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Ni-Foam Structured Ni-Phyllosilicate Ensemble as an Efficient Monolithic Catalyst for CO2 Methanation

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Abstract

This work proposed a new path to synthesize Ni-phyllosilicate through the reaction of nickel hydroxide and silica sol on the surface of Ni-foam to form the monolithic Ni-phyllosilicate/Ni-foam catalyst. Ni-phyllosilicate could reprint the morphology of nickel hydroxid and firmly anchor on the framework of Ni-foam, which obtained fine Ni particles of 2.8 nm after reduction in H2 at 650 °C, resulting in high catalytic activity for CO2 methanation. In addition, the Ni-phyllosilicate/Ni-foam catalyst showed high long-term stability in a 100 h-lifetime test owing to the combined effects of surface confinement of Ni-phyllosilicate, firm anchoring between Ni-phyllosilicate and Ni-foam, as well as the high heat transfer property of Ni-foam.

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Acknowledgements

The authors gratefully acknowledge the supports from National Natural Science Foundation of Shandong Province (No. ZR202102220024) and Foundation of Division of Chemical Sciences of Qingdao University of Science and Technology (No. QUSTHX201912).

Funding

This study was funded by Foundation of Division of Chemical Sciences of Qingdao University of Science and Technology (No. QUSTHX201912) and National Natural Science Foundation of Shandong Province (No. ZR202102220024).

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Authors and Affiliations

  1. Key Laboratory of Low Carbon Energy and Chemical Engineering, Shandong University of Science and Technology, Qingdao, 266590, China

    Yaqi Chen & Qing Liu

  2. Schneider Electric (China) Co., Ltd., Beijing, 100102, China

    Xiaoren Wu

  3. Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China

    Maoshuai He

  4. State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University, Yinchuan, 750021, China

    Hongcun Bai

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  1. Yaqi Chen
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  2. Xiaoren Wu
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  3. Qing Liu
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  4. Maoshuai He
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  5. Hongcun Bai
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Correspondence to Qing Liu, Maoshuai He or Hongcun Bai.

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Chen, Y., Wu, X., Liu, Q. et al. Ni-Foam Structured Ni-Phyllosilicate Ensemble as an Efficient Monolithic Catalyst for CO2 Methanation. Catal Lett 152, 2738–2744 (2022). https://doi.org/10.1007/s10562-021-03850-y

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  • DOI: https://doi.org/10.1007/s10562-021-03850-y

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