Ultra-dense hydrogen H(0) as dark matter in the universe: new possibilities for the cosmological red-shift and the cosmic microwave background radiation

50 experimental publications exist on ultra-dense hydrogen H(0) from our laboratory. A review of these results was published recently (L. Holmlid and S. Zeiner-Gundersen in Phys. Scr. 74(7), 2019, https://doi.org/10.1088/1402-4896/ab1276). The importance of this quantum material in space is accentuated by a few recent publications: The so called extended red emission (ERE) spectra in space agree well (L. Holmlid in Astrophys. J. 866:107, 2018a) with rotational spectra measured from H(0) in the laboratory, supporting the notion that H(0) is a major part of the dark matter in the Universe. The proton solar wind was shown to agree well with the protons ejected by Coulomb explosions in p(0), thus finally providing a convincing detailed energy mechanism for the solar wind protons (L. Holmlid in J. Geophys. Res. 122:7956–7962, 2017c). The very high corona temperature in the Sun is also directly explained (L. Holmlid in J. Geophys. Res. 122:7956–7962, 2017c) as caused by well-studied nuclear reactions in H(0). H(0) is the lowest energy form of hydrogen and H(0) is thus expected to exist everywhere where hydrogen exists in the Universe. The so called cosmological red-shifts have earlier been shown to agree quantitatively with stimulated Raman processes in ordinary Rydberg matter. H(0) easily transforms to ordinary Rydberg matter and can also form the largest length scale of matter, with highly excited electrons just a few K from the ionization limit. Such electronic states provide the small excitations needed in the condensed matter H(0) for a thermal emission at a few K temperature corresponding to the CMB, the so called cosmic microwave background radiation. These excitations can be observed directly by ordinary Raman spectroscopy (L. Holmlid in J. Raman Spectrosc. 39:1364–1374, 2008b). A purely thermal distribution from H(0) and also from ordinary Rydberg Matter at 2.7 K is the simplest explanation of the CMB. The coupling of electronic and vibrational degrees of freedom observed as in experiments with H(0) gives almost continuous energy excitations which can create a smooth thermal CMB emission spectrum as observed. Thus, both cosmological red-shifts and CMB are now proposed to partially be due to easily studied microscopic processes in ultradense hydrogen H(0) and the other related types of hydrogen matter at the two other length scales. These processes can be repeated at will in any laboratory. These microscopic formation processes are much simpler than the earlier proposed large-scale non-repeatable processes related to Big Bang.


Introduction
Ultra-dense hydrogen H(0) has been extensively studied during the last decade by laser-induced mass spectrometry and neutral kinetic energy spectroscopy (Badiei et al. 2009a(Badiei et al. ,b, 2010aAndersson and Holmlid 2009, 2010, 2012aHolmlid 2011a,b). (Note that a change in nomenclature has been made due to improved theoretical understanding; H(0) was initially named H(−1) for a theoretically supported, inverted form of Rydberg Matter). Laser pulses excite the bonding electrons and induce Coulomb explosions (CE) in the H(0) material (Badiei et al. 2009a(Badiei et al. ,b, 2010aAndersson and Holmlid 2009, 2010, 2012a  2011a,b). The CE process ejects ionic and neutralized fragments with kinetic energy up to 630 eV from spin state s = 2, and up to 2.5 keV from spin state s = 1 (Andersson and Holmlid 2010). A review of H(0) was recently published (Holmlid and Zeiner-Gundersen 2019). Ultra-dense hydrogen H(0) contains clusters of various forms, with different modes of CE fragmentation. Large clusters are mainly in the form of chains of H-H pairs (see Fig. 1) Holmlid 2011, 2012a). From the CE experiments, the bond distance in d(0) in spin state s = 2 is determined to be 2.3 pm, a factor of 100 smaller than in ordinary molecules. This means that the material has very high density, of the order of 10 29 cm −3 (100 kg cm −3 ). H(0) will absorb electromagnetic radiation only at energies above several hundred eV due to the strong atomic bonding in the keV range, and it is thus not easily observable in absorption in space. However, rotational emission spectra in the visible can be observed (Holmlid 2017a(Holmlid , 2018a. In H(0), it is observed that nuclear processes take place easily (Holmlid and Zeiner-Gundersen 2019), even continuously at a low rate. Experiments showing both spontaneous and laserinduced fusion d + d in d(0) have been described (Badiei et al. 2010c;Andersson and Holmlid 2012b;Olafsson 2015a,b, 2016). The material p(0), ultra-dense protium (Holmlid 2013a), is probably the most common ultradense material in the universe. This material has a slightly more complex cluster structure than ultra-dense deuterium d(0). The nuclear processes in p(0) are however similar to those in d(0), giving meson showers containing all types of kaons (Holmlid 2015(Holmlid , 2016(Holmlid , 2017b. The organization of this contribution is such that it is firstly aimed at summarizing the published evidence for the closely related phases RM and H(0) in space through the interpretation of several complex sets of observations, especially spectroscopic results with no other known explanations, like ERE (Holmlid 2018b) and DIBs (Holmlid 2004(Holmlid , 2008a(Holmlid , 2011c. Secondly, quantitative evidence is already published on how RM gives cosmological redshifts (Holmlid 2005). This publication may not be so easily accessible, and part of its results is now included here in Appendix. Thirdly, the interpretation of CMB as due to thermal emission from H(0) is discussed, especially concerning the densely spaced energy levels in this condensed material.
It is possible that this interpretation of the CMB is worth a treatment in a separate publication: however, a temperature measurement as the CMB is just one parameter with small information content and it can thus have almost any cause.

Ultra-dense hydrogen H(0)
Ultra-dense hydrogen H(0) is closely related to the lowest form of Rydberg Matter (RM) of the type H(1) (Manykin et al. 1992);Holmlid 1998Holmlid , 2012. The ultra-dense hydrogen materials will all be named H(0) here, while the different isotopic forms studied will be named p(0), d(0) and pd(0). A review of H(0) was recently published (Holmlid and Zeiner-Gundersen 2019) and the description given in the present study is thus kept brief. The quantum mechanical basis for d(0) was discussed by Winterberg (Winterberg 2010a,b) suggesting the formation of d-d bonding by exchange forces as the crucial factor of its formation. Other more general theoretical descriptions have been published (Holmlid and Zeiner-Gundersen 2019;Holmlid 2013b). d(0) as well as p(0) is observed experimentally to be superfluid at room temperature . They are both also proposed to be type-II superconductors at room temperature from the observed Meissner effect (Andersson et al. 2012;Holmlid and Fuelling 2015). Only hydrogen atoms are expected to give an ultra-dense material form, since the inner atomic electrons prevent this formation for all other atoms but possibly for doubly excited He atoms (Holmlid 2004(Holmlid , 2008a(Holmlid , 2011c. d(0) is the first example studied on Earth of the ultradense hydrogen materials that apparently exist in many different objects in space for example in stars and giant planets. H(0) is the lowest energy form of hydrogen, and it will exist everywhere in space where hydrogen exists. Thus, the properties of H(0) are of general importance for our understanding of the Universe (Holmlid 2018b). H(0) has a density up to a thousand times higher than the interior of the Sun, and the particles released in the laboratory by relatively weak laser pulses have kinetic energy of at least 15 MK, similar to the temperature in the Sun (Andersson and Holmlid 2010). Recently, the proton solar wind was shown to agree well with the protons ejected by CE from p(0) (Holmlid 2017c). The most important properties observed for H(0) have not been considered to be possible previously, namely the short bond distances and the strong bonds. The H(0) clusters have dimensions down to a few pm. This is directly verified by rotational spectroscopy in the visible (Holmlid and Zeiner-Gundersen 2019;Holmlid 2017aHolmlid , 2018a. This means that the H(0) clusters will not scatter electromagnetic radiation with wavelength longer than a few pm, and thus that H(0) clusters will be invisible in absorption in any spectral range with wavelength longer than typical gamma rays. Due to the strong interatomic bonding in H(0) with energy of the order of 1-2 keV, absorptions in the visible or UV ranges are unlikely. No stationary electronic excited states at intermediate energies exist in H(0), but several different spin states have been observed (Holmlid 2017a(Holmlid , 2018a. Rotational transitions exist at many eV energies, as described in two recent publications (Holmlid 2017a(Holmlid , 2018a).

H(0) formation
Next, we need to consider the energetics of H(0) formation. The d-d and p-p bond energy of the order of 500 eV corresponds to a temperature of approximately 5 MK. Thus, in any dense region in space where the temperature is lower than approximately 1 MK, ultra-dense hydrogen H(0) is the most important form of hydrogen (Holmlid 2018b). This means that even inside many stars will this form of hydrogen be of great importance. The formation of H(0) is spontaneous from higher Rydberg matter (RM) states, for example by H(3) falling down to H(1) (Andersson et al. 2012). H(1) (Badiei and Holmlid 2006) is easily converted to H(0). The facile oscillatory conversion between D(1) and D(0) was even directly observed in real time (Badiei et al. 2010b). This means that the stable state H(0) is easily reached by hydrogen in space at large enough densities or low enough temperatures. Thus, vast amounts of H(0) are proposed to exist in the Universe and this should be the primordial form of hydogen in space. Of course, if H 2 molecules dominate in some region at present, the formation of H(0) there is slower and more complex, often requiring absorption of H 2 on solid surfaces like carbon or metal oxide surfaces which give dissociative adsorption.

H(0) stability
The stability of H(0) will be higher than for any other known material. Temperatures above the MK range are required to dissociate this material after it has been formed. Of course, fragmentation due to ionizing photons and fast particles will take place. When the energy density of the radiation field is lower than that corresponding to 1 MK, the ultra-dense hydrogen phase should be stable. The superfluid H(0) phase will quite easily transport energy deposited in one location to other places.
All implications of the large densities of the superfluid and superconductive material H(0) in space are certainly not yet clear. A few conclusions about the effects of H(0) in space were published recently (Holmlid 2018b).

Star formation in H(0)
H(0) consists of small clusters H 2N with pm sizes (Holmlid and Zeiner-Gundersen 2019). The main forces which may give condensation of such clusters to larger solid or liquid volumes have not yet been studied directly. Winterberg (Winterberg 2010a,b) proposed exchange forces to form larger volumes of D(0), but that was for condensing atoms, not for clusters. Basic forces like dispersion forces and electrostatic forces like dipole interactions (Holmlid 2017a(Holmlid , 2018a between the clusters will always exist. Such forces vary with distance as r −6 , so they may be 10 12 times stronger for typical distances r of 2 pm in H(0) instead of 2 Å = 200 pm for typical molecules. However, since the polarizability is several orders of magnitude smaller for H(0) clusters than for ordinary molecules due to their strongly bound electrons, the interaction giving condensation in H (0) is not 10 12 times stronger; it seems likely that it is 10 3 -10 6 times stronger than in an H 2 gas. The high energy electrons which exist at the largest length scale of H(0) (Hirsch 2012) are more easily influenced by Coulomb interactions and will give attractive forces between the clusters. These much stronger attractive forces for H(0) will lead to a much faster condensation than in H 2 , and the nuclear processes in H(0) Olafsson 2015a,b, 2016) will start almost immediately in an H(0) cloud. That this will speed up the onset of ordinary p + p fusion reactions seems likely, since the increased temperature given by the nuclear reactions in H(0) should help in starting ordinary fusion reactions. Thus, the rate of star formation may be strongly increased by the condensation and nuclear reaction properties of H(0). This means that also the rate of galaxy formation will be strongly increased. It is suggested that H(0) was the primordial form of hydrogen in space due to its stability up to MK temperatures.

Three levels of matter
The description used here of matter at three different length scales is based on a publication by J.E. Hirsch (Hirsch 2012), stating on p. 5 "There exists a remarkable parallel in the physics at the three different length scales" r q = /(2mec) the 'quantum electron radius', a 0 = 2 /m e e 2 the Bohr radius and 2λ L = 137 a 0 with λ L the London penetration depth, and with the fine structure constant α = 1/137 as the common ratio between these length scales" (Hirsch 2012). Ultra-dense hydrogen H(0) has the length scale r q while ordinary Rydberg matter has length scale a 0 . Super properties like superconductivity are coupled to the largest length scale which is also similar in its properties to Rydberg matter at large excitation levels (Rydberg-like circular electron orbits, Hirsch 2012). The energy scales are related by the square of the fine structure constant α 2 which gives the energy scale for the largest length scale of 181 µeV (Hirsch 2012). This is equal to 2.1 K, relatively close to the CMB temperature of 2.7 K (see further below). A real thermal contribution from the material H(0) is the most likely factor giving the observed CMB temperature of 2.7 K.

Ordinary RM in space
From the description of H(0) above, it is concluded that it exists everywhere in space, since it is the lowest energy state of hydrogen and also of matter in general (based on the quantum electron radius r q ). It can easily transform into the lowest excitation level of ordinary hydrogen Rydberg matter named H(1) (Badiei et al. 2010b;Andersson et al. 2012;Holmlid and Fuelling 2015). This gives a mechanism for generating vast amounts of Rydberg matter (RM) in space thus of the form H(RM); such a mechanism has not been apparent previously, even if many spectroscopic results strongly indicated that RM is common in interstellar, interplanetary and even intergalactic space and in the atmospheres of planets and satellites. A short list of published results on this theme is given here: 1. DIBs (diffuse interstellar bands), which are due to absorbing doubly excited atoms especially He within an RM phase (probably in H (1)) in interstellar space. Close to 300 DIB transition wavelengths have been calculated accurately (Holmlid 2004(Holmlid , 2008a(Holmlid , 2011c.

Red-shifts by stimulated Raman effects
The very large polarizability of RM due to the high Rydberg levels of its atoms gives rise to a stimulated Raman effect which shifts the wavelength of light passing through RM without a simultaneous deflection. This gives redshifts or blueshifts of the light depending on the excitation state of the RM. The general theory of stimulated Raman is summarized together with the experimental detection and studies of this effect using tunable diode lasers in the medium infrared range in Refs. (Holmlid 2005(Holmlid , 2004a. The most important direct results for the present study are collected in Appendix below, but many general results for example concerning the properties of the shifts are not repeated here since they require the theory of stimulated Raman scattering which is a specialized theory for interactions between quanta and matter far from astrophysics. With H(0) as dark matter, Rydberg matter H(1) and higher excitation levels H(RM) are formed easily, giving dark matter with a large polarizability of its atoms, and red-shifts for distant objects seen through cold RM (Holmlid 2005(Holmlid , 2004a. Thus, there is no need for any non-repeatable mechanisms of expansion giving fast receding objects to explain large redshifts, since the stimulated Raman mechanism is much simpler and only involves wellknown small-scale physics, which is repeatable and independently testable in any laboratory. The stimulated Raman process is known and extensively studied since the 1960's, but it appears to be quite little known outside laser physics and spectroscopy: thus some basic information on its theory and significance for redshifts in space is repeated in Appendix below.

Raman shifts at a few K energy
Very small Raman shifts can be observed in RM using an intense IR laser with a tunable cavity and an interferometer as in Holmlid (2008b). Also so called Rabi-flopping features were observed in this study. Rabi-flopping is a type of avoided forbidden transition (Holmlid 2008b). These Raman shifts have an energy of a few K, and were concluded to be due to transitions in the vibrational-electronic structure of the RM clusters. These results were published before H(0) was known to exist and hydrogen gas was not introduced deliberately in the experiments, thus it is not known but unlikely that H(0) (the lowest state of matter) gave these results. It is however likely that the highest level of matter contributed to the detection and size of the shifts in this case in the form of high excitation levels of K(RM), not only low excitation levels of K(RM) as was assumed in that paper. With H(0) as dark matter in the Universe, the transitions between these electronic levels are likely to give a thermal emission background in space with a temperature of a few K, close to the energy levels corresponding to the largest scale of matter as described above and by Hirsch (2012). Of course, the CMB observations strongly indicate matter with a real black-body temperature as the origin of this radiation. It was probably only since no such material was observed or known to exist a long time ago which made other ideas for the origin of CMB acceptable: however, now when H(0) seems to exist as dark matter almost everywhere in space, H(0) is the prime likely origin for the 2.7 K background emission radiation. One important requirement for such a thermal background emission is that the emitting material can support numerous small excitations so that a quantal structure is not observed in the emission spectrum. Such a quasi-continuous energy distribution exists in ordinary RM and in matter at the largest length scale due to the conduction band electrons. In ultra-dense H(0) another such important factor exists through the coupling of the electrons to the vibrations in this material (Holmlid and Zeiner-Gundersen 2019). This coupling gives the relatively broad bands observed in the rotational emission spectra (Holmlid 2017a(Holmlid , 2018a. Thus, there is no need for the explanations involving recombination radiation and wavelength changes due to the expansion of the universe which are normally invoked to "explain" the CMB, since a much simpler and robust thermal emission explanation exists. It should be noted that the wavelength expansion from the early Universe is a process that cannot be observed and studied experimentally, and thus it does fulfill the requirements of ordinary science as a verifiable and repeatable process. The processes giving the CMB and redshifts from H(0) of course fulfill all such requirements of being reproducible and repeatable in experiments, in the case of CMB in a really very basic sense as thermal radiation from an observable condensed material existing now, not emitted from matter 14 × 10 9 years ago with no changes due to absorption after that.
The energy scales for the three levels of matter are related by the square of the fine structure constant α 2 which gives the energy scale for the largest length scale at 181 µeV (Hirsch 2012). This is equal to 2.1 K, smaller than the observed CMB temperature of 2.7 K. This means that there should be a large enough number of transitions together with the coupling to vibrational degrees of freedom in the H(0) material to support a smooth thermal distribution in emission. Here, no argument is given to prove that the temperature of the H(0) dark matter is 2.7 K. Such an argument will mainly depend on the properties of the Universe and not on the properties of H(0), and they are thus outside the scope of the present contribution. Further studies will hopefully be published in this direction.
There is no interaction between the two processes, forming CMB and the redshifts in H(0) dark matter. The amount of dark matter is very large, normally assumed to be much larger than the amount of visible matter and the two processes discussed require just a small number of atoms. The density of H(0) is a few orders of magnitude larger than for ordinary condensed matter like hydrogen ice, so the fraction of H(0) dark matter involved in the two processes is very small.

Conclusions
It is concluded that the properties of ultra-dense hydrogen H(0) must be taken into account to understand numerous important features in space, since H(0) is the most common form of hydrogen and matter in the Universe. Several of these features like DIBs and UIR have been well studied and described in the literature as due to processes in ordinary Rydberg matter, which is closely related to H(0). It is observed in experiments that H(0) is easily transformed to the lowest Rydberg matter form H(1). Other features in space such as the so-called cosmological redshifts and the so-called cosmological microwave background (CMB) have much simpler explanations within the H(0) framework than outside this framework; for example the H(0) based redshifts have been studied as due to stimulated Raman many years ago in laboratory experiments with spectroscopic methods which can be repeated and tested in any laboratory. It is now suggested that processes in the Universe that are believed to have taken place only once and which are neither possible to repeat nor to study independently should be removed from science and be considered like creation as belonging to the sector of personal belief only.
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Appendix: Redshifts in space from stimulated Raman scattering
Only the most significant information needed to quantitatively understand the stimulated Raman scattering as the origin of cosmological redshifts is included here. For a more complete treatment, see Refs. (Holmlid 2005(Holmlid , 2004a and the fundamental theoretical descriptions cited there. In what follows, the term light is used for simplicity in many places where the term electromagnetic radiation is more generally valid. An important process for the interaction between light and Rydberg Matter (RM) is the stimulated electronic Raman scattering of the Stokes or anti-Stokes type (SERS, ASERS) (White 1992). Anti-Stokes Raman scattering and similar processes in RM have been observed in different types of experiments, even at low light intensities. See further references in Holmlid (2005). For cold ground-state RM, Stokes scattering should be observed instead. There is no phase matching condition for this type of process (White 1992), and the Raman-scattered light proceeds in the same direction as the incident light.
It is necessary to estimate the magnitude of the stimulated Raman effect in the case of an RM material. For this, we use the ordinary classical steady-state gain factor originally derived for molecular vibrational transitions (cited in Holmlid 2005(cited in Holmlid , 2004a. The formulas are given for the Stokes scattering, which is the case of interest for astrophysical processes. The equations are identical in form for the anti-Stokes and Stokes cases. The incident light frequency is ω L and the generated Stokes wave has a frequency ω s . The difference ω E = ω L − ω S is the resulting electronic excitation in the RM material. For the Stokes wave, the steady-state gain factor G ss at its maximum is given by Yariv (1989) In this expression, N d is the density of the dipoles created by the incident light wave, here chosen to correspond to the number of electrons in the RM; k s is the wavenumber for the Stokes wave; m is the mass of the driven oscillator, in this case, one electron mass; ε = ε r ε 0 is the permittivity of the medium, with ε r close to unity, γ is the coupling constant for the electronic excitation in the intermediate state to other degrees of freedom; ∂α/∂q is the variation of the polarizability with the coordinate describing the excited motion, here the electronic motion; and E L is the electric field strength of the incident light.
The excitation levels in Rydberg matter observed from the so-called unidentified infrared bands (Holmlid 2000) have the most probable value close to n (or l) = 80. A comparison with the parameter values appropriate for the laboratory studies of cold RM (Holmlid 2005(Holmlid , 2004a, shows that the density N d is several orders of magnitude smaller in space than in the laboratory experiments. On the other hand, for visible light, the wave number k s is approximately 50 times larger than for the experimental IR studies used to quantify the stimulated Raman effect in Refs. (Holmlid 2005(Holmlid , 2004a. Equation (3) in Holmlid (2005) shows that a shift due to the stimulated Raman effect exists if the product G ss x is larger than unity. With Eq. (1) used for G ss and with reasonable values also used for estimation of this factor as in Ref. (Holmlid 2005), it is possible to find a condition on the electric field strength of the light field. The distance covered by light in space is denoted by l. Then the inequality should be valid for the SERS effect to exist. In this inequality, the space-related quantities are collected at the right hand side. The difference ω L − ω s was replaced by c ν, where ν is in wavenumbers. Assuming conservatively that γ is as large as the upper experimental limit found, 10 3 s −1 , we find that the left-hand side is equal to 2 × 10 −12 m 3 V −2 , with the other parameter values estimated as previously (Holmlid 2005). With the experimental values from the study of the cold RM described in Holmlid (2004b), ν = 0.02 cm −1 , N d = 10 17 m −3 , l = 0.25 m, and E L = 90 V m −1 , the right-hand side becomes 1×10 −20 m 3 V −2 . This is many orders of magnitude smaller than the left-hand side, as required by Eq.
(2). Because some of the quantities are anyway somewhat uncertain, we may assume that the right-hand side of Eq.
(2) in space should be as small as this value found in the experiments. (This is a very conservative estimate.) Then ≈ 10 4 cm −1 (the typical total summed SERS shift in observations in space), N d = 10 6 m −3 (Holmlid 2005), and l = 8 × 10 8 pc = 2.5 × 10 25 m may be used, giving E L = 3 × 10 −3 V m −1 . The distance l used is smaller than the radius of the observable universe by about a factor of 10. This gives a light intensity of 2 × 10 −8 W m −2 as the minimum intensity required to make the stimulated Raman process work, corresponding to the intensity of light from the Sun at our nearest star α Centauri. This is a very conservative estimate, based on the experimental results. If we instead use the condition that the right-hand side in Eq.
(2) should only be smaller than the estimated value 2 × 10 −12 m 3 V −2 of the left-hand side, the required light intensity may even be a factor of 10 9 smaller, thus larger than 2 × 10 −17 W m −2 corresponding to the field strength E L = 10 −7 V m −1 . This is the same as the intensity of light from the Sun at the distance 4 × 10 4 pc, i.e., on the other side of our galaxy. Thus, a redshift due to SERS exists even at very large distances from the source. For redshifts from distant galaxies and similar objects, the incident light intensity E L is much larger than for the Sun for a large distance along the light beam, so the right-hand side of Eq.
(2) becomes smaller and the inequality is more easily fulfilled. It is further concluded that the density of H(0) was much larger in space during earlier epochs of the Universe since much less material was condensed into galaxies. This increases the SERS effect for distant galaxies, for which redshifts of a cosmological origin were assumed to exist.