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Lithium storage performance of Sn-MOF-derived SnO2 nanospheres as anode material

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Abstract

In this work, a spherical Sn-MOF precursor was synthesized through hydrothermal method using 1,3,5-benzenetricarboxylic acid (H3BTC) as the organic ligand. Sn-MOF-200, Sn-MOF-250, and Sn-MOF-300 were obtained at different annealing temperatures. Among them, the Sn-MOF-250 composite obtained by annealing at 250 ℃ was stable in structure, and the specific surface area is 118.8 m2 g−1. The specific capacity of Sn-MOF-250 can be maintained up to 846.6 mA h g−1 after 110 cycles at the current density of 100 mA g−1 when used as the anode material of lithium-ion battery. The excellent cycling performance of Sn-MOF-250 is due to the special framework structure of metal–organic frameworks (MOFs). After combining with Sn ion, the metal–organic coordination compound formed can greatly improve the diffusion and transport efficiency of lithium ion. This facile synthesis strategy has a certain application prospect in the development of high-performance lithium-ion battery anode materials.

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All data generated or analyzed during this study are included in this published article.

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Funding

This work was supported by the Scientific Research Program of Hebei Province (No. 16273706D) and the Basic Innovation Team of Tangshan (2017).

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Authors and Affiliations

  1. College of Materials Science and Engineering, North China University of Science and Technology, Hebei, 063210, Tangshan, China

    Hang Fu, Chonghua Shi, Jiajin Nie, Jianqiang Xie & Shaowei Yao

  2. Key Laboratory of Inorganic Material of Hebei Province, Tangshan, 063210, China

    Shaowei Yao

Authors
  1. Hang Fu
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  2. Chonghua Shi
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  3. Jiajin Nie
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by Chonghua Shi, Jiajin Nie, Jianqiang Xie, and Shaowei Yao. The first draft of the manuscript was written by Hang Fu, and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Jianqiang Xie or Shaowei Yao.

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Fu, H., Shi, C., Nie, J. et al. Lithium storage performance of Sn-MOF-derived SnO2 nanospheres as anode material. J Solid State Electrochem 26, 2919–2928 (2022). https://doi.org/10.1007/s10008-022-05298-5

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  • DOI: https://doi.org/10.1007/s10008-022-05298-5

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