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Palladium Complex Immobilized on Magnetic Nanoparticles Modified with 2-Aminopyridine Ligand: A Novel and Efficient Recoverable Nanocatalyst for C–S and C–Se Coupling Reactions

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A Correction to this article was published on 29 March 2022

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Abstract

A novel, versatile and efficient magnetically recoverable palladium nanocatalyst [Fe3O4@SiO2/2-aminopyridine-Pd(II)] was fabricated via the immobilization of palladium(II) complex on the surface of magnetic nanoparticles modified with 2-aminopyridine ligand. The structure of the as-fabricated Fe3O4@SiO2/2-aminopyridine-Pd(II) nanocomposite was characterized by a series of spectroscopic techniques including FT-IR, SEM, TEM, EDX, TGA, XRD, VSM and ICP-OES techniques. The Fe3O4@SiO2/2-aminopyridine-Pd(II) nanocomposite was utilized under mild and eco-friendly conditions in C–S and C–Se coupling reactions to afford a vast variety of diaryl sulfides and diaryl selenides with good to excellent yields. This heterogeneous palladium catalyst can be magnetically separated and reused for at least 7 consecutive trials without any reduction in activity.

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Acknowledgement

This work is supported by the Natural Science Foundation of the Jiangsu Higher Education Institutions of China, Study on the change of microenvironment and electrochemical characteristics of protein activity center induced by targeted molecule, (16KJB150042,19KJD430005), “333” Talent Training Project of Jiangsu Province, and the “Six one” Top Health Talent Project of Jiangsu Province, Study on electron transport properties of targeted drug molecule doped protein, (LGY2018089), Research project of Jiangsu Health Vocational College (JKA202004, JKB202002, JKB202005, JKD202002).

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Authors and Affiliations

  1. Science and Technology Branch, Jiangsu Health Vocational College, Nanjing, 211800, China

    Xiaoqing Xu, Weiqi Wang, Lu Lu, Jingzheng Zhang & Jia Luo

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  1. Xiaoqing Xu
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  2. Weiqi Wang
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  3. Lu Lu
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  4. Jingzheng Zhang
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  5. Jia Luo
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Correspondence to Xiaoqing Xu.

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The original version of this article was revised due to missing Acknowledgement section. The Acknowledgement section is now added.

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Xu, X., Wang, W., Lu, L. et al. Palladium Complex Immobilized on Magnetic Nanoparticles Modified with 2-Aminopyridine Ligand: A Novel and Efficient Recoverable Nanocatalyst for C–S and C–Se Coupling Reactions. Catal Lett 152, 3031–3045 (2022). https://doi.org/10.1007/s10562-021-03908-x

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  • DOI: https://doi.org/10.1007/s10562-021-03908-x

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