Abstract
Advanced oxidation processes (AOPs) are an effective choice for removal of reactive azo dyes used in the textile industry due to high solubility and low degradability. Within the scope of this study, reactive orange 122 (RO122) azo dye was removed using the UV-based AOPs of ultraviolet (UV) radiation, UV/hydrogen peroxide (UV/H2O2), UV/persulfate (UV/S2O82−), and UV/peroxymonosulfate (UV/HSO5−). Oxidant concentration, initial solution pH, initial RO122 concentration, different anions (Cl−, NO3− and SO42−), and solution temperature effects were compared. With only UV radiation (254 nm), 19.5% RO122 removal occurred at the end of 120 min. The RO122 removal reduced with the UV/oxidant processes at pH 9. Experimental results revealed RO122 removal followed pseudo-first-order (PFO) kinetics. There was a linear correlation identified between initial oxidant concentration and the PFO kinetic rate constant (k1). Among the three UV-based processes, with oxidant concentration 50 mg/L, temperature 20 °C, and pH 5, RO122 removal efficiency was in the order UV/H2O2 > UV/HSO5− > UV/S2O82−. RO122 removal rate increased as initial oxidant concentration and temperature increased and reduced as initial RO122 concentration increased. Energy requirements and oxidant costs were assessed. The UV/H2O2 process was concluded to be the most efficient and economic process for RO122 removal.
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References
Adar, E. (2021). Removal of acid yellow 17 from textile wastewater by adsorption and heterogeneous persulfate oxidation. International Journal of Environmental Science and Technology, 18(2), 483–498. https://doi.org/10.1007/s13762-020-02986-5
Alaton, I. A., Balcioglu, I. A., & Bahnemann, D. W. (2002). Advanced oxidation of a reactive dyebath effluent: Comparison of O3, H2O2/UV-C and TiO2/UV-A processes. Water Research, 36(5), 1143–1154. https://doi.org/10.1016/S0043-1354(01)00335-9
Ao, X., & Liu, W. (2017). Degradation of sulfamethoxazole by medium pressure UV and oxidants: Peroxymonosulfate, persulfate, and hydrogen peroxide. Chemical Engineering Journal, 313, 629–637. https://doi.org/10.1016/j.cej.2016.12.089
Azam, A., & Hamid, A. (2006). Effects of gap size and UV dosage on decolorization of C.I. Acid Orange 7 by UV/H2O2 process. Journal of Hazardous Materials, 133(1–3), 167–171. https://doi.org/10.1016/j.jhazmat.2005.10.005
Bakht Shokouhi, S., Dehghanzadeh, R., Aslani, H., & Shahmahdi, N. (2020). Activated carbon catalyzed ozonation (ACCO) of Reactive Blue 194 azo dye in aqueous saline solution: Experimental parameters, kinetic and analysis of activated carbon properties. Journal of Water Process Engineering, 35, 101188. https://doi.org/10.1016/j.jwpe.2020.101188
Balapure, K., Bhatt, N., & Madamwar, D. (2015). Mineralization of reactive azo dyes present in simulated textile waste water using down flow microaerophilic fixed film bioreactor. Bioresource Technology, 175, 1–7. https://doi.org/10.1016/j.biortech.2014.10.040
Beltrán, F. J., González, M., & González, J. F. (1997). Industrial wastewater advanced oxidation. Part 1. UV radiation in the presence and absence of hydrogen peroxide. Water Research, 31(10), 2405–2414. https://doi.org/10.1016/S0043-1354(97)00077-8
Blackburn, R. S. (2004). Natural polysaccharides and their interactions with dye molecules: Applications in effluent treatment. Environmental Science and Technology, 38(18), 4905–4909. https://doi.org/10.1021/es049972n
Bolton, J. R., Bircher, K. G., Tumas, W., & Tolman, C. A. (2001). Figures-of-merit for the technical development and application of advanced oxidation technologies for both electric- and solar-driven systems. Pure and Applied Chemistry, 73(4), 627–637. https://doi.org/10.1351/pac200173040627
Bolton, J. R., Stefan, M. I., Shaw, P.-S., & Lykke, K. R. (2011). Determination of the quantum yields of the potassium ferrioxalate and potassium iodide–iodate actinometers and a method for the calibration of radiometer detectors. Journal of Photochemistry and Photobiology a: Chemistry, 222(1), 166–169. https://doi.org/10.1016/j.jphotochem.2011.05.017
Cai, A., Deng, J., Zhu, T., Ye, C., Li, J., Zhou, S., Li, Q., & Li, X. (2021). Enhanced oxidation of carbamazepine by UV-LED/persulfate and UV-LED/H2O2 processes in the presence of trace copper ions. Chemical Engineering Journal, 404, 127119. https://doi.org/10.1016/j.cej.2020.127119
Cao, J., Sanganyado, E., Liu, W., Zhang, W., & Liu, Y. (2019). Decolorization and detoxification of Direct Blue 2B by indigenous bacterial consortium. Journal of Environmental Management, 242, 229–237. https://doi.org/10.1016/j.jenvman.2019.04.067
Chen, L., Cai, T., Cheng, C., Xiong, Z., & Ding, D. (2018). Degradation of acetamiprid in UV/H2O2 and UV/persulfate systems: A comparative study. Chemical Engineering Journal, 351, 1137–1146. https://doi.org/10.1016/j.cej.2018.06.107
Cui, M. H., Cui, D., Liang, B., Sangeetha, T., Wang, A. J., & Cheng, H. Y. (2016). Decolorization enhancement by optimizing azo dye loading rate in an anaerobic reactor. RSC Advances, 6, 49995–50001. https://doi.org/10.1039/c6ra04665g
De Gisi, S., & Notarnicola, M. (2017). Industrial Wastewater Treatment. In Abraham, M. A., Encyclopedia of Sustainable Technologies (pp. 23–42). Elsevier. https://doi.org/10.1016/B978-0-12-409548-9.10167-8
Değermenci, G. D. (2021). Removal of reactive azo dye using platinum-coated titanium electrodes with the electro-oxidation process. Desalination and Water Treatment, 218, 436–443. https://doi.org/10.5004/dwt.2021.26981
Deng, J., Shao, Y., Gao, N., Xia, S., Tan, C., Zhou, S., & Hu, X. (2013). Degradation of the antiepileptic drug carbamazepine upon different UV-based advanced oxidation processes in water. Chemical Engineering Journal, 222, 150–158. https://doi.org/10.1016/j.cej.2013.02.045
Devi, P., Das, U., & Dalai, A. K. (2016). In-situ chemical oxidation: Principle and applications of peroxide and persulfate treatments in wastewater systems. Science of the Total Environment, 571, 643–657. https://doi.org/10.1016/j.scitotenv.2016.07.032
Dhaka, S., Kumar, R., Lee, S., & hun, Kurade, M. B., & Jeon, B. H. (2018). Degradation of ethyl paraben in aqueous medium using advanced oxidation processes: Efficiency evaluation of UV-C supported oxidants. Journal of Cleaner Production, 180, 505–513. https://doi.org/10.1016/j.jclepro.2018.01.197
Ding, D., Liu, C., Ji, Y., Yang, Q., Chen, L., Jiang, C., & Cai, T. (2017). Mechanism insight of degradation of norfloxacin by magnetite nanoparticles activated persulfate: Identification of radicals and degradation pathway. Chemical Engineering Journal, 308, 330–339. https://doi.org/10.1016/j.cej.2016.09.077
Ding, X., Gutierrez, L., Croue, J. P., Li, M., Wang, L., & Wang, Y. (2020). Hydroxyl and sulfate radical-based oxidation of RhB dye in UV/H2O2 and UV/persulfate systems: Kinetics, mechanisms, and comparison. Chemosphere, 253, 126655. https://doi.org/10.1016/j.chemosphere.2020.126655
Dionysiou, D. D., Suidan, M. T., Baudin, I., & Laîné, J. M. (2004). Effect of hydrogen peroxide on the destruction of organic contaminants-synergism and inhibition in a continuous-mode photocatalytic reactor. Applied Catalysis b: Environmental, 50(4), 259–269. https://doi.org/10.1016/j.apcatb.2004.01.022
Ferreira, S. A. D., Donadia, J. F., Gonçalves, G. R., Teixeira, A. L., Freitas, M. B. J. G., Fernandes, A. A. R., & Lelis, M. F. F. (2019). Photocatalytic performance of granite waste in the decolorization and degradation of Reactive Orange 122. Journal of Environmental Chemical Engineering, 7(3), 103144. https://doi.org/10.1016/j.jece.2019.103144
Franca, R. D. G., Vieira, A., Carvalho, G., Oehmen, A., Pinheiro, H. M., Crespo, M. T. B., & Lourenco, N. D. (2020). Oerskovia paurometabola can efficiently decolorize azo dye Acid Red 14 and remove its recalcitrant metabolite. Ecotoxicology and Environmental Safety, 191, 110007. https://doi.org/10.1016/j.ecoenv.2019.110007
Ganesh, R., Boardman, G. D., & Michelsen, D. (1994). Fate of azo dyes in sludges. Water Research, 28(6), 1367–1376. https://doi.org/10.1016/0043-1354(94)90303-4
Gao, N., & yun, Deng, Y., & Zhao, D. (2009). Ametryn degradation in the ultraviolet (UV) irradiation/hydrogen peroxide (H2O2) treatment. Journal of Hazardous Materials, 164(2–3), 640–645. https://doi.org/10.1016/j.jhazmat.2008.08.038
Guo, H. X., Lin, K. L., Zheng, Z. S., Xiao, F. B., & Li, S. X. (2012). Sulfanilic acid-modified P25 TiO2 nanoparticles with improved photocatalytic degradation on Congo red under visible light. Dyes and Pigments, 92(3), 1278–1284. https://doi.org/10.1016/j.dyepig.2011.09.004
He, X., Mezyk, S. P., Michael, I., Fatta-Kassinos, D., & Dionysiou, D. D. (2014). Degradation kinetics and mechanism of β-lactam antibiotics by the activation of H2O2 and Na2S2O8 under UV-254 nm irradiation. Journal of Hazardous Materials, 279, 375–383. https://doi.org/10.1016/j.jhazmat.2014.07.008
Hu, X., Wang, X., Ban, Y., & Ren, B. (2011). A comparative study of UV-Fenton, UV-H2O2 and Fenton reaction treatment of landfill leachate. Environmental Technology, 32(9), 945–951. https://doi.org/10.1080/09593330.2010.521953
Kausar, A., Shahzad, R., Asim, S., BiBi, S., Iqbal, J., Muhammad, N., Sillanpaa, M., & Din, I. U. (2021). Experimental and theoretical studies of Rhodamine B direct dye sorption onto clay-cellulose composite. Journal of Molecular Liquids, 328, 115165. https://doi.org/10.1016/j.molliq.2020.115165
Kermani, M., Farzadkia, M., Morovati, M., Taghavi, M., Fallahizadeh, S., Khaksefidi, R., & Norzaee, S. (2020). Degradation of furfural in aqueous solution using activated persulfate and peroxymonosulfate by ultrasound irradiation. Journal of Environmental Management, 266, 110616. https://doi.org/10.1016/j.jenvman.2020.110616
Khan, J. A., He, X., Shah, N. S., Khan, H. M., Hapeshi, E., Fatta-Kassinos, D., & Dionysiou, D. D. (2014). Kinetic and mechanism investigation on the photochemical degradation of atrazine with activated H2O2, S2O82- and HSO5-. Chemical Engineering Journal, 252, 393–403. https://doi.org/10.1016/j.cej.2014.04.104
Kishor, R., Purchase, D., Saratale, G. D., Ferreira, L. F. R., Bilal, M., Iqbal, H. M. N., & Bharagava, R. N. (2021). Environment friendly degradation and detoxification of Congo red dye and textile industry wastewater by a newly isolated Bacillus cohnni (MW406977). Environmental Technology & Innovation, 22, 101425. https://doi.org/10.1016/j.eti.2021.101425
Klavarioti, M., Mantzavinos, D., & Kassinos, D. (2009). Removal of residual pharmaceuticals from aqueous systems by advanced oxidation processes. Environment International, 35(2), 402–417. https://doi.org/10.1016/j.envint.2008.07.009
Kolthoff, I. M., & Miller, I. K. (1951). The Chemistry of Persulfate. I. The Kinetics and Mechanism of the Decomposition of the Persulfate Ion in Aqueous Medium. Journal of the American Chemical Society, 73(7), 3055–3059. https://doi.org/10.1021/ja01151a024
Lee, Y. M., Lee, G., & Zoh, K. D. (2021). Benzophenone-3 degradation via UV/H2O2 and UV/persulfate reactions. Journal of Hazardous Materials, 403, 123591. https://doi.org/10.1016/j.jhazmat.2020.123591
Lei, Y., Lu, J., Zhu, M., Xie, J., Peng, S., & Zhu, C. (2020). Radical chemistry of diethyl phthalate oxidation via UV/peroxymonosulfate process: Roles of primary and secondary radicals. Chemical Engineering Journal, 379, 122339. https://doi.org/10.1016/j.cej.2019.122339
Li, W., Jain, T., Ishida, K., & Liu, H. (2017). A mechanistic understanding of the degradation of trace organic contaminants by UV/hydrogen peroxide, UV/persulfate and UV/free chlorine for water reuse. Environmental Science: Water Research and Technology, 3, 128–138. https://doi.org/10.1039/c6ew00242k
Liang, C., Wang, Z. S., & Bruell, C. J. (2007). Influence of pH on persulfate oxidation of TCE at ambient temperatures. Chemosphere, 66(1), 106–113. https://doi.org/10.1016/j.chemosphere.2006.05.026
Liu, X., Liu, Y., Lu, S., Wang, Z., Wang, Y., Zhang, G., Guo, X., Guo, W., Zhang, T., & Xi, B. (2020). Degradation difference of ofloxacin and levofloxacin by UV/H2O2 and UV/PS (persulfate): Efficiency, factors and mechanism. Chemical Engineering Journal, 385, 123987. https://doi.org/10.1016/j.cej.2019.123987
Liu, Y., He, X., Fu, Y., & Dionysiou, D. D. (2016). Degradation kinetics and mechanism of oxytetracycline by hydroxyl radical-based advanced oxidation processes. Chemical Engineering Journal, 284, 1317–1327. https://doi.org/10.1016/j.cej.2015.09.034
Mahmoud, M. E., Khalifa, M. A., El-Mallah, N. M., Hassouba, H. M., & Nabil, G. M. (2021). Performance of MnO2 nanoparticles-coated cationic CTAB for detoxification and decolorization of sulfonated remazol red and reactive black 5 dyes from water. International Journal of Environmental Science and Technology. https://doi.org/10.1007/s13762-021-03153-0
Malakootian, M., Mansoorian, H. J., Hosseini, A., & Khanjani, N. (2015). Evaluating the efficacy of alumina/carbon nanotube hybrid adsorbents in removing Azo Reactive Red 198 and Blue 19 dyes from aqueous solutions. Process Safety and Environmental Protection, 96, 125–137. https://doi.org/10.1016/j.psep.2015.05.002
Meerbergen, K., Crauwels, S., Willems, K. A., Dewil, R., Van Impe, J., Appels, L., & Lievens, B. (2017). Decolorization of reactive azo dyes using a sequential chemical and activated sludge treatment. Journal of Bioscience and Bioengineering, 124(6), 668–673. https://doi.org/10.1016/j.jbiosc.2017.07.005
Oturan, M. A., & Aaron, J. J. (2014). Advanced oxidation processes in water/wastewater treatment: Principles and applications. A review. Critical Reviews in Environmental Science and Technology., 44, 2577–2641. https://doi.org/10.1080/10643389.2013.829765
Pearce, C. I., Lloyd, J. R., & Guthrie, J. T. (2003). The removal of colour from textile wastewater using whole bacterial cells: A review. Dyes and Pigments., 58(3), 179–196. https://doi.org/10.1016/S0143-7208(03)00064-0
Peng, Y., Fu, D., Liu, R., Zhang, F., & Liang, X. (2008). NaNO2/FeCl3 catalyzed wet oxidation of the azo dye Acid Orange 7. Chemosphere, 71(5), 990–997. https://doi.org/10.1016/j.chemosphere.2007.10.065
Pérez-Calderón, J., Santos, M. V., & Zaritzky, N. (2020). Synthesis, characterization and application of cross-linked chitosan/oxalic acid hydrogels to improve azo dye (Reactive Red 195) adsorption. Reactive and Functional Polymers, 155, 104699. https://doi.org/10.1016/j.reactfunctpolym.2020.104699
Qi, C., Liu, X., Ma, J., Lin, C., Li, X., & Zhang, H. (2016). Activation of peroxymonosulfate by base: Implications for the degradation of organic pollutants. Chemosphere, 151, 280–288. https://doi.org/10.1016/j.chemosphere.2016.02.089
Ravadelli, M., da Costa, R. E., Lobo-Recio, M. A., Akaboci, T. R. V., Bassin, J. P., Lapolli, F. R., & Belli, T. J. (2021). Anoxic/oxic membrane bioreactor assisted by electrocoagulation for the treatment of azo-dye containing wastewater. Journal of Environmental Chemical Engineering, 9(4), 105286. https://doi.org/10.1016/j.jece.2021.105286
Rehman, F., Sayed, M., Khan, J. A., Shah, N. S., Khan, H. M., & Dionysiou, D. D. (2018). Oxidative removal of brilliant green by UV/S2O82-, UV/HSO5- and UV/H2O2 processes in aqueous media: A comparative study. Journal of Hazardous Materials, 357, 506–514. https://doi.org/10.1016/j.jhazmat.2018.06.012
Rodrigues de Almeida, E. J., Christofoletti Mazzeo, D. E., Deroldo Sommaggio, L. R., Marin-Morales, M. A., Rodrigues de Andrade, A., & Corso, C. R. (2019). Azo dyes degradation and mutagenicity evaluation with a combination of microbiological and oxidative discoloration treatments. Ecotoxicology and Environmental Safety, 183, 109484. https://doi.org/10.1016/j.ecoenv.2019.109484
Santos, S. C. R., & Boaventura, R. A. R. (2016). Adsorption of cationic and anionic azo dyes on sepiolite clay: Equilibrium and kinetic studies in batch mode. Journal of Environmental Chemical Engineering, 4(2), 1473–1483. https://doi.org/10.1016/j.jece.2016.02.009
Sanz, J., Lombraña, J. I., & de Luis, A. (2013). Temperature-assisted UV/H2O2 oxidation of concentrated linear alkylbenzene sulphonate (LAS) solutions. Chemical Engineering Journal, 215–216, 533–541. https://doi.org/10.1016/j.cej.2012.09.133
Saratale, R. G., Saratale, G. D., Chang, J. S., & Govindwar, S. P. (2009). Ecofriendly degradation of sulfonated diazo dye C.I. Reactive Green 19A using Micrococcus glutamicus NCIM-2168. Bioresource Technology, 100(17), 3897–3905. https://doi.org/10.1016/j.biortech.2009.03.051
Siegrist, R. L., Crimi, M., & Simpkin, T. J. (2011). In situ chemical oxidation for groundwater remediation. Springer. https://doi.org/10.1007/978-1-4419-7826-4
Sirajudheen, P., Nikitha, M. R., Karthikeyan, P., & Meenakshi, S. (2020). Perceptive removal of toxic azo dyes from water using magnetic Fe3O4 reinforced graphene oxide–carboxymethyl cellulose recyclable composite: Adsorption investigation of parametric studies and their mechanisms. Surfaces and Interfaces, 21, 100648. https://doi.org/10.1016/j.surfin.2020.100648
Tan, C., Gao, N., Deng, Y., Zhang, Y., Sui, M., Deng, J., & Zhou, S. (2013). Degradation of antipyrine by UV, UV/H2O2 and UV/PS. Journal of Hazardous Materials, 260, 1008–1016. https://doi.org/10.1016/j.jhazmat.2013.06.060
Wang, F., Wang, W., Yuan, S., Wang, W., & Hu, Z. H. (2017). Comparison of UV/H2O2 and UV/PS processes for the degradation of thiamphenicol in aqueous solution. Journal of Photochemistry and Photobiology a: Chemistry, 348, 79–88. https://doi.org/10.1016/j.jphotochem.2017.08.023
Yang, S., Yang, X., Shao, X., Niu, R., & Wang, L. (2011). Activated carbon catalyzed persulfate oxidation of Azo dye acid orange 7 at ambient temperature. Journal of Hazardous Materials, 186(1), 659–666. https://doi.org/10.1016/j.jhazmat.2010.11.057
Zhan, B. J., Li, J. S., Xuan, D. X., & Poon, C. S. (2020). Recycling hazardous textile effluent sludge in cement-based construction materials: Physicochemical interactions between sludge and cement. Journal of Hazardous Materials, 381, 121034. https://doi.org/10.1016/j.jhazmat.2019.121034
Zhang, T., Chen, Y., Wang, Y., Le Roux, J., Yang, Y., & Croué, J. P. (2014). Efficient peroxydisulfate activation process not relying on sulfate radical generation for water pollutant degradation. Environmental Science and Technology, 48(10), 5868–5875. https://doi.org/10.1021/es501218f
Zhang, Y., Zhang, J., Xiao, Y., Chang, V. W. C., & Lim, T. T. (2016). Kinetic and mechanistic investigation of azathioprine degradation in water by UV, UV/H2O2 and UV/persulfate. Chemical Engineering Journal, 302, 526–534. https://doi.org/10.1016/j.cej.2016.05.085
Zhao, C., Pelaez, M., Duan, X., Deng, H., O’Shea, K., Fatta-Kassinos, D., & Dionysiou, D. D. (2013). Role of pH on photolytic and photocatalytic degradation of antibiotic oxytetracycline in aqueous solution under visible/solar light: Kinetics and mechanism studies. Applied Catalysis b: Environmental, 134–135, 83–92. https://doi.org/10.1016/j.apcatb.2013.01.003
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Çobanoğlu, K., Değermenci, N. Comparison of reactive azo dye removal with UV/H2O2, UV/S2O82− and UV/HSO5− processes in aqueous solutions. Environ Monit Assess 194, 302 (2022). https://doi.org/10.1007/s10661-022-09964-z
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DOI: https://doi.org/10.1007/s10661-022-09964-z