Improvements to the Water Quality of the Acidic Berkeley Pit Lake due to Copper Recovery and Sludge Disposal

The chemistry and limnology of the Berkeley Pit lake, located in Butte, Montana, have substantially changed during the past 15 years. These changes are due to: (1) a large-scale Cu recovery project in which deep water was pumped to a Cu precipitation plant and returned to the surface of the lake; and (2) in-pit disposal of lime-treatment sludge. As a consequence, the lake has shifted from a meromictic to a holomictic state, over 99% of the dissolved Fe has precipitated as schwertmannite and other ferric solids, the total acidity of the water column has dropped by roughly 35%, and the pH has risen from about 2.5 to near 4.1. Whereas most of the lake was anoxic prior to 2013, the water column now contains > 6 mg/L dissolved oxygen from the lake surface to the deepest levels sampled (> 150 m). Concentrations of several other solutes, including As, P, Cr, and V, have fallen sharply due to adsorption or co-precipitation with Fe, while other species, such as Al, Mg, and Mn, have increased due to dissolution of solids in the sludge. Although the Cu recovery circuit was discontinued in 2013, in-pit disposal of sludge is expected to continue. The pit water is now close to saturation with basaluminite, and the pH should remain poised in the range of 4.1–4.5 for many years as Al precipitates out of the water column. Pumping and treating of pit water is set to commence in 2019, and will continue for the foreseeable future. Continued in-pit disposal of sludge should translate into long term water-quality improvement and a decrease in annual lime-consumption costs. Although the Berkeley Pit still has a long ways to go before it will meet water quality standards, it is heartening to mine-water specialists that the pit lake may not be a problem that is “too big to fix”.


Introduction
In the field of mine-lake research, the Berkeley Pit lake in Butte, Montana, USA, is iconic, both from the point of view of its size (> 185 billion L) and the severity of its chemistry. Reviews of mining lakes worldwide (e.g. Blanchette and Lund 2016;Castendyk and Eary 2009;Castro and Moore 2000;Davis and Eary 1997;Gammons et al. 2009a, b;Geller et al. 2013;Miller et al. 1996;Soni et al. 2014) often consider the Berkeley Pit to be an end-member of poor water quality. The lake's metal toxicity poses a threat to wildlife (two mass fatalities of migratory waterfowl have occurred on the lake, most recently in Dec., 2016, see Robbins 2016), and the lake's location within the city limits of Butte adds to its high profile in the media. Pumping and lime treatment of the Berkeley Pit has commenced (May, 2019) and is projected to continue for the foreseeable future. At the time of this writing, no beneficial "end use" is foreseen for the pit, other than as a sump to collect acidic and metal-rich groundwater associated with the historic mining complex of Butte.
When first described (Davis and Ashenberg 1989;Sonderegger et al. 1987), the Berkeley Pit had a pH of 2.7-3.1 and thousands of mg/L of total dissolved metals, including Fe, Al, Zn, Mn, Cu, Cd, and As. In a more recent paper, Gammons and Duaime (2006) showed that the chemistry of the pit had changed relatively little since the 1980s. However, beginning in the mid-2000s, a massive-scale precipitation of dissolved Fe out of the water column was noticed (Tucci 1 3 and Gammons 2015). This event was attributed to a copper recovery circuit which pumped water from the deep lake and returned it to the surface, allowing oxidation of ferrous to ferric iron. During the period 2013-2016, unstable mine walls forced a suspension in monitoring and lake-sampling efforts in the Berkeley Pit. When monitoring resumed in the summer of 2017 with the help of a specially designed remotely controlled (RC) boat, the pH of the lake had risen to > 3.0, and by 2018 to > 4.0 (GWIC 2019; Hill et al. 2018). Meanwhile, sometime before Dec., 2016, the color of the lake changed from deep red-brown to blue-green (Fig. 1a, b).
The purpose of this paper is to summarize the various changes in the chemistry of the Berkeley Pit that have taken place since the review of Gammons and Duaime (2006), and to present possible explanations for these changes. Readers are referred to the MWEN special issue on Butte, in which Gammons and Duaime (2006) appeared, for more background on the geology, mining history, and history of flooding of the Berkeley Pit and surrounding underground mine workings. Additional information can be found in other journal articles (Gammons et al. 2003(Gammons et al. , 2009aPellicori et al. 2005;Stierle and Stierle 2013), and publications of the Montana Bureau of Mines and Geology (MBMG) (e.g. Duaime et al. 1998Duaime et al. , 2016Duaime et al. , 2018. A chronology with detailed notes on field and analytical methods used by the MBMG for Berkeley Pit sampling between 1982 and 2017 is given in . All field and analytical data for samples of Berkeley Pit water collected since monitoring began in the 1990s are available on the internet (GWIC 2019).  . The Berkeley Pit continues to fill from a combination of groundwater inputs and precipitation/runoff. In the past, the lake received additional diverted water from the mine complex. The most significant of these in terms of volume is the so-called "Horseshoe Bend springs" (HSB), a collection of acidic springs and seeps draining the active tailings impoundment and heap leach pads to the north and east of the Berkeley Pit (Fig. 3). During the period 2000-2003, the HSB flow was diverted (untreated) to the Berkeley Pit. Beginning in 2003 to the present day, the HSB flow has been treated with lime and reused by the active mine (Duaime et al. 2016). High-density sludge from the lime-treatment plant is discharged directly to the surface of the Berkeley Pit at a rate of ≈ 0.8-0.9 million L/day. This flow represents less than 8% of the total influx of water to the pit, but nonetheless has had a large impact on the lake chemistry, as discussed below. The lime-treatment plant discharges a combination of "Stage 1 sludge" and "Stage 2 sludge". Information on the chemistry and mineralogy of representative sludge samples is provided as a Supplemental Information file.

Mine Flooding and Pit Management 2003-2018
Another process that has profoundly influenced the chemistry and limnology of the Berkeley Pit is Cu recovery Tucci and Gammons 2015). Between 1998 and 2000, and again from 2003 to 2013, the active mining company pumped tremendous volumes (averaging 50 million L/day) of deep-pit water to a Cu-precipitation plant where the acidic water interacted with scrap Fe to form elemental Cu. The reaction, sometimes referred to as cementation, is written: Approximately 10,000 snow geese land on the pit lake, resulting in over 3000 fatalities July-17 First successful deployment of remotely controlled (RC) boat for vertical profiling and water sampling of Berkeley Pit lake May-19 Pumping and lime treatment of Berkeley Pit lake begins Aside from the changes to the dissolved Cu and Fe concentrations, Reaction (1) had no discernable effect on the concentrations of other solutes, nor on the pH of the water (Gammons and Duaime 2006). The Cu-depleted and Fe(II)enriched water was returned via a ditch to the rim of the Berkeley Pit where it cascaded down the pit wall to mix into the surface of the lake (Figs. 1c,d,3). Pumping water from the deep lake, passing it through the Cu recovery plant, and returning it to the surface of the lake caused a steady decline in the elevation of the chemocline between the lower TDS mixolimnion from the higher TDS monimolimnion (Fig. 4). By the end of 2009, the chemocline was drawn down to the bottom of the pit and the lake ceased to be meromictic. In Feb., 2013, the Cu recovery circuit was discontinued due to damage to the pumps from one of the large landslides. In 10 years of operation between 2003 and 2013, the project circulated ≈ 1.5 pit volumes through the precipitation plant and recovered over 15 million kg of copper.

Changes to Chemistry
Figures 5 and 6 summarize changes in selected chemical attributes of the Berkeley Pit with time and depth, respectively. Prior to the suspension of conventional sampling in Nov., 2012, the pH of the pit water varied between 2.4 and 3.0, and there were no clear trends in pH with time or depth (Fig. 5a). When sampling resumed in 2016, the pH of the surface of the lake had risen to > 3.4 , and by Nov., 2018 the pH of the lake was 4.1 ± 0.1 from top to bottom (Figs. 5a, 6a). Remarkably, between 2003 and 2018, the concentration of total dissolved Fe in the deep lake dropped from > 1000 to < 10 mg/L. The drop in ΣFe also decreased the total acidity of the pit lake ( Fig. 5c); acidity values were calculated from published chemical analyses of pit-lake water samples (GWIC 2019), as follows: Part of the scatter in the acidity graph is due to uncertainty in the relative concentrations of Fe(II) and Fe(III) for a given sampling date. For dates when no Fe speciation data  Once the chemocline was drawn down to the bottom of the pit (in early 2010), the lake transitioned from a meromictic to a holomictic state were available, the valence of dissolved Fe was assumed to be 80% ferrous for the deep water, and 20% ferrous for the shallow water. These ratios are based on historical trends (Montana Resources Inc., unpublished data). Pellicori et al. (2005) provide a more detailed discussion of dissolved Fe speciation in the Berkeley Pit.
As would be expected, the precipitation of > 99% of the dissolved Fe out of the water column resulted in a decrease in specific conductance (Fig. 6b). Unexpectedly, the pit lake now contains elevated dissolved oxygen (DO) from top to bottom (Fig. 6c). Prior to 2012, concentrations of DO were below the practical quantification limit at all depths below the zone of wave mixing. Since 2017, DO concentrations have been poised at 6.2 ± 0.2 mg/L in the deep lake. It is not known if there is a drawdown in DO concentration during the stratified seasons of mid-summer or mid-winter, as sampling of the Berkeley Pit is typically conducted in late spring or late autumn when the lake is most likely to be vertically mixed.   (Allison et al. 1991). More details on the methods and results of the geochemical modeling can be found in the Supplementary Information file.

Iron
In 2002, the deep Berkeley Pit contained roughly 1000 mg/L of dissolved Fe (Fig. 7a), most of which was Fe(II) (Pellicori et al. 2005). In contrast, samples collected in March 2018 contained < 5 mg/L of total dissolved Fe to a depth of 137 m. Thus, in 15 years, > 99% of the dissolved Fe in the pit lake precipitated out of the water column. Imhoff sediment samplers deployed in 2008 showed that most of the Fe-rich solid was schwertmannite, with lesser amounts of K-jarosite (Tucci and Gammons 2015). The mass of Fe precipitated out of the water column between 2002 and 2018 is estimated at roughly 2 × 10 8 kg Fe. Roughly 10% of this total came from Fe(II) generated at the precipitation plant by Reaction (1), with the remainder being equivalent to the total load of dissolved Fe in the water column in 2002. In addition, a considerable amount of Fe in the form of ferric hydroxide was added to the lake by disposal of lime-treatment sludge. Like the precipitates that formed in situ, any ferric solids in the sludge would have settled to the bottom of the lake.
Samples collected in Nov. 2017 and March 2018 were found to contain negligible dissolved Fe(II) at depths to 140 m (unpublished MBMG data), as might be expected from the presence of DO at all depths. Iron in samples collected in Nov 2018 was primarily Fe(III) at depths of 1 and 17 m, but switched to Fe(II) at 67 and 139 m. More frequent sampling at additional depths is needed to draw firm conclusions on the current redox behavior of the dissolved Fe.

Copper and Zinc
Concentrations of dissolved Zn have been remarkably constant (≈ 600 mg/L) over time since 2002 (Fig. 7d). In contrast, 10 years of pumping and Cu recovery between 2003 and 2013 lowered Cu concentrations from ≈ 160 to ≈ 60 mg/L (Fig. 7c), where they have remained to the present day. It is not obvious why Zn and Cu concentrations should be poised at 600 and 60 mg/L, respectively. Based on Visual Minteq modeling, there are no common Zn(II), Cu(II), or Cu(I) solid phases close to saturation in the pit water. Also, sorption reactions cannot be the primary control on dissolved Zn and Cu concentrations, for two reasons. First, until recently, the pH of the pit water has been too low to expect much sorption of Cu 2+ or Zn 2+ . In the future,  some sorption of Cu 2+ onto schwertmannite could take place as pH values rise above 4.0 (Swedlund and Webster 2001). More importantly, if Cu and Zn were sorption-controlled, then their dissolved concentrations should have decreased as pH of the lake increased from 2.6 to > 4.0, bearing in mind the pH sensitivity of sorption of metal cations onto hydrous metal oxide surfaces (e.g., Dzombak and Morel 1990). It is more likely that the concentrations of Cu and Zn are sourcecontrolled. That is, there is a more or less constant influx of Cu and Zn to the lake from influent groundwater, pit-wall runoff, and dissolution of soluble salts as the lake levels rise, but there is no chemical "sink" for these metals. Given that the Berkeley Pit waters are close to saturation with basaluminite now, it is unlikely that Al concentrations will continue to increase. In fact, as pH continues to rise due to sludge disposal, it is more likely that large quantities of basaluminite will precipitate out of the water column. The reaction of interest can be written as follows:

Concentrations of dissolved
Considering the high concentration of dissolved Al (320 mg/L or 11.9 mmol/L), Reaction (3) is expected to buffer the pH of the lake for many years into the future.

Calcium and Sulfate
Gypsum is a major constituent of sediment in the Berkeley Pit lake (Twidwell et al. 2006), and calculated S.I. values for this mineral have always been close to equilibrium (Davis and Ashenberg 1989;Pellicori et al. 2005;Tucci and Gammons 2015). Samples collected in Nov., 2017 yield gypsum S.I. values of +0.05 ± 0.01 (see Supplemental Information file). Gypsum is also a major component of the lime-treatment sludge. Gypsum precipitation probably accounts for most of the decrease in (3) 4AlSO + 4 + 10H 2 O = Al 4 (OH) 10 SO 4 + 3SO 2− 4 + 10H + .
concentration of dissolved sulfate from ≈ 10,000 mg/L in 2002 to ≈ 7000 mg/L in 2017 (Fig. 8b). Some sulfate also would have precipitated as schwertmannite and jarosite. If all of the dissolved Fe in the pit precipitated as schwertmannite, then a stoichiometric decrease in the SO 4 concentration of the water column of 2.8 mmol/L (≈ 270 mg/L SO 4 ) would have occurred. This estimate is less than 10% of the observed decrease in SO 4 concentration (≈ 31 mmol/L), which supports the ideas that gypsum is the main sink for dissolved sulfate in the Berkeley Pit.
To maintain equilibrium with gypsum, one might presume from the common ion effect that a proportional increase in Ca 2+ concentration would have occurred as SO 4 2− concentrations decreased. However, such an increase has not happened; concentrations of Ca were 440 ± 20 mg/L in 2002 compared to 445 ± 5 mg/L in 2017. The explanation is that much (approximately a third) of the dissolved SO 4 in the 2002 pit lake was complexed with dissolved Fe(II) and Fe(III) in the form of FeSO 4 (aq) and FeSO 4 + ion pairs. Thus, despite a 30% decrease in total dissolved SO 4 concentration between 2002 and 2017, the concentration of "free" sulfate has remained about the same.

Phosphorus and Arsenic
The dominant forms of dissolved P and As in the Berkeley Pit lake are di-protonated phosphate (H 2 PO 4 − ) and arsenate (H 2 AsO 4 − ). Being anions, both of these species adsorb strongly onto schwertmannite and other hydrous ferric oxides that form at low pH (Dixit and Hering 2003;Manning and Goldberg 1996;Tucci and Gammons 2015). The massive precipitation of ferric precipitates between 2002 and 2017 resulted in almost complete removal of phosphate and arsenate from the water column (Fig. 8c, d). Concentrations of dissolved arsenic in March, 2018 were 10 ± 3 µg/L, essentially equivalent to the U.S. drinking water standard of 10 µg/L, and concentrations of dissolved phosphate were below the detection limit of 0.1 mg/L as P. It is possible that phosphate concentrations are also constrained by precipitation of strengite (FePO 4 •2H 2 O), although this cannot be quantitatively evaluated without accurate data on P concentration and Fe(II)/Fe(III) speciation. The pit-lake water also has very low concentrations of nitrate (0.3 mg/L as N, measured in March 2018). Overall, the lake has very low nutrient levels to support growth of algae and other microorganisms.

Other Solutes
Two other trace elements that have experienced a sharp decrease in concentration during this time frame are vanadium and chromium. In Nov., 2007, V and Cr concentrations in the deep pit lake were 241 and 77 µg/L, respectively. By March 2018, V was below detection (< 1 µg/L) and Cr had dropped to ≈ 6 µg/L. At the current Eh and pH conditions of the Berkeley Pit, dissolved V most likely occurs as H 2 VO 4 − (Huang et al. 2015), while Cr could be either hexavalent (HCrO 4 − ) or trivalent (Cr 3+ or Cr(OH) 2+ ). Similar to As and P, dissolved V and Cr were likely stripped out of the water column by adsorption onto secondary ferric precipitates. A smaller but significant decrease in concentration has occurred for uranium and the rare earth elements (REE). Gammons et al. (2003) reported concentrations of 820 to 880 µg/L U, 1050 to 1170 µg/L Ce and 480 to 500 µg/L Nd for pit-lake samples collected at different depths in July 1999, whereas samples collected in March 2018 contained 680 µg/L U, 707-737 µg/L Ce, and 300-314 µg/L Nd (GWIC 2019). Uranium adsorbs strongly onto hydrous ferric oxide at pH > 4 (Waite et al. 1994), and the lanthanides adsorb onto hydrous Fe or Al oxides at pH > 5 (Ayora et al. 2016;Verplanck et al. 2004). As the pH of the Berkeley Pit continues to rise, it is likely that REE and U will be completely stripped out of the water column by sorption processes. In contrast, concentrations of Cd, Co, and Ni have remained essentially unchanged in the past 20 years, averaging 2.0 ± 0.2, 1.7 ± 0.2, and 1.2 ± 0.2 mg/L, respectively. Dissolved Mn values have increased slightly, from about 240 mg/L in 2002 to about 280 mg/L in 2018 (GWIC 2019). Other solutes, such as Mo, Pb, Se, and W, have insufficient data to discern long-term trends.

Combined Impacts of Copper Recovery and Sludge Disposal
In a recent paper, Tucci and Gammons (2015) attributed the massive-scale precipitation of ferric solids observed in the Berkeley Pit to the then-active copper recovery circuit, which moved much larger volumes of water (roughly 50 × 10 6 L/day) compared to the volume of sludge (roughly 0.8 × 10 6 L/day). Tucci and Gammons downplayed the importance of sludge disposal, which was an oversight, as discussed below. To be sure, copper recovery did play a key role in the precipitation of ferric solids by mixing deep water with surface water and allowing complete oxidation of dissolved Fe(II) to Fe(III) (e.g., as the FeSO 4 + ion pair). After oxidation, most of the ferric iron precipitated as schwertmannite or jarosite, via the following reactions: 8FeSO + 4 + 1.25SO 2− 4 + 13.5H 2 O = Fe 8 O 8 (OH) 5.5 SO 4 1.25 (schwertmannite) Precipitation of jarosite and schwertmannite resulted in a net decrease in total acidity of the water column (9 equivalents on the left side of Reaction 4 vs. 6 on the right; 24 equivalents of acidity on the left side of Reaction 5 vs. 21.5 on the right). Provided these solids do not revert to goethite, this mineral acidity would be stored indefinitely in the sediment at the bottom of the lake (Tucci and Gammons 2015). However, the fact that pH increased between 2013 and 2018 when the Cu recovery circuit was not active indicates that oxidation of Fe(II) and precipitation of ferric solids was not the only reason for the decrease in acidity. Some external source of alkalinity, i.e. the sludge, was needed to drive these reactions to completion and to raise the pH above 4.
The disposal of alkaline lime-treatment sludge from the Horseshoe Bend treatment plant into the Berkeley Pit has been continuous from 2003 to the present day. Although the rate of sludge inflow has been small compared to the total volume of the pit lake (> 1.6 × 10 11 L), the effects (2.0 × 10 7 kg) of CaO, with the waste product being a two-stage, high density sludge. The first stage sludge is discharged at a pH in the range of 7 to 7.5, while the second stage is produced at a pH > 10.5 (Montana Resources, Inc., pers. commun.). Data on the chemical composition of each sludge are included in the Supplemental Information file, along with x-ray diffraction (XRD) data. Based on XRD, the dominant crystalline phase in the sludge is gypsum. The elements Al, Cu, Fe, Mg, Mn, and Zn are believed to be present as poorly crystalline hydroxides, possibly layered double hydroxides (Boclair and Braterman 1999)  to a pH endpoint of 2.5 indicated an alkalinity of almost exactly 1 eq/kg, or 1.14 eq/L (the sludge has a measured density of 1.12 g/mL; MBMG, unpublished data). This agrees with mass balance calculations made by combining the known mass of lime added at the treatment plant (e.g. 4.74 × 10 6 kg in the first quarter of 2015) and the sludge volume discharged (1.63 × 10 8 L in the same time period). At the pH endpoint of the lime treatment process (≈ 11), the contribution to total alkalinity from molecules that remain in solution, such as CO 3 2− or OH − , is very small (about 3 meq/L, or 0.3% of the total alkalinity). Most of the alkalinity in the sludge is stored as precipitated metals (Fe, Al, Zn, Mn, Cu, Mg, etc.…) in the form of amorphous hydroxides or other poorly crystalline phases. After disposal into the acidic pit lake, some of the solids in the sludge redissolve, releasing their "mineral alkalinity" back to the waters: where Me is any of the various metals in the sludge, and x is either 2 or 3. However, not all of the solid hydroxides would have redissolved into the pit lake. For example, at the present pH (≈ 4.1) of the Berkeley Pit, ferric hydroxide will remain insoluble, or will convert to another phase (e.g. jarosite or schwertmannite).
If we assume a constant rate of lime use over 15 years, the Horseshoe Bend plant consumed roughly 3 × 10 8 kg of lime, which equates to 1.1 × 10 10 moles of alkalinity (2 mol of alkalinity per mole of CaO). Assuming a total lake volume of 1.6 × 10 11 L and an average total acidity for the pre-2003 water column of 0.1 mol/L ( Fig. 5c; see also Tucci and Gammons 2015), there would have been around 1.6 × 10 10 mol of total acidity in the pit prior to interaction with the sludge. If all of the alkalinity in the lime wound up being stored as solid particles in sludge, and if these solids completely dissolved after disposal into the pit, then roughly two-thirds of the acidity of the pit lake could have been neutralized in 15 years. However, as stated above, some fraction of the sludge, in particular the ferric hydroxide, would not have reacted. Based on historical trends (Fig. 5c), the total acidity of the Berkeley Pit has actually dropped by roughly 35% to 40% in the period 2003 to 2018.
Because the flux of sludge into the pit has been more or less constant since 2003, the drop in acidity has been more or less linear (Fig. 5c). In contrast, the pH of the lake hardly changed between 2003 and 2013 (Fig. 5a). The constancy in pH is explained by the strong buffering effect of dissolved ferric iron precipitating as schwertmannite and jarosite (Reactions 4, 5; see also Nordstrom and Campbell 2014). Once most of the dissolved ferric iron was titrated out of the water column, the pH of the pit lake rose rapidly to > 4, and the lake shifted from being Fe-controlled to being Alcontrolled (Reaction 3). Inconveniently, much of the rise in pH occurred between 2012 and 2017, when monitoring was suspended for safety reasons.

What Lies Ahead?
The long-term remedial plan for the Berkeley Pit is to pump and treat the water to maintain a water elevation (critical water level) below the lowest point in the local groundwater/ surface water system to prevent the spread of contamination (EPA 2016). At the current filling rate of 10.8 million L/day, the critical water level will be reached in 2023. In anticipation of this, and to assess various treatment options, pumping and treating of Berkeley Pit water will begin in 2019. Water pumped from the Berkeley Pit will be treated at the lime-treatment plant currently treating Horseshoe Bend (HSB) water and the HSB water will be diverted to the active tailings pond. Because the current chemistry of the Berkeley Pit is different than the HSB chemistry, the sludge discharged to the pit will be different. The character of the sludge, and its potential impact on the future chemistry of Berkeley Pit, will depend on the treatment systems that are currently being assessed.
Although mine-water management of the Berkeley Pit has resulted in significant decreases in acidity, increases in pH, and decreases in dissolved arsenic, it is unlikely that concentrations of other toxic metals (e.g. Cd, Cu, Zn) will drop in the near future. The pH of the lake is presently buffered by precipitation of basaluminite (Reaction 3) or some other hydrous Al phase. It could take 10 years or more to titrate all of the dissolved Al out of the lake at current rates of sludge disposal. Once the Al is removed, pH is expected to rise to the next buffer, which could involve precipitation of Cu or Zn as hydroxide or mixed hydroxy-sulfate-carbonate minerals (e.g. brochantite, hydrozincite). For the foreseeable future, discouraging exposure of wildlife (e.g. migratory waterfowl) to the lake via hazing will remain a priority.

Conclusions
In the past 15 years, the total acidity of the Berkeley Pit has dropped by more than a third, the pH has increased from ≈ 2.5 to > 4.0, and the total dissolved Fe concentrations have plummeted from ≈ 1000 mg/L to < 5 mg/L. These changes were the result of two processes: (1) Cu recovery, which completely mixed the lake and allowed oxidation of Fe(II) to Fe(III); and (2) sludge disposal, which neutralized the "iron acidity" released by precipitation of schwertmannite and other ferric solids. With Fe removed, the pH of the lake quickly rose to values > 4.0 where it is presently buffered by precipitation of hydrous Al phases. Other solutes have experienced decreases in concentrations (e.g. As, P, V, Cr, SO 4 ), increases in concentrations (e.g. Mg, Mn), or negligible change (e.g. Ca, Cd, Co, Ni, Zn). In the past 2 years of monitoring, DO concentrations have been poised near 6 mg/L at all depths. The lake is presently holomictic, with seasonal mixing driven by wind events.
To pit-lake researchers, it may be heartening to consider that the Berkeley Pit is not an entirely hopeless case. The chemistry of the pit has improved in the past 15 years and future changes in treatment processes and water management may result in yet more changes. Although pumping and lime treatment will continue for decades (if not centuries), the slow but steady drop in acidity due to sludge disposal should translate into gradual water-quality improvement and a decrease in annual lime-consumption costs. Whether or not the chemistry of the lake will ever improve to the point where treatment could be safely discontinued is not known at this time.
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