rev. Mater. 3: 4. https://doi.org/10.1038/natrevmats.2018.13

    Article  Google Scholar 

  8. H. Lin, Z. Zhang, Y. Wang, X. Zhang, Z. Tie, Z. Jin (2021) Template-sacrificed hot fusion construction and nanoseed modification of 3D porous copper nanoscaffold host for stable-cycling lithium metal anodes. Adv. Funct. Mater. 31: 2102735. https://doi.org/10.1002/adfm.202102735

    Article  CAS  Google Scholar 

  9. H. Wang, D. Yu (2019) Stainless steel as low-cost high-voltage cathode via stripping/deposition in metal-lithium battery. Electrochim. Acta. 298: 186–193. https://doi.org/10.1016/j.electacta.2018.12.064

    Article  CAS  Google Scholar 

  10. Y. Li, W. Xu, T. Sun, J. Yao (2023) Preparation and sodium storage performance of 2D bilayered V2O5⋅nH2O nanomaterial with Zn2+ intercalation. J. Electroanal. Chem. 937: 117416. https://doi.org/10.1016/j.jelechem.2023.117416

    Article  CAS  Google Scholar 

  11. W. Xu, Y. Li, J. Yao, Q. Zhu, B. Liu (2022) Lithium storage behavior and mechanism of hexagonal FePO4/C composite as a novel anode material for lithium-ion batteries. J. Alloy. Compd. 933: 167766. https://doi.org/10.1016/j.jallcom.2022.167766

    Article  CAS  Google Scholar 

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Acknowledgements

This work is supported by the Guangxi Natural Science Foundation of China (2015GXNSFGA139006).

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WX: Investigation, Writing – original draft. YL: Conceptualization, Methodology, Writing – review & editing. JY: Conceptualization, Methodology, Writing – review & editing. JJ: Helped to discuss partial experimental data. QZ: Helped to discuss partial experimental data. All authors reviewed the manuscript.

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Correspondence to Yanwei Li or Jinhuan Yao.

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The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

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Xu, W., Li, Y., Yao, J. et al. Explore the electrochemical performance of a novel metal copper–sodium battery. J Appl Electrochem 53, 1953–1957 (2023). https://doi.org/10.1007/s10800-023-01904-0

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