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Development of Silicalite-1-Encapsulated Ni Catalyst from Ni Phyllosilicate for Dry Reforming of Methane

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Abstract

CO2 (dry) reforming of methane (DRM) is a significant and useful reaction from the standpoint of effective utilization and conversion of two main greenhouse gases to value-added synthesis gas. To achieve highly efficient and stable DRM reaction, a Silicalite-1-encapsulated ultrafine Ni nanoparticle catalyst (Ni@S-1)by using Ni phyllosilicate (Ni-PS) as precursor was newly developed. This Ni@S-1 catalyst exhibited negligible coke deposition (0.5 wt.%) evaluated at 600 °C for 5 h. Additionally, this Ni@S-1 catalyst presented high and stable catalytic performances and maintained the Ni nanoparticles with ultrafine size (< 7 nm) at 850 °C for 24 h. Therefore, this Ni@S-1 catalyst showed good suppression of coke formation and high resistance to nickel sintering and thus was promising for DRM reaction.

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Acknowledgements

This work was partly supported by Grants in Aid for Scientific Research (B) (21H01700) and JST under STCORP program (JPMJSC2101). Mr. Zhang also appreciates the financial support of China Scholarship Council (No. 202108050037). The authors would also like to acknowledge Materials Analysis Division, Open Facility Center of Tokyo Institute of Technology for the TEM equipment and analysis.

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Authors and Affiliations

  1. Department of Chemical Science and Engineering, Tokyo Institute of Technology, 9 2-12-1, Ookayama, Meguro-Ku, Tokyo, 152-8552, Japan

    Yusheng Zhang, Ryota Takahashi, Kentaro Kimura & Teruoki Tago

  2. Department of Chemical Engineering, Kyoto University, Kyotodaigaku-Katsura, Nishikyo-Ku, Kyoto, 615-8510, Japan

    Hiroyasu Fujitsuka

Authors
  1. Yusheng Zhang
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  2. Ryota Takahashi
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  3. Kentaro Kimura
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  4. Hiroyasu Fujitsuka
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  5. Teruoki Tago
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Contributions

YZ, Conceptualization, Methodology, Formal analysis and investigation, Writing—original draft preparation RT, Conceptualization, Methodology, Formal analysis and investigation KK, Conceptualization, Methodology, Writing—review and editing, Supervision HF Conceptualization, Methodology, Supervision TT, Conceptualization, Methodology, Writing—review and editing, Funding acquisition, Supervision.

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Correspondence to Teruoki Tago.

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Zhang, Y., Takahashi, R., Kimura, K. et al. Development of Silicalite-1-Encapsulated Ni Catalyst from Ni Phyllosilicate for Dry Reforming of Methane. Catal Surv Asia 27, 56–66 (2023). https://doi.org/10.1007/s10563-022-09379-3

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  • DOI: https://doi.org/10.1007/s10563-022-09379-3

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