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Synthesis and photo-physicochemical properties of phthalocyanines substituted with sterically hindered phenol

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Abstract

Synthesis of the Zn, Mg, and LuOAc phthalocyanines (Pcs) containing sterically hindered 2,6-di-(tert-butyl)-4-methylphenol group were successfully achieved by the cyclotetramerization of the 4-[2,6-di-(tert-butyl)-4-methylphenoxy]phthalonitrile. All compounds were fully characterized by 1H and 13C NMR, infrared, elemental analysis, UV–Vis, and MALDI-TOF spectral data. The photo-physicochemical properties of the targeted molecules include fluorescence quantum yields, lifetimes, singlet oxygen generation, and photodegradation quantum yields were recorded in dimethyl sulfoxide.

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Acknowledgements

We are gratefully acknowledge the financial support of this research from Gebze Technical University.

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Authors and Affiliations

  1. Department of Chemistry, Gebze Technical University, Kocaeli, Turkey

    Kevser Harmandar, Esra N. Kaya, Mehmet F. Saglam, Ibrahim F. Sengul & Devrim Atilla

Authors
  1. Kevser Harmandar
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  2. Esra N. Kaya
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  3. Mehmet F. Saglam
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  4. Ibrahim F. Sengul
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  5. Devrim Atilla
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Corresponding authors

Correspondence to Mehmet F. Saglam or Devrim Atilla.

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Harmandar, K., Kaya, E.N., Saglam, M.F. et al. Synthesis and photo-physicochemical properties of phthalocyanines substituted with sterically hindered phenol. Monatsh Chem 152, 1561–1569 (2021). https://doi.org/10.1007/s00706-021-02864-x

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  • DOI: https://doi.org/10.1007/s00706-021-02864-x

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