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Carbon cloth supported lithiophilic carbon nanotubes@Ag skeleton for lithium anode via ultrafast Joule heating method

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Abstract

Regulating lithium deposition and stripping behavior during cycles is critical for constructing high-performance and stable lithium metal anodes (LMAs). Herein, a three-dimensional (3D) flexible hierarchical carbon clothes/carbon nanotube (CC/CNTs) host decorated with uniform lithiophilic Ag nanoseeds is obtained via a facile ultrafast Joule heating (UJH) method. Benefiting from high conductivity and large space for Li storage, the as-prepared CC/CNTs@Ag-Li anode displays favorable cycling efficiency and long-life stability. Moreover, the planted Ag lithiophilic sites can efficiently alleviate the growth of lithium dendrites. The synergistic effect of 3D conductive CC/CNTs and Ag nanoseeds endows the skeleton to guide the uniform deposition of Li during the plating/stripping process. The full cells assembled with LiFePO4 (LFP) cathode and CC/CNTs@Ag-Li anode present a high discharge capacity of 155.9 mA h g−1 at 0.1 C and a good capacity retention of 91.4% after 80 cycles at 1 C. The novel design strategy sheds new light on the synthesis of novel alkali metal anodes for energy storage.

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Acknowledgements

This work is supported by National Natural Science Foundation of China (Grant No. 52073252, 52103350, 52002052, U20A20253, 21972127, 22279116), Natural Science Foundation for Distinguished Young Scholars of Zhejiang Province (Grant No. LR20E020001), Science and Technology Department of Zhejiang Province (Grant No. 2023C01231), Key Research and Development Project of Science and Technology Department of Sichuan Province (2022YFSY0004), Natural Science Foundation of Zhejiang Province (Grant No. Q23E020046, LD22E020006 and LY21E020005), Foundation of State Key Laboratory of Coal Conversion (Grant No. J20-21-909), the state Key Laboratory of Silicon Materials (Grant No. SKL2021-12) and Key Laboratory of Engineering Dielectrics and Its Application (Harbin University of Science and Technology), Ministry of Education (Grant No. KFM 202202).

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Authors and Affiliations

  1. State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, People’s Republic of China

    Xinyi Shan, Yu Zhong, Lei Huang, Xinhui Xia & Jiangping Tu

  2. College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014, China

    Lei Huang, Yang Xia, Xinhui Xia & Xinping He

  3. Department of Engineering Technology, Huzhou College, Huzhou, 313000, People’s Republic of China

    Feng Cao

  4. Narada Power Source Co., No. 822 Wen’er Xi Rd, Hangzhou, 310030, People’s Republic of China

    Jiayuan Xiang

  5. Institute of Fundamental and Frontier Science, University of Electronic Science and Technology of China, Chengdu, 611371, China

    Yongqi Zhang

  6. Key Laboratory of Engineering Dielectric and Applications (Ministry of Education), School of Electrical and Electronic Engineering, Harbin University of Science and Technology, Harbin, 150080, China

    Minghua Chen

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  1. Xinyi Shan
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  2. Yu Zhong
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  9. Minghua Chen
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  10. Xinping He
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Correspondence to Yu Zhong, Jiayuan Xiang or Xinhui Xia.

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Shan, X., Zhong, Y., Huang, L. et al. Carbon cloth supported lithiophilic carbon nanotubes@Ag skeleton for lithium anode via ultrafast Joule heating method. J Solid State Electrochem 27, 1391–1398 (2023). https://doi.org/10.1007/s10008-023-05448-3

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