Modification of polycaproamide by 1H,1H,13H-trihydroperfluorotridecan-1-ol immobilized on montmorillonite produced an F-containing polymer composite. The structure of the resulting composite was investigated using x-ray structure analysis and solid-state 19F NMR spectroscopy. The polymorphous composition of this heterochain polymer was shown to reorganize to enhance its thermal stability and diminish its flammability. Possible mechanisms for the stabilizing effect of the used modifier that were related to the involvement of organo-clay paramagnetic centers in the binding of macroradicals formed during thermal decomposition of macromolecular chains were discussed.
Similar content being viewed by others
References
B. Ameduri, H. Sawada, and T. Narita, Fluorinated Polymers. Vol. 1: Synthesis, Properties, Processing and Simulation (RSC Polymer Chemistry), Royal Society of Chemistry, RSC Publishing, 2016, 439 pp.
B. Ameduri, H. Sawada, and T. Narita, Fluorinated Polymers. Vol. 2: Applications (Polymer Chemistry Series) (RSC Polymer Chemistry), Royal Society of Chemistry, RSC Publishing, 2016, 396 pp.
S. V. Kudashev, Fluorine Notes, No. 3 (130), 60 (2020); http://ru.notes.fluorine1.ru/journals/by_issue/130.
I. A. Novakov, N. A. Rakhimova, et al., Zh. Prikl. Khim., 82, No. 1, 160-164 (2009).
S. V. Kudashev, Ya. V. Zubavichus, et al., Trenie Iznos, 34, No. 5, 524-529 (2013).
S. V. Kudashev, I. A. Zvereva, et al., Zh. Prikl. Khim., 93, No. 6, 844-851 (2020).
S. V. Kudashev, V. M. Shapovalov, et al., Khim. Volokna, No. 5, 22-25 (2019).
S. V. Kudashev, Yu. M. Shul2ga, and V. P. Medvedev, Kauch. Rezina, 78, No. 5, 296-300 (2019).
N. A. Rakhimova and S. V. Kudashev, Zh. Prikl. Khim., 83, No. 11, 1905-1910 (2010).
B. L. Deopura, R. Alagirusamy, et al., Polyesters and Polyamides, Woodhead Publ., 2008, 632 pp.
Y. Mai, in: Polymer Nanocomposites, Y. Mai and Z. Yu (eds.), Woodhead, Cambridge, 2006, 594 pp.
L. A. Utracki, Clay-Containing Nanocomposites, Vols. 1 and 2, Rapra Technol. Ltd, UK, 2004.
V. N. Aderikha, A. P. Krasnov, and V. A. Shapovalov, Polim. Mater. Tekhnol., 2, No. 1, 54-60 (2016).
D. M. Lincoln, R. A. Vaia, and R. Krishnamoorti, Macromolecules, 37, 4554-4561 (2004).
D. Tabuani, J. Polym. Sci., Part B: Polym. Phys., 47, 1935-1948 (2009).
W. R. Dolbier, Jr., Guide to Fluorine NMR for Organic Chemists, 2nd ed., John Wiley & Sons, Inc., Hoboken,
V. M. Buznik, S. P. Gabuda, et al., J. Struct. Chem., 44, No. 6, 1067-1070 (2003).
A. J. Vega and A. D. English, Macromolecules, 13, No. 6, 1635-1647 (1980).
J. Zhu, F. M. Uhl, et al., Chem. Mater., 13, 4649-4654 (2001).
D. H. Solomon, Clays Clay Miner., 16, 31-39 (1968).
S. V. Kudashev, N. A. Zhuravlev, et al., Khim. Volokna, No. 1, 10-14 (2019).
S. V. Kudashev, V. A. Babkin, et al., Fluorine Notes, 6, No. 133, 7 (2020); http://en.notes.fluorine1.ru/journals/by_issue/133.
A. A. Granovsky, Firefly, ver. 8; http://classic.chem.msu.su/gran/firefly/index.html.
M. W. Schmidt, K. K. Baldridge, et al., J. Comput. Chem., 14, 1347-1363 (1993).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Khimicheskie Volokna, No. 5, pp. 3-7, September—October, 2021.
Rights and permissions
About this article
Cite this article
Kudashev, S.V., Kondrasenko, A.A., Maiulev, A.N. et al. Modification of Polycaproamide Composites Based on 1H,1H,13H-rihydroperfluorotridecan-1-ol and Montmorillonite. Fibre Chem 53, 291–295 (2022). https://doi.org/10.1007/s10692-022-10287-5
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10692-022-10287-5