Late Palaeozoic extensional volcanism along the northern margin of Gondwana in southern Turkey: implications for Palaeotethyan development

The Late Palaeozoic–Early Mesozoic Tethyan development of the Eastern Mediterranean region remains debatable, especially in Turkey, where alternative northward and southward subduction hypotheses are proposed. Relevant to this debate, new whole-rock geochemical data are provided here for early Carboniferous (Late Tournaisian-Late Visean; c. 340–350 Ma) tuffaceous sedimentary rocks within the Çataloturan thrust sheet (Aladağ nappe), eastern Taurides. The tuffs accumulated from evolved alkaline volcanism, variably mixed with terrigenous and radiolarian-rich sediments. In addition, Late Palaeozoic meta-volcanic rocks, c. 150 km farther NE, within the Binboğa (= Malatya) metamorphics (a low-grade high-pressure unit), are indicative of a within-plate setting. An impersistent geochemical subduction signature in these volcanics may represent an inherited, rather than contemporaneous, subduction influence, mainly because of the absence of a continental margin arc or of arc-derived tuff. Both the Binboğa metamorphics and the Çataloturan thrust sheet (Aladağ nappe) restore generally to the north of the relatively autochthonous Tauride carbonate platform (Geyik Dağ), within the carbonate platform bordering north-Gondwana. The Çataloturan thrust sheet is interpreted, specifically, as a c. E–W, deep-water, volcanically active rift that progressively infilled. Regional geological evidence suggests that melange units (Konya Complex, Afyon zone), Teke Dere unit, Lycian nappes), and Chios–Karaburun melange, E Aegean) accreted to the north-Gondwana continental margin during the late Carboniferous; this was coupled with localised calc-alkaline granitic magmatism (Afyon zone of Anatolide crustal block). We propose an interpretation in which Late Devonian–Carboniferous alkaline intra-plate volcanism relates to extension/rifting along the north-Gondwana margin. In contrast, the melange accretion and granitic magmatism could relate to short-lived late Carboniferous southward subduction that accompanied the diachronous closure of Palaeotethys.


Introduction
The geological development of the northern margin of Gondwana, in Turkey, during the Late Palaeozoic is critical to an understanding of the wider Tethyan region. Three general (partly overlapping) tectonic models are currently proposed that have implications for the northern margin of Gondwana during Late Palaeozoic time, when Palaeotethys was open, with Eurasia to the north.
Model 1 Palaeotethys existed since Early Palaeozoic (Fig. 1ai) and later, during Devonian-Carboniferous, subducted southwards beneath the northern margin of Gondwana (Fig. 1aii). This process led to the construction of the Sakarya magmatic arc. Southward subduction triggered rifting of a back-arc basin to the south which became the Southern Neotethys during the Triassic (Fig. 1aiii). In Turkey, the 1 3 northern margin of Gondwana effectively formed a continental margin arc during the Late Palaeozoic. The arc was located along the borderland or off-margin separated by a marginal basin. Subduction of Palaeotethys terminated by collision of the rifted Cimmerian continent with Eurasia during the Early Jurassic. This was followed by opening of a Mesozoic ocean basin to the north (northern Neotethys). The above interpretations are based on the south-dipping tectonic models of Şengör and Yılmaz (1981), Şengör et al. (1984), Göncüoğlu et al. (2000) and Romano et al. (2006).
Model 2 The Rheic ocean opened, probably during the Ordovician (Fig. 1bi). This ocean subducted southwards beneath Gondwana during Late Silurian-Devonian, detaching a continental strip ('ribbon continent') from Gondwana to create Palaeotethys (Fig. 1bi). The rifted Gondwana fragment drifted northwards and accreted to Eurasia (future Anatolides) by Late Devonian. This was followed by construction of the continental margin arc (Sakarya arc) in the Pontides (Fig. 1bii). The Sakarya arc rifted during the Triassic to create a wide back-arc (marginal) oceanic basin in the north, close to Eurasia (Küre/Pindos back-arc basin). As this ocean widened, the frontal arc, fore-arc basin and accretionary prism migrated southwards towards Gondwana. Gondwana rifted during the Permian to create the Southern Neotethys, and as a result an elongate crustal sliver (Cimmerian continent) drifted northwards towards Eurasia (Fig. 1biii). The northward-moving Cimmerian continent collided with the southward-migrating Eurasian continental fore-arc fragment during the latest Triassic, finally closing Palaeotethys in Turkey. This interpretation is based on with mainly northward subduction of Palaeotethys, but also localised southward subduction during the late Carboniferous. See text for explanations and literature citations the tectonic models of Stampfli et al. (2001), Stampfli and Borel (2002), Eren et al. (2004), Stampfli and Kozur (2006), Stampfli et al. (2013), Moix et al. (2008Moix et al. ( , 2013. In a modification of the above back-arc basin interpretation, in Greece (S Aegean) collision of the southward-migrating Eurasian active margin fragment with the rifted 'Cimmerian' continent (Phyllite-Quartzite unit sensu stricto) is put at Middle Triassic (Ladinian) rather than latest Triassic (Zulauf et al. 2013(Zulauf et al. , 2015(Zulauf et al. , 2016(Zulauf et al. , 2018. In all variants of the above interpretation, the north margin of Gondwana remained passive throughout the Palaeozoic onwards. Model 3 The Taurides and Anatolides remained along the northern margin of Gondwana during the Palaeozoic (Robertson andDixon 1984, 2008;Robertson et al. 2004;Okay et al. 2006;Özbey et al. 2013). The Sakarya arc was constructed along the southern margin of Eurasia related to northward subduction of Palaeotethys Robertson 1993, 1997;Cocks and Torsvik 2006;Okay et al. 2006Okay et al. , 2008Linnemann et al. 2007;P.A. Ustaömer et al. 2012;Ustaömer et al. 2013;Rolland et al. 2016;Topuz et al. 2019;Uğurcan et al. 2019). Late Carboniferous melanges and related units within the Anatolides (Konya Complex) and the Taurides (Lycian nappes), and also in the Karaburun Peninsula (E Aegean) are interpreted as fragments of a regional subduction complex that accreted to the northern margin of Gondwana (Robertson and Ustaömer 2009a). Late Carboniferous granitic rocks cutting the Afyon zone (Anatolides) represent continental margin arc magmatism Ustaömer et al. 2020). The interpreted accretion and continental margin arc magmatism along both the Eurasian and Gondwana margins points to double subduction of Palaeotethys (Fig. 1cii). Limited subduction is inferred during the late Carboniferous (c. 320-300 Ma), either generally southwards (Robertson andUstaömer 2009a, b, 2011;Ustaömer et al. 2019), or generally westwards (Okay and Topuz 2017). Palaeotethys closed throughout the south Aegean-Balkan region before the Permian Zanchi et al. 2003;Okay and Topuz 2017), coupled with right-lateral displacement near the Eurasian active margin (Fig. 1cii). The northern margin of Gondwana rifted to open the Neotethyan İzmir-Ankara-Erzincan ocean during the Triassic. With further northward subduction, the Karakaya Complex accreted, including seamounts ( Fig. 1ciii) (Pickett and Robertson 1996;P.A. Ustaömer et al. 2012;Ustaömer et al. 2016a). In model three, the northern margin of Gondwana was passive during the Palaeozoic, but switched to active during the Late Carboniferous; afterwards, the passive margin resumed until the collisional tectonics of the Late Cretaceous-early Cenozoic.
The geological development of the northern margin of Gondwana is obviously critical to help distinguish between the contrasting interpretations. Here, we consider some new and published information concerning Late Palaeozoic volcanogenic rocks within the Tauride and Anatolide crustal units of central and eastern Anatolia. We also summarise and re-evaluate the tectonic setting of the Late Carboniferous melanges and granitic rocks within the Anatolides (Afyon zone). Because these units are allochthonous we also need to restore the later Mesozoic-Cenozoic contractional tectonics that affects them in order to infer the Late Palaeozoic palaeogeography.

Regional geology
There are two main occurrences of Late Palaeozoic volcanogenic rocks within the Geyik Dağ (Tauride platform), one in the central Taurides and one in the eastern Taurides (Fig. 2).
First, there is a sparse record of Late Palaeozoic volcanism within the unmetamorphosed central Taurides, mainly in the form of localised tuffaceous and volcaniclastic sediments, and also rarely as lavas (Göncüoğlu et al. 2007). The volcanogenic rocks occur widely in the west-central Taurides, within the Sultan Dağ unit (Fig. 2), which is interpreted as part of the relatively autochthonous Geyik Dağ. Part of the succession in the Sultan Dağ (Kuz Member of the Harlak Formation) comprises grey-to violet-coloured slates, with occasional layers and lenses of fine-grained, chloritic, volcaniclastic sediments, interpreted as tuffs, together with basic lavas and grey-to green intraformational conglomerates (pebblestones) (Fig. 3 log 1). This volcanogenic succession is dated as early Carboniferous (Mississippian), specifically early Tournaisian-late Visean, based mainly on conodonts (Göncüoğlu et al. 2007). Secondly, there is a very small outcrop of basaltic extrusive rocks within the extension of the Geyik Dağ into the eastern Taurides, in the Feke area, of inferred Late Devonian or early Carboniferous age (Dalkılıç 2009;Çimen 2018) (Fig. 2).
Well-preserved tuffaceous sediments, for which we provide new sedimentological and geochemical evidence, occur within a thrust sheet making up the regional Aladağ unit in the easternmost central Taurides, known as the Çataloturan thrust sheet (Tekeli 1981;Tekeli et al. 1984;Balcı 2010;Alan et al. 2007) (Fig. 2). The succession is well dated as early Carboniferous, based mainly on conodonts and radiolarians (Göncüoğlu et al. 2007).
Late Palaeozoic meta-basic igneous rocks occur widely within the Binboğa metamorphic unit of the Eastern Taurides, which is generally correlated with the larger scale Malatya-Keban platform (MTA 2011) (Fig. 2). The metavolcanic rocks of the Binboğa unit stratigraphically underlie palaeontologically dated Permian platform carbonates (Perinçek and Kozlu 1984;Bedi et al. 2009Bedi et al. , 2012Bedi and Yusufoğlu 2018). Meta-igneous rocks are also present as isolated dykes farther east, where they transect the Keban metamorphic unit (part of the Malatya-Keban 1 3 platform). The cross-cut metamorphic rocks are dated, palaeontologically, as Carboniferous. Dykes are absent from the overlying Permian and younger rocks suggesting a pre-Permian age for these dykes (Kaya 2016).
In this paper, we use the IGC International Chronostratigraphic Chart (Cohen et al. 2020).

Methods and materials
For the tuffaceous sedimentary rocks of the Tauride Çataloturan thrust sheet, a section was logged; representative samples were studied petrographically, and six samples were chemically analysed for major and trace elements including rare earth elements (REEs). Petrographic study indicated the presence of abundant tuffaceous material, suggesting that useful information could be obtained geochemically for the associated volcanism.
Following petrographic study, four samples of aphyric or sparsely feldspar-phyric metabasalt from one section of the meta-volcanic rocks of the Binboğa metamorphic unit were found to be suitable for tectonic discriminant analysis, using a combination of major, trace and rare earth elements (REEs). However, petrographic study of the meta-basalts from another section showed that these are highly feldspar-porphyritic and so ill-suited to tectonic discrimination.
The analysis of major and trace elements and REEs (see Table 1) was carried out at Acme Analytical Laboratories Ltd., Vancouver, Canada. Major element contents were determined from a LiBO 2 fusion by ICP-ES by using 5 g of sample pulp. Trace element and REE contents were determined from a LiBO 2 fusion by ICP-MS by using 5 g of sample pulp. Detection limits range between 0.01 and 0.04 wt% for major oxides, between 0.01 and 0.1 ppm for trace and rare earth elements. The relative standard deviation for the REE is ~ 5% and for all other trace elements is up to 10%, with quality control using international geostandards.

Specific objectives
Our specific objectives are as follows: (1) To determine the setting of deposition and provenance of the early Carboniferous tuffaceous sediments of the Tauride Çataloturan thrust sheet; (2) To discriminate the tectonic setting of the volcanogenic contribution to the Çataloturan succession; (3) To determine the composition and magmatic affinity of the meta-volcanic rocks of the Late Palaeozoic Binboğa (Malatya) unit; (4) To compare the compositions of the different Late Palaeozoic volcanogenic units, including a small occurrence within the eastern Tauride autochthon (Feke area); (5) To review and re-evaluate information for the late Carboniferous melanges and granitic magmatism, particularly from the metamorphosed Afyon zone (Konya Complex) and from the unmetamorphosed Lycian nappes (Teke Dere unit) (Fig. 2). (6) Finally, the assembled information and interpretations are used to help understand the geological development of the northern margin of Gondwana, and thereby help to test the alternative tectonic models of Palaeotethys during the Late Palaeozoic ( Fig. 1).

Stratigraphy and sedimentology of tuffaceous sediments
The tuffaceous sediments are located within the Çataloturan thrust sheet, one of five main thrust sheets exposed in the Aladağ area (Fig. 2). These thrust sheets represent emplaced parts of the Mesozoic Tauride carbonate platform and its Late Palaeozoic substratum (Blumenthal 1952;Tekeli 1981;Tekeli et al. 1984;Alan et al. 2007;MTA 2011). The structurally lowest unit, the Yahyalı thrust sheet, includes evidence of high pressure-low temperature metamorphism (HP-LT) (Pourteau et al. 2010). The Carboniferous succession in the Çataloturan thrust sheet is dated as Mississippian (early Carboniferous) (Aksay 1980;Işık 1981). The succession studied, as exposed in the Nohutluk Tepe section (Figs. 3b,4a,b), is specifically dated as late Tournaisian-late Visean using conodonts and radiolarians (Okuyucu and Vachard 2006;Göncüoğlu et al. 2007 and references). The Nohutluk Tepe section begins with organic carbon-rich black shales and sandstones, of inferred Total Fe is reported as FeO* and "<" means below detection limit. See "Methods and materials" for analytical methods. The data for the standard is from ACME, together with analytical precision.
Intercalations of greenish radiolarite occur throughout the lower to mid parts of the succession (Fig. 5e). The lower c. 25 m of the succession includes numerous intercalations of greenish, finely laminated volcanogenic mudstones and siltstones, together with rare fine-to locally mediumgrained volcaniclastic sandstones, mainly near the base of the succession (Fig. 5f). The finer-grained volcanogenic facies are commonly partly silicified. The tuffaceous material becomes finer-grained and decreases up-section, whereas redeposited neritic carbonate increases until the succession becomes shallow marine near the top.

Petrography and geochemistry of tuffaceous sediments
The thickest-bedded, relatively homogeneous volcaniclastic beds (individually up to 0.8 m thick) that occur near the base of the succession were sampled for petrographic and chemical analysis (Fig. 4c).
In thin section, the volcaniclastic sandstones are dominated by abundant angular plagioclase grains, altered volcanic glass (shards), together with monocrystalline quartz, set in a chloritized matrix (Fig. 5g). Grains of altered basalt and felsic volcanic rocks are visible in the coarsergrained facies. There is a patchy calcite spar cement. The volcaniclastic siltstones are composed mostly of feldspar, quartz and glass shards (altered), together with tiny muscovite laths, set in a greenish chloritic and calcareous matrix (Fig. 5h). Outlines of radiolarian tests are occasionally visible. The interbedded limestones, interpreted as calciturbidites, contain abundant echinoderm debris (e.g., spines), shell fragments, grains of basalt (with feldspar microphenocrysts) and common plagioclase. The petrography indicates that there was a strong-to dominant volcaniclastic input to these sediments.
The available geochemical data (Table 1) were plotted and interpreted using well-known compositional and discrimination diagrams that are designed for sedimentary or igneous rocks. Complete analyses (including REEs) of Carboniferous Tauride sandstones from other areas are not available. However, four analyses of Ordovician Tauride sandstones from the Antalya Complex (Antalya nappes) in the Alanya window, Southern Turkey , were plotted for comparison. The Ordovician sandstones are chemically similar to Ordovician, Devonian, Carboniferous and Triassic shales from the Hadim (Aladağ) and Bolkar nappes of the Central Taurides (Mackintosh and Robertson 2012a). Detrital zircon geochronology, including evidence from late Carboniferous sandstones of the Yahyalı thrust sheet, Aladağ unit, indicates provenance from NE Gondwana (Ustaömer et al. 2020 and references). The Ordovician sandstones plotted are, therefore, indicative of the NE Gondwana provenance that does not include tuffaceous sediments.
On the Log (SiO 2 /Al 2 O 3 ) vs. Log (Na 2 O/K 2 O) diagram (after Pettijohn et al. 1972), the Çataloturan unit tuffaceous samples plot as greywacke and litharenite (Fig. 6a), and as wacke, litharenite and arkose on the Log (SiO 2 /Al 2 O 3 ) vs. Log (Fe 2 O 3 /K 2 O) diagram (after Herron 1988) (Fig. 6b). On the Th/U vs. Th plot (after McLennan et al. 1993), the samples plot in the upper crust area, with indications of mild, but variable weathering (Fig. 6c). On the Al 2 O 3 vs. CaO + Na 2 O vs. K 2 O CIA (chemical index of alteration) diagram (after Nesbitt and Young 1984), the tuffaceous sediments plot in the vicinity of basalt (Fig. 6d). The lack of evidence of strong weathering is consistent with an origin as gravityreworked fallout tuff. On the average upper continental crust (UCC)-normalised plot, the samples are markedly enriched in Nb, Ta, La, Ce, Nd, Hf, Zr, Sm, Tb, Y, Tm and Yb, but depleted in Ba, Sr, K, P and Ti (Fig. 6e), consistent with their variable mixed volcanogenic, terrigenous and biogenic composition. On a shale-normalised REE plot, the samples have relatively flat patterns of REEs, similar to terrigenous shales, for example the North Atlantic shale composite (NASC) (Gromet et al. 1984), or the PAAS (post-Archean average Australian shale composite (Taylor and McLennan 1985). The marked negative Eu anomaly (Fig. 6f) reflects the abundance of plagioclase, as seen in thin sections (Fig. 5g, h). On the La vs. Th vs. Sc plot (after McLennan and Taylor 1984), the samples are strongly La-enriched, more so than upper continental crust (UCC) and typical of continental shale (PAAS) (Fig. 6g), which corresponds to the abundance of La-enriched volcanogenic material. On the Th/Sc vs. Zr/Sc plot (after McLennan et al. 1993), the samples are strongly enriched in Zr and Th, compared to basalt, andesite, or UCC (Fig. 6h). The relative enrichment in Th and Zr represents the high volcanogenic content.
The petrographic evidence, coupled with the relatively high, e.g., Zr and Th, indicates that the Çataloturan unit sediments are rich in volcanogenic material and are, therefore, suitable for plotting on several igneous rock discrimination diagrams. On the Zr/Ti vs. Nb/Y diagram (after Pearce 1996) the samples plot mainly in the trachyte to alkali rhyolite field (Fig. 6i). On the Nb vs. Y plot (after Pearce et al. 1984), compared to different granites, the samples plot in the within-plate granite field (Fig. 6j). On the chrondrite-normalised REE plot, the samples show a marked enrichment in light rare earth (LRE) elements versus heavy rare earth (HRE) elements. The strong negative Eu anomaly (Fig. 6k) confirms the abundance of plagioclase in the source magma (Rollinson 1993). Last, on the Th/Y vs. Ta/Yb diagram (after Pearce 1982), the samples mainly plot in the within-plate volcanic zones, overlapping with MORB and WPB areas (Fig. 6l).
On all of the above plots the Ordovician sandstones from the Tauride Antalya unit are consistent with the composition of terrigenous shale (e.g., Fig. 6e-h), andesite and basaltic andesite (Fig. 6i), volcanic arc granite + syn-collisional granite ( Fig. 6j) and active continental margins (Fig. 6l). The sandstones are variably altered (Fig. 6a, c, d). The source of the sandstones was the Neoproterozoic-Cambrian basement of NE Gondwana, quite different from that of the Carboniferous tuffaceous sediments of the Çataloturan unit. This supports the use of igneous tectonic discrimination diagrams to interpret the origin of the tuffaceous sediments.

Interpretation of the tuffaceous sediments
The tuffaceous sediments accumulated in relatively deep water (100 s m) in a lower slope or proximal base-ofslope setting during the early Carboniferous (late Tournaisian-early Visean) (Göncüoğlu et al. 2007). The petrography indicates that the sediments have a high volcanogenic content, as indicated by the abundance of altered glass (tephra), plagioclase and volcanic rock fragments. However, there is a subordinate contribution of siliciclastic (terrigenous) material, as represented by polycrystalline (metamorphic) quartz and mica, together with minor amounts of biogenic material, mostly radiolarians. The normal-graded tuffs were ejected from a volcanic centre some distance away, settled to the seafloor and were then redeposited by turbidity currents. Fine-grained tuffaceous laminae are likely to be the product of direct ash fallout. Volcanism possibly began with an explosive pulse and then waned, judging from the upward general decrease in the relative abundance and grain size of the tuffaceous sediments. The interbedded calciturbidites are dominated by shallow-water-derived carbonate detritus and represent different depositional events. However, they include detrital volcanic grains. This suggests that the tuffaceous sediments relate to volcanism within, or adjacent to, 1 3 the deep-water basin rather than being wind-carried from far away.
The chemical data confirm that the tuffaceous sandstones are relatively mafic, similar to greywackes and some litharenites ( Fig. 6a, b). The compositions are enriched in REEs compared to average terrigenous shales (NASC or PAAS). The strong relative enrichment in LILEs on the chrondrite-normalised plot (Fig. 6k) is similar to that of within-plate volcanics (Fig. 6l). The relative enrichment in Zr (Fig. 6h) is also consistent with 'enriched' alkaline volcanism.
In summary, the early Carboniferous tuffaceous sediments are interpreted as the product of evolved alkaline volcanism, variably mixed with continentally derived silt and siliceous biogenic material.

Late Palaeozoic meta-basic igneous rocks of the Binboğa metamorphic unit
Meta-basaltic extrusive rocks and minor meta-intrusive rocks are mapped within the overall Late Palaeozoic succession in eastern Anatolia (Figs. 2, 7). Regionally, the metamorphic rocks have three main outcrops, separated by major neotectonic left-lateral faults (MTA 2011). The outcrop to the northwest, the main area of interest here, is mapped as the Binboğa Metamorphics (Perinçek and Kozlu 1984;Özgül and Kozlu 2002). The largest metamorphic outcrop, which is located south and southwest of Malatya, is termed the Malatya Metamorphics. The outcrop to the east and southeast of Malatya is known as the Keban Metamorphics. Prior to neotectonic left-lateral fault displacement, these three outcrops formed parts of a regional-scale metamorphic unit (Malatya-Keban platform) (MTA 2011). The overall succession has some similarities with the Afyon zone (Anatolides) to the west, for example the presence of up-to low high-pressure metamorphism (Bedi et al. 2009;Bedi and Yusufoğlu 2018;Robertson et al. 2021a). However, there are some significant differences with the Afyon zone, notably the presence of Late Cretaceous granitic rocks, only in the Malatya-Keban platform including the Binboğa metamorphics (Parlak 2006;Rızaoğlu et al. 2009;Karaoğlan et al. 2016).
The Binboğa metamorphic outcrop includes widespread intercalations of meta-basic igneous rocks, mainly amphibolite, within a mixed carbonate-siliciclastic shelf succession (Yoncayolu Formation) (Perinçek and Kozlu 1984;Bedi et al. 2009). The exposures studied here are located in the relatively remote Binboğa Mountains that remain to be mapped in detail. Interbedded meta-carbonates have so far yielded only Eotuberitina sp. and Tetraxis sp. (benthic foraminifera), suggestive of a Late Devonian-Carboniferous age. The overlying recrystallised limestone succession (Çayderesi Formation) includes a rich assemblage of large foraminifera, indicating a Late Permian age (Perinçek and Kozlu 1984;Bedi et al. 2009). A Carboniferous age of the volcanism is likely, similar to the inferred age of the dykes in the Keban metamorphics further east (see above). However, a Devonian age cannot be excluded in view of the rare occurrences of Late Devonian or early Carboniferous volcanics within the relatively autochthonous succession in the Eastern Taurides (Feke area) (Dalkılıç 2009;Çimen 2018) (see below).

Stratigraphy of the meta-volcanics
Two sections of the Binboğa metamorphic unit were studied. The first section (Fig. 7, log 1) exposes basaltic lava flows, individually up to tens of metres thick ( Fig. 5i-l). The meta-lavas are strongly foliated, sheared and folded and are interbedded with meta-quartz sandstones/siltstones and recrystallised limestones (marble). There are also occasional intraformational conglomerates and also slumped beds that together indicate reworking and soft-sediment instability. Measurements of fold axial planes and fold hinges indicate deformation about c. E-W axes (Robertson et al. 2021b). The second section (Fig. 7, log 2), located c. 10 km to the northwest, is similar although the meta-lavas there are highly feldspar-phyric and so unsuited to chemical analysis.

Petrography and geochemistry of the meta-volcanics
In thin section, the meta-lava exhibits granoblastic to nematoblastic textures, with preferred orientation of hornblende (65-85%) and plagioclase (15-20%). Dark hornblendedominated layers (Fig. 8a, b) typically alternate with lighter bands, lenses and stringers of plagioclase, epidote and minor quartz (Fig. 8c, d). Plagioclase is extensively altered to calcite, albite and sericite. The mineralogy of the samples studied suggests greenschist to lower amphibolite facies conditions. However, low high-pressure metamorphism, in Field photographs and photomicrographs of the early Carboniferous tuffaceous sediments from the Nohutluk section, Çataloturan thrust sheet (a-h), and of the Late Palaeozoic meta-basaltic volcanics of the Binboğa (= Malatya) metamorphic unit in the E. Taurides (i-l). a Lower part of the early Carboniferous Nohutluk Formation. The section is dominated by very well-bedded, redeposited limestones (packstone/grainstone), with greenish volcaniclastic layers, mainly near the base (thickness of strata shown = c. 35 m) (view to SE); b Lower part of the section, as a; note the greenish volcaniclastic layer near the base (c. 80 cm thick); c Well-bedded, fine to mediumgrained packstone/grainstone; beds are sharp-based, weakly normalgraded, parallel laminated and variably bioturbated; part of the outcrop in b; pen for scale; d Normal-graded thin beds of packstone/ grainstone, intercalated with micritic limestone, with dark organic carbon-rich laminae and nodules of black chert of diagenetic replacement origin; part of the section in b; pen for scale; e Intercalation of green tuffaceous siltstone (partially silicified). The intercalation comprises at least three depositional events. The pale brown interbed represents redeposited packstone/grainstone; part of the section in b; hammer for scale; f thin bed of largely silicified, greenish grey finegrained tuffaceous siltstone, interbedded with redeposited packstone/ grainstone; part of the section in b; hammer head for scale; g Photomicrograph of relatively coarse-grained, redeposited volcaniclastic sandstone; contains abundant angular grains of plagioclase, together with volcanic glass (isotropic) and partial diagenetic replacement by calcite spar; part of section in b; h typical greenish, fine-grained tuffaceous siltstone with small angular feldspar crystals and volcanic glass shards (isotropic); also poorly preserved radiolarians in a chloritic matrix, partly replaced by calcite; part of section in b; i Greenish foliated amphibolite of the Binboğa metamorphic unit, with folded metasomatic quartz vein (near base); 15 km WSW of Afşin, E Taurides; hammer for scale; j Amphibolite (partly replaced by chlorite), with deformed feldspar porphyroblasts (same section as i); k Foliated amphibolite, with deformed metasomatic grains and segregations (same section as i); l Dark-coloured foliated amphibolite, with feldspar-rich layers; cut by quartz veins at right angles (same section as l); pen nib for scale ◂ Fig. 6 Chemical analyses of the early Carboniferous tuffaceous sedimentary rocks of the Nohutluk Formation, Çataloturan thrust sheet (Tauride allochthon), plotted on well-known sedimentary and igneous rock discrimination diagrams. Published Ordovician terrigenous sandstones from the Taurides (Antalya Complex) are plotted for comparison (from Robertson et al. 2020 Rudnick and Gao (2003) and Hu and Gao (2008); f REE elements normalized to North Atlantic shale composite (NASC); nor-malising values from Gromet et al. (1984); g La vs. Th vs. Sc plot; the values of potential source rocks (grey squares) are from McLennan and Taylor (1984); h Th/Sc vs. Zr/Sc plot (after McLennan et al. 1993). Black solid circles indicate the average compositions of granite, andesite and basalt (after Condie 1993). Grey square represents the average compositions of UCC (Rudnick and Gao 2003;Hu and Gao 2008). The purple arrow indicates the trend from basic to felsic rock, and the green arrow the sedimentary recycling trend (i.e., zircon addition); i Zr/Ti vs. Nb/Y volcanic rock classification diagram (after Pearce 1996); j Nb vs. Y plot for discrimination of granitic rocks (after Pearce et al. 1984); k REE concentrations, normalised to chondrite; normalising values from Sun and McDonough (1989); l Th/Yb vs. Ta/Yb diagram (after Pearce 1982). See text for explanation places, is suggested by reports of glaucophane within the Malatya Metamorphics (Bedi et al. 2009). Low-grade metamorphism, recorded by Bozkaya et al. (2007), may represent retrograde metamorphism.
In addition, a rare clast of meta-basalt (M13.68) was analysed from Late Cretaceous meta-debris flow-deposits in the uppermost part of the stratigraphy within the Binboğa metamorphics. This unit is known as the Karaböğürtlen Formation, with its type area in the western Taurides (Muğla region) (MTA 2011). The Karaböğürtlen Formation is inferred to be of Late Cretaceous age, mainly based on occurrences of rudist bivalves (Bedi et al. 2009;Robertson et al. 2021a). The Karaböğürtlen Formation commonly includes thin-to medium-bedded greenish to brownish, foliated, porphyritic metabasic igneous rocks between schists and calcschists. Most of these are lava flows but some could represent dykes and/or sills (Bedi et al. 2009).
We observed scattered meta-basaltic clasts (up to 10 s cm in size) within meta-matrix-supported conglomerates during our study, near Afşin, but no in situ lava flows in this area (Fig. 7). The analysed meta-lava clast came from a depositional unit of matrix-supported conglomerate, c. 2.5 km NE of Afşin (near Abaz Tepe, GPS: 37S 0329013/4236061). This meta-conglomerate is dominated by sub-rounded boulders of marble (up to several m in size), with subordinate meta-lava clasts. Associated units of matrix-supported conglomerate are up to 10 m thick, individually. The Karaböğürtlen Formation includes large-scale debris-flow deposits ('olistostromes') including the unit sampled. The formation is interpreted as part of a regional-scale flexurally-controlled foredeep, related to Late Cretaceous ophiolite emplacement (Robertson et al. , 2021a. The analysed meta-basalt clast was probably derived by reworking of basaltic flows within the Late Cretaceous succession. However, derivation from deeper-level Late Palaeozoic volcanic rocks cannot be excluded. LOI (loss on ignition) values in the analysed samples range from 0.8 to 7.7 wt.%, consistent with moderate  (Lechler and Desilets 1987). Immobile elements including Ti, Nb, Ta, Zr, Y and REES were used to identify rock groups, petrogenetic trends and tectonic environments (Pearce and Cann 1973;Winchester 1975, 1978;Pearce and Norry 1979). On the Nb/Y vs. Zr/Ti protolith discrimination diagram (after Pearce 1996), the meta-lavas plot as basalt, andesite and basaltic andesite and alkali basalt, whereas the clast from the Karaböğürtlen Formation is basaltic (Fig. 9a). On the Y/Ta vs. Y/Nb plot, indicative of magmatic affinity, the samples range from near N-MORB (normal mid-ocean ridge basalt), to near E-MORB (enriched mid-ocean ridge basalt) and near OIB (ocean island basalt) (Fig. 9b). Chondrite-normalised spider diagrams (Fig. 9c (Fig. 9f), mainly owing to relative Nb depletion.

Interpretation of the meta-volcanic rocks
The meta-lavas have the chemical characteristics of withinplate, i.e., rift or seamount extrusives. They are interbedded with shallow-water continental shelf-type siliciclastic and carbonate sediments, consistent with an extensional setting. However, there is no evidence of deep-water conditions (e.g. chert), in contrast to the unmetamorphosed tuffaceous sediments of the Çataloturan thrust sheet (Aladağ unit). This suggests that platform deposition kept pace with any extension-related subsidence. The most 'enriched' sample, close to OIB in composition, is typical of a low-degree partial melt of a spinel peridotite mantle, in a continental rift setting (e.g., Fitton 2007). The near-E-MORB sample represents a greater degree of partial melting, potentially of compositionally similar upper mantle. In a rift setting, co-existing OIB and E-MORB can be explained by a mantle plume or by enriched "blobs" or "streaks" in the upper mantle (Fitton 2007). Where present, the subduction influence (negative Nb and Ta anomalies) could relate to coeval subduction. However, the subduction influence could also represent derivation from sub-continental mantle lithosphere that was fluxed with subduction fluids during some earlier unrelated subduction event (e.g. Pearce 1982Pearce , 1983Fitton et al. 1991;Gibson et al. 1993;Verma 2009). The latest prior metamorphism that affected the Tauride and Anatolide crustal units was Cambrian, c. 520-530 Ma (Kröner and Şengör 1990;Gürsu and Göncüoğlu 2005;Zlatkin et al. 2013).

Late Palaeozoic volcanic rocks of the East-Tauride carbonate platform
The Precambrian-Eocene succession of the Eastern Tauride autochthon (Feke area) (Fig. 2) includes a minor occurrence of basaltic extrusive rocks (Dalkılıç 2009). The location is southeast of Develi (near Derebaşı) in south-Kayseri Province (Fig. 2). The volcanics (Paleovolcanite of Metin 1986) are located at the contact of the Late Devonian Gümüşali Formation (Demirtaşlı 1967) and the early Carboniferous Tuzludere Formation (Metin 1983). The Gümuşali Formation is dated by a rich assemblage of conodonts and some brachiopods (Metin 1986), whereas the overlying Tuzludere formation is mainly dated using a diverse brachiopod assemblage (Metin 1986). The volcanics were included in the Late Devonian Gümüşali Formation by Metin (1986), but were later considered to be early Carboniferous, based on regional facies correlations (Dr. Yavuz Bedi, personal communication 2000 to Dalkılıç 2009). Çimen (2018) followed Metin (1986) in assuming a Late Devonian age. The exact age of these volcanics, therefore, remains debatable.
Within the small outcrop, individual lava flows are no more than 30-50 cm thick and are exposed laterally for several tens of metres. The basalts range from aphyric to plagioclase-pyroxene-phyric. Chemical analysis of five samples shows that these rocks are basaltic, with near-MORB, to slightly 'enriched' trace element patterns. Immobile element discrimination diagrams indicate the presence of a minor subduction influence (e.g. Nb). The basalts are inferred to have a contemporaneous back-arc basin origin based on subduction geochemical signature (Çimen 2018).
The Tauride autochthon volcanics (Feke area) are compared with the Binboğa unit metavolcanics in Fig. 9. The majority of the samples from both volcanic units are basaltic (Fig. 9a). Four of the Tauride autochthon samples (Feke area) are enriched (E-MORB), similar to several of the Binboğa metavolcanic samples. However, one sample from the Tauride autochthon has a near-MORB composition (Fig. 9b). On the rock/chondrite plot vs. REE plot, the Tauride autochthon samples overlap in composition with the Binboğa metavolcanics but are generally more depleted (Fig. 9c). A similar pattern is present in the rock vs. N-MORB spider plots (Fig. 9d). On the Th/Yb vs. Ya/ Yb plot, eight of the samples plot within the field of volcanic arc rocks, while two (one from each area) plot near to E-MORB; one plots near MORB (Fig. 9e). On the Nb/Y vs. Zr/Y diagram, the samples mainly overlap in composition and are relatively 'depleted' compared to Icelandic basalts (Fig. 9f).
Both sets of volcanic rocks can also be compared with the early Carboniferous Çataloturan unit tuffs. These are more evolved magmatically as they plot in the trachyte and alkali rhyolite fields (Fig. 6i). Their relatively enriched character is confirmed by plotting in the within-plate granite field (Fig. 6j), their marked enrichment in the rock/ chrondrite spider plots and their evidence of plagioclase fractionation (negative Eu) (Fig. 6k).
In summary, two different volcanic compositional groupings are represented within the Tauride platform units, regionally. The first comprises the meta-volcanics of the Late Palaeozoic Binboğa unit and also the Tauride autochthon volcanics (Feke area). Together, these represent a variably fractionated basaltic suite with a common subduction influence (Fig. 6). The second grouping is represented by the tuffs of the early Carboniferous Çataloturan thrust sheet, which represent a variably 'enriched', evolved alkaline suite.

Regional setting of Late Palaeozoic volcanism
Any interpretation needs to take account of the Late Cretaceous and Cenozoic tectonics which affected the allochthonous Çataloturan thrust sheet and the Binboğa metamorphics (part of the Malatya-Keban platform), related to

Early Carboniferous tuffaceous sediments: an intra-platform rift
The early Carboniferous tuffaceous sediments begin just above the lowest exposed level of the succession in the Çataloturan thrust sheet. The Çataloturan thrust sheet is the third lowest thrust sheet making up the Aladağ massif (Fig. 10). Each of these thrust sheets is dominated by Mesozoic Tauride-type shallow-water platform, or platform-slope carbonate successions, with deeper-water distal slope sediments, oceanic sediments and volcanics structurally above (Tekeli et al. 1984;Polat and Casey 1995;Polat et al. 1996;Robertson et al. 2021b). However, only the three lowest thrust sheets include Palaeozoic rocks (Fig. 10).
The thrust sheet that directly underlies the Çataloturan thrust sheet with its tuffaceous deposits is the Siyah Aladağ thrust sheet (Fig. 10). This begins with a mixed neritic carbonate-siliciclastic succession of Late Devonian to Late Permian age, c. 1000 m thick (Blumenthal 1952;Tekeli 1981;Tekeli et al. 1984;Balcı 2010). The succession is typically grey-green in the lower part, to blackish in the upper part. Sandstones are quartz rich. Limestones range from wackestones, to packstones, to grainstones and are locally rich in brachiopods, coral, gastropods, calcareous algae and large foraminifera. The lower part of the succession includes the benthic foraminifera, Nanicella sp. and Eonodosaria sp. together with the brachiopods, Productella subaculeata and Cryptospirifer syringothyriformis of Late Devonian age. The middle part of the succession contains an early Carboniferous fauna (Tournaisian-Visean), including the large foraminifera Archaediscus sp., Mediocris sp., Milerella sp., Neoarchaediscus sp., Fusulinella sp., Schubertella sp., Ozawainella sp. and Pseudostaffella sp., together with the calcareous alga Koninckopora sp. An upward continuation into the late Carboniferous is suggested by the presence of the large foraminifera, Pseudotextularia sp., Triticites sp. and Boultonia sp., together with the calcareous algae Girvanella sp. and Koninckopora sp. The succession includes an interval of pale-coloured, well-sorted quartzarenite (orthoquartzite) (Köşkdere formation), in which  (Tekeli 1981;Tekeli et al. 1984). Note: An additional, small and discontinuous thrust sheet, mainly made up of Mesozoic platform carbonates, is exposed in the southwest (Minaretepeler thrust sheet), where it underlies the Çataloturan thrust sheet detrital zircons are mainly of Precambrian age (Ustaömer et al. 2020). Above this, there is a richly fossiliferous interval of Permian shallow-water carbonates, including the Early Permian Girvanella zone, which passes upwards into Triassic shallow-water shelf carbonates and mudrocks, as in the Taurides generally (Tekeli et al. 1984;Ayhan and Lengeranlı 1986). The Siyah Aladağ thrust sheet, therefore, documents a subsiding carbonate platform without evidence of Carboniferous tuffaceous or slope deposits.
Beneath the Siyah Aladağ thrust sheet, there is one more thrust sheet, the regional-scale Yahyalı thrust sheet (Fig. 10). Combining information from the Aladağ and Malatya areas (Tekeli 1981;Tekeli et al. 1984;Ayhan and Lengeranlı 1986;Alan et al. 2007;Balcı 2010), the succession is dominated by dark grey to black, medium to thick-bedded, recrystallised limestone and dolomite, with subordinate quartzarenite (quartzite) and mudrock (metashale and calcschist). Poorly preserved brachiopods, corals, gastropods and calcareous algae suggest a Late Devonian age in the Aladağ area (Tekeli 1981;Tekeli et al. 1984). Overlying medium to thick-bedded, recrystallised limestone, quartzite, dolomite and meta-mudrock contain large foraminifera (fusulinids) of Carboniferous age. The succession continues with Early Permian Girvanella-bearing meta-limestones. Emergence is marked by meta-bauxite in places. The Late Permian is characterised by meta-carbonates with Mizzia. Above further metabauxite and/or a basal conglomerate the Early Triassic is more pelitic, followed by typical Tauride shelf carbonates of Late Triassic to Late Cretaceous age. Tiny carpholite relics (10-to 100 μm-long fibers) occur within quartz grains indicating that the Yahyalı thrust sheet has undergone HP/ LT metamorphism (Pourteau et al. 2010). The Yahyalı thrust sheet can be generally correlated with the Bolkar Dağ thrust sheet in the central Taurides farther west, which contains glaucophane and fibrous calcite after aragonite, again indicative of HP-LT metamorphism (Pourteau et al. 2010). Similar carpholite-bearing lithologies have been traced for > 600 km c. E-W across the Afyon zone, within the Anatolide crustal unit (Pourteau et al. 2010).
The Siyah Aladağ thrust sheet and the Yahyalı thrust sheet restore as different parts of a gently subsiding Late Palaeozoic shelf, with variable influxes of neritic carbonate and siliciclastic sediments, largely controlled by a combination of tectonic instability (extension) and sea-level fluctuations. Similar Late Palaeozoic successions (e.g. Gümüşali Formation) are exposed within the relatively autochthonous Geyik Dağ in the eastern Taurides, including the Tufanbeyli area (Göncüoğlu et al. 2004) and the Karsantı-Akdam area (Ünlügenç and Demirkol 1991). Comparable successions also occur in the Bolkar Dağı, central Taurides (Demirtaşlı et al. 1984) and farther west in the Hadim (Aladağ) and Bolkar thrust sheets, as exposed in the Taşkent-Hadim area (Özgül 1984Mackintosh and Robertson 2012b).
The Aladağ thrust sheets, including the Çataloturan thrust sheet, are imbricated beneath the over-riding Late Cretaceous supra-subduction zone Pozantı-Karsantı ophiolite (Lytwyn and Casey 1995;Polat and Casey 1995;Parlak et al. 2000). There are two alternative restorations of the thrust sheets making up the Aladağ unit: (1) In-sequence thrusting. The Aladağ thrust sheets restore from south to north as follows: Yahyalı thrust sheet, Çataloturan thrust sheet, Beyaz Aladağ thrust sheet, Karanfil Tepe unit, followed by the Late Cretaceous Pozantı-Karsantı ophiolite and the related Aladağ melange (Tekeli 1981;Tekeli et al. 1984;Polat and Casey 1995;Alan et al. 2007;Robertson et al. 2021b). The HP/LT Yahyalı thrust sheet at the structural base of the thrust stack represents by far the most deeply buried tectonic unit in the region. The ophiolite is not itself imbricated with the platform units and the overlying Aladağ melange (Polat and Casey 1995;Robertson et al. 2021b), suggesting that the imbrication of the unmetamorphosed platform units beneath predated or accompanied the latest Cretaceous ophiolite and melange emplacement. Also, there is an absence of intercalated Eocene 'flysch' which accompanied Eocene thrusting throughout the central Taurides (e.g. Özgül 1984MTA 2011). However, post-Cretaceous imbrication cannot be excluded as there are no age-controlling cover units; (2) Out-of-sequence thrusting (i.e. rethrusting). The HP-LT Yahyalı unit originated farthest north and was deeply buried and metamorphosed as the leading edge of the Tauride-Anatolide continent underthrust/subducted northwards. HP-LT metamorphism of the Afyon zone is dated as Early-Middle Palaeocene (65-60 Ma), based on 40 Ar-39 Ar geochronology on white mica and multi-equilibrium thermobarometric calculations (Pourteau et al. 2010;Pourteau 2011). The metamorphism was followed by exhumation and re-thrusting over unmetamorphosed, high-level Tauride units (Pourteau et al. 2010;Pourteau 2011). Re-imbrication, probably during the Eocene, finally placed the Tauride units, including the Late Cretaceous Pozantı-Karsantı ophiolite, over the exhumed HP-LT Yahyalı unit. The present structural position could be achieved more easily by back-thrusting of the LP-LT sheets over the HP-LT (Yahyalı) sheets, as mapped in the central Taurides (Özgül 1984Mackintosh and Robertson 2012b).
The sedimentology and volcanism of the successions also hint at proximal-distal relations. Quartzose sediments are coarser-grained and more abundant in the Aladağ thrust sheet (relatively proximal), particularly during Late Permian and Late Triassic rifting, compared to the Bolkar Dağ thrust sheet (more distal). Consistent with this interpretation, the Bolkar Dağ thrust sheet includes Late Triassic volcanogenic lithologies related to rifting (Demirtaşlı et al. 1984;Alan et al. 2007;Robertson et al. 2009;Mackintosh and Robertson 2012a, b).

3
The balance of evidence suggests that the HP-LT Yahyalı thrust sheet restores to a more northerly location than the LP-LT thrust sheets including the Çataloturan one. The HP-LT vs. LP-LT successions of the Aladağ unit must have been structurally reorganised during the latest Cretaceous or later. However, there is no obvious reason to infer major outof-sequence thrusting within the unmetamorphosed Tauride platform carbonate units. The Çataloturan unit is, therefore, likely to have originated within the Late Palaeozoic carbonate platform prior to the Mesozoic rifting of the Tauride-Anatolide continental crust. The Çataloturan unit is, therefore, restored as an early Carboniferous intra-platform rift. Radiolaria or other pelagic organisms can accumulate in deep-water rift basins assuming that they are open to oceanic currents (e.g. Bernoulli and Jenkyns 1974). Assuming an intra-platform origin, the early Carboniferous alkaline tuffaceous sediments of the Çataloturan thrust sheet restore as a relatively deep-water rift (100 s of m). Tuffaceous input progressively waned and the basin had filled with calciturbidites by the end of the Visean. A depositional hiatus ensued before resumption of shallow-water carbonate deposition during the Late Permian. This hiatus contrasts with the successions in the Siyah Aladağ and Yahyalı thrust sheets (Fig. 10). A possible explanation is that the inferred rift was shortened, stratigraphically inverted, uplifted and eroded prior to Late Permian transgression. A similar unconformity, related to contractional tectonics, affects the Konya Complex in the Afyon zone farther west (see below). The Çataloturan thrust sheet might restore to a relatively distal (northerly) location close to the Palaeozoic continental margin. However, an intra-platform rift setting is preferred over a deep-water continental margin setting, mainly because of the evidence of upward shallowing.
In an alternative tectonic model, Göncüoğlu et al. (2007) proposed that the Çataloturan unit formed in a back arc-basin that rifted along the northern margin of Gondwana, related to early Carboniferous southward subduction. The early Carboniferous tuffaceous sediments accumulated on the northern margin of this rifted crust, facing an off-margin magmatic arc (Sakarya arc). Tuff drifted from the arc and settled in the deep-water Çataloturan basin to the south. However, the evolved alkaline nature of the source volcanism is incompatible with a volcanic arc origin. An intra-plate setting is instead indicated by the geochemical evidence (Fig. 6).

Late Palaeozoic Binboğa meta-volcanics: an extensional setting
The Late Palaeozoic alkaline meta-volcanics of the Binboğa metamorphic unit are also indicative of a within-plate setting, based on the geochemical evidence (Fig. 9). The localised presence of intraformational debris-flow deposits is consistent with an unstable, mixed carbonate-siliciclastic shelf setting. There is no evidence of deep-water conditions (e.g. meta-chert), in contrast to the alkaline tuffs of the Çataloturan thrust sheet.
The palaeogeography of the Late Palaeozoic within-plate volcanism depends on the palinspastic restoration of the Taurides vs. the Anatolides. There are two main alternatives: In the first alternative, the Binboğa (Malatya) Late Palaeozoic volcanics erupted in an intra-platform setting, to the north of both the Tauride autochthon (Geyik Dağ) and the allochthonous Tauride Munzur platform (MTA 2011). The Binboğa (Malatya) metamorphics correlate with the HP-LT Afyon zone (Anatolides) of the central and western Taurides. The Afyon zone restores to the north of the unmetamorphosed Tauride thrust sheets (Aladağ (Hadim) of the central and western Taurides (Özgül 1984Göncüoğlu et al. 2003;Okay et al. 2006;Pourteau et al. 2010Pourteau et al. , 2013Pourteau et al. , 2016Mackintosh and Robertson 2012b). The HP-LT metamorphism affecting the Anatolides generally relates to northward underthrusting/subduction of the Tauride-Anatolide crustal block during latest Cretaceous-early Cenozoic (Candan et al. 2005;Pourteau et al. 2010Pourteau et al. , 2013Pourteau et al. , 2016. In this alternative, the Binboğa metamorphics restore to the north of the unmetamorphosed Tauride units. The Late Cretaceous ophiolites and related accretionary melanges were emplaced southwards over the Binboğa/Malatya crust (Malatya-Keban platform), directly onto the Tauride platform carbonates to the south (Munzur platform).
In the second alternative, the Binboğa metamorphics between the Tauride autochthon (Geyik Dağ) to the south and the unmetamorphosed Munzur platform to the north. The field relations indicate that the Binboğa (Malatya) metamorphics are to the south of, and structurally beneath, the Munzur platform, with the ophiolites/accretionary melanges above (Perinçek and Kozlu 1984;Robertson et al. 2006Robertson et al. , 2013Robertson et al. , 2021aAlan et al. 2007;Bedi et al. 2009;Bedi and Yusufoğlu 2018). Conceivably, the present structural organisation was achieved by thrusting of the Binboğa/ Malatya metamorphic crust southwards over the Tauride carbonate platform (Munzur limestones) during the latest Cretaceous, followed by re-thrusting to position the Munzur platform above the Binboğa/Malatya metamorphics. Some re-thrusting did indeed take place during the Eocene and/ or Miocene (Perinçek and Kozlu 1984;Bedi et al. 2009;Robertson et al. 2013Robertson et al. , 2021a, but this seems unlikely to have completely reorganised the stacking order of the major tectonic units in the eastern Taurides. On the other hand, the Binboğa/Malatya crust was intruded by granitic rocks (Baskil granitoids), dated radiometrically as 88-82 Ma (Santonian-Campanian) (Parlak 2006;Rızaoğlu et al. 2009;Karaoğlan et al. 2016). These granitoids are interpreted to relate to northward subduction of oceanic crust to the south (Rheic ocean) implying a relatively southerly position of the Binboğa/Malatya crust (Malatya-Keban platform) before southward ophiolite emplacement (c. 75-68 Ma). In alternative two, a deep zone of underthrusting/subduction separated the Malatya-Keban platform in the south from the Munzur platform to the north. The Malatya-Keban units represented separate platforms, perhaps with a basin between that collapsed and deeply underthrust northwards to form the HP-LT Binboğa (Malatya-Keban) metamorphics. The metamorphism is inferred to be Late Cretaceous because the youngest succession (Karaböğürtlen Formation) in the Malatya-Keban platform is Late Cretaceous (Cenomanian), whereas the unconformable sedimentary cover begins in the Maastrichtian (Kemaliye and Gündüzbey formations) (Perinçek and Kozlu 1984;Bedi et al. 2009;Robertson et al. 2013Robertson et al. , 2021aBedi and Yusufoğlu 2018). In the second alternative, the Late Palaeozoic Binboğa volcanics erupted in an intraplatform setting adjacent to the exposed Tauride autochthon (Geyik Dağ), where geochemically similar magmatic rocks are locally present (Feke area), as shown in Fig. 11. The palaeogeography of the central and eastern Taurides differed markedly in this preferred alternative.

Tectonic development of the N Gondwana continental margin
The tectonic-magmatic setting of the north-Gondwana continental margin also needs to take account of the late Carboniferous melanges and granitic rocks within the Afyon zone, and also the unmetamorphosed melanges in the Lycian nappes (Teke Dere unit) and in the Karaburun Peninsula (eastern Aegean) (Fig. 2).

Konya melange and granitic rocks (Anatolides)
In central-southern Anatolia, late Cretaceous accretionary melanges and ophiolites are unconformably underlain by the Late Palaeozoic-Early Mesozoic, tectonically assembled Konya Complex, within the Afyon zone (Anatolides) (Fig. 2). The Afyon zone is proposed to be a fragment of the Eurasian active continental margin that accreted to the Tauride crustal block during latest Triassic (see Fig. 1bii) (Stampfli et al. 2001;Eren et al. 2004;Moix et al. 2008). However, the Afyon zone is also interpreted as part of the Tauride-Anatolide continental block which remained close to Gondwana (e.g. Şengör and Yılmaz 1981;Göncüoğlu et al. 2000Göncüoğlu et al. , 2003Okay et al. 2006;Göncüoğlu 2011;Robertson et al. 2009;Candan et al. 2016). The main evidence for the two alternative interpretations is reviewed below taking account of recent geochronological data.
The matrix of the melange includes meta-mudrocks with siliceous microfossils (Muellerisphaerida) and also pelagic limestones with deep-water conodonts of Late Silurian (Wenlock)-Early Devonian age (Göncüoğlu and Kozur 1998;Göncüoğlu et al. 2001). The siliciclastic matrix is locally dated as early Carboniferous (Visean), based on rare interbedded limestones with benthic foraminifera of this age (Göncüoğlu et al. 2001), although these could be 1 3 redeposited. Detrital zircons from six sandstone from the melange are significantly older than the biostratigraphically determined age of the melange matrix (Löwen et al. 2020;Ustaömer et al. 2020). Löwen et al. (2020) also report a unit of 'meta-flysch' above the melange and also above the adjacent Late Palaeozoic carbonate platform (Bozdağ unit). The 'meta-flysch' comprises well-bedded meta-mudstones, meta-siltstones and meta-sandstones, locally with plant material and common meta-volcanic fragments. Petrographically, the 'meta-flysch' is generally similar to the meta-sandstones of the melange beneath, although richer in meta-volcanic clasts (Löwen et al. 2020). Detrital zircons from one sample yielded the youngest ages (spot ages) of 326.3 ± 5.3 and 328.3 ± 3.8 Ma (Serpukhovian). Another sample provided three late Carboniferous spot ages (Löwen et al. 2020). Löwen et al. (2020) assumed a late Carboniferous-early Permian (Pennsylvanian-Cisuralian) age for the 'meta-flysch', based mainly on the youngest detrital age data present. Comparable, low-grade metamorphosed turbidites occur within the Karaburun melange (Karaburan Peninsula) (Fig. 2) have also yielded detrital zircons with late Carboniferous-Early Permian youngest ages (Löwen et al. 2017).
The oldest cover of the Devonian-Carboniferous Konya Complex is a shallow-marine mixed siliciclastic-carbonate succession exposed in the east (Eldeş Formation) (Özcan et al. 1988Robertson and Ustaömer 2009a, b). In the west, the Konya melange is locally overlain, unconformably, by Early Triassic meta-trachyandesites (Volcanic-sedimentary unit) (Akal et al. 2012). Elsewhere in the same general area, volcanics are absent and the Konya Complex is unconformably overlain, above a basal conglomerate, by non-marine to shallow-marine siliciclastic sediments (Ardıçlı Formation) (Özcan et al. 1988Robertson and Ustaömer 2009a, b). Based on the youngest detrital zircons present, these siliciclastics are no older than Late Triassic (Löwen et al. 2020). In one area, red metaclastics, correlated with the Ardıçlı Formation, are interbedded with meta-volcanics (Kadınhanı meta-trachyandesites), with a crystallisation age of 220.24 ± 0.7 Ma (Norian) (Güven et al. 2012;Ustaömer et al. 2016b). In addition, zircons from two metarhyolites (İlgin area) are dated as Middle Triassic (230-229 Ma) by the shrimp method (Özdamar et al. 2013). Phengites from the same metarhyolites gave Palaeocene Ar-Ar plateau ages (~ 63 Ma), interpreted as the timing of the regional HP-LT metamorphism affecting the Afyon zone. The overall succession passes upwards into lenticular shallow-marine carbonates and siliciclastics that in turn grade into Late Triassic-Early Cretaceous platform carbonates, typical of the Afyon zone generally (Eren 1993;Özcan et al. 1988Göncüoğlu et al. 2007;Robertson and Ustaömer 2009a, b).
In addition, late Carboniferous (320-310 Ma) (Moscovian-Bashkirian) granitic rocks cut the Afyon zone in its type area, c. 200 km NW of the Konya melange Ustaömer et al. 2020). Also, blocks of granitoid rocks, loosely dated by the K-Ar method as Carboniferous-Devonian, occur within the Mersin melange on the southern slopes of the Taurus Mountains (Parlak and Robertson 2004), although these require more accurate dating to allow proper interpretation.
On the other hand, Ustaömer et al. (2020) note that the Lu-Hf isotopic compositions of the Carboniferous zircons of the Triassic Tauride sandstones plot within the distribution of the Afyon Zone granites (studied by these authors), consistent with the Anatolide crustal block as a possible source for the zircons in these sandstones. Although Devonian granites are unknown in the Anatolide crustal unit, inherited Devonian zircons occur within the Carboniferous metagranites of the Afyon zone Ustaömer et al. 2020). Specifically, Devonian zircon cores occur in two samples of Carboniferous Anatolide granites, as analysed by Ustaömer et al. (2020). A Devonian igneous source could, therefore, exist within the Afyon zone crustal block. However, it is unclear whether the Late Palaeozoic granites of the Afyon zone were exhumed and eroding during the late Carboniferous formation of the Konya Complex. At present, therefore, the source of the Mid-Devonian magmatic zircons remains uncertain.
The upper composite unit ('İncirbeleni Formation') is interpreted as early Carboniferous oceanic crust, deep-sea siliceous sediments and distal calciturbidites (seamount-derived?) that accreted, together with sandstone turbidites, at a subduction trench. The late Carboniferous-earliest Permian volcanic-sediment units are interpreted as the remains of a late Carboniferous seamount and capping carbonate platform that collapsed during latest Carboniferous-earliest Permian, shedding debris into deep water, before being accreted in an active margin setting (Stampfli and Kozur 2006;Robertson andUstaömer 2009b, 2011). The volcanic build-up subsided relatively slowly which could favour an origin as part of a rifted off-margin crustal block rather than a typical ocean-ocean seamount.
In summary, the Teke Dere unit is interpreted as part of a Palaeotethyan accretionary complex, which included the Konya Complex. The accretionary terrane included the Karaburun melange (Karaburun) and other outcrops in the eastern Aegean (notably Chios) which will not be considered here (e.g. Papanikolaou and Sideris 1983;Robertson and Pickett 2000;Zanchi et al. 2003;Meinhold et al. 2008;Robertson andUstaömer 2009b, 2011;Löwen et al. 2017;Ustaömer et al. 2020).
In many interpretations, the closure of the Rheic ocean was achieved by southward subduction, coupled with the opening of Palaeotethys farther south (Stampfli and Borel 2002;von Raumer et al. 2003;Cocks and Torsvik 2006;Rolland et al. 2016;Rolland 2017). In one model, the subsequent early Carboniferous (340-330 Ma; mainly Visean) granitic magmatism of the circum-Black Sea region, including the Sakarya arc, extending at least as far east as the Caucasus, relates to northward subduction of Palaeotethys Rolland et al. 2016;Okay and Topuz 2017). Subduction continued during the late Carboniferous-Permian based on evidence from adjacent regions (e.g. Bulgaria) (Bonev et al. 2019). In another model (Dokuz et al. 2011(Dokuz et al. , 2015, Palaeotethys restores to the north of the Rheic ocean. Rifting of a 'peri-Laurussian terrane' above a northward-subducting Rheic ocean generated Palaeotethys as a marginal basin along the southern margin of Laurussia during Late Silurian-Early Devonian. Driven by southward subduction of the Rheic Ocean, the 'peri-Laurussian terrane' drifted southwards and collided with the north-Gondwana margin, triggering the Variscan orogeny during Late Devonian-early Carboniferous (Dokuz et al. 2011(Dokuz et al. , 2015. More evidence is needed to test the above Rheic-Palaeotethys alternatives. In one of the tectonic models (Fig. 1aii), Palaeotethys closed by southward subduction, creating the Sakarya arc 1 3 within, or close to, the northern borderland of Gondwana (Şengör and Yılmaz 1981(Şengör and Yılmaz , 2003(Şengör and Yılmaz , 2007Şengör et al. 1984;Göncüoğlu et al. 2000;Dokuz et al. 2011;van Hinsbergen et al. 2020). Göncüoğlu et al. (2007) interpreted the Sakarya arc as an oceanic arc that was separated from Gondwana by a marginal basin (or trapped oceanic crust), possibly similar to the modern Aleutian arc (e.g. Kelemen et al. 2003). The host rocks of the Sakarya crustal unit as a whole are metaigneous rocks, quartzo-feldspathic schists, gneisses and amphibolites, without ophiolitic rocks (e.g. P.A. Ustaömer et al. 2012;Karslı et al. 2016;Okay and Topuz 2017). The available evidence, therefore, suggests a continental rather than oceanic basement to the Sakarya crustal unit and thus that the Sakarya arc formed along a continental borderland.
In other tectonic models (Fig. 1bii, cii) the Sakarya arc formed by northward subduction beneath, or adjacent to, the southern margin of Eurasia (Robertson and Dixon 1984;Stampfli and Borel 2002;Topuz et al. 2010;P.A. Ustaömer et al. 2012;Okay and Topuz 2017;Barrier et al. 2018). Northward subduction created the early Carboniferous (320-330 Ma) granitic rocks of the Sakarya zone and those of late Carboniferous-Permian age more widely in the circum-Black Sea region (Okay and Topuz 2017;Aysal et al. 2018;Bonev et al. 2019). No definite evidence has so far been identified of a Late Palaeozoic suture zone and/ or subduction-accretion complex related to southward subduction between the Pontides and Eurasia, as in model 1 (Fig. 1aii, aiii). Northward subduction is also inferred in the Caucasus, farther east during the Late Palaeozoic (Adamia et al. 2003(Adamia et al. , 2011Rolland et al. 2016;Rolland 2017).
Assuming overall northward subduction of Palaeotethys (Fig. 1b,c), there are three main options to explain the late Carboniferous inferred accretionary origin of the melanges (Konya Complex, Teke Dere, Karaburun Peninsula), and also the late Carboniferous granites of the western Afyon zone.
The first option is accretion of Eurasian fore-arc crust to Gondwana during latest Triassic (Eren et al. 2004;Moix et al. 2008Moix et al. , 2011 (Fig. 1bii-biii). The Sakarya arc rifted and drifted southwards until it collided with Gondwana during latest Triassic. However, problems include the following: (1) the absence of a Triassic subduction complex or volcanic arc accreted to Gondwana; (2) the correlation of the Konya Complex Late Palaeozoic platform (Bozdağ unit) with the Tauride autochthon (Geyik Dağ); (3) the absence of a Triassic collisional (flexural) foreland basin; (4) the Southern Neotethys began to open during the Late Triassic (e.g. Robertson et al. 2012;Barrier et al. 2018), such that the Tauride crustal block was still located close to Gondwana rather than having drifted away northwards towards Eurasia; (5) modern and ancient intra-continental margin basins typically remain narrow rather than developing into wide ocean basins (e.g. Black Sea; Tyrrhenian Sea; Aleutians back-arc basins; Japan Sea) (e.g. Sdrolias and Müller 2006, and references).
The second option is that the late Carboniferous accretionary melange and the 320-310 Ma (Moscovian-Bashkirian) granitoid rocks cutting the Afyon zone both relate to southward subduction; this implies double, northward and southward subduction at least during the late Carboniferous (Robertson et al. 2009a(Robertson et al. , b, 2012Candan et al. 2016;Ustaömer et al. 2020) (Fig. 1cii). In this interpretation, Palaeotethys narrowed westwards from the Turkish region to the Balkan region (e.g. Cocks and Torsvik 2006). Closure was complete in the Dinaride region (North Macedonia, Croatia, Serbia, Slovenia) by the end of the Carboniferous. For example, in Slovenia late Carboniferous clastics include pebbles derived from the Variscan basement (Pamić and Jurković 2002). Palaeotethys existed as westward-narrowing gulf during the late Carboniferous in the (restored) south and central Aegean region (Zanchi et al. 2003). Contraction of Palaeotethys in a confined oceanic space farther east, in western Turkey (Afyon zone), then triggered southward subduction beneath Gondwana, creating a short-lived late Carboniferous active margin with melange accretion Ustaömer et al. 2020) and localised granitic intrusion Ustaömer et al. 2020). Southward subduction ended when collision intensified prior to Early Permian. During the Permian, there was a switch to crustal extension along the entire north-Gondwana margin.
The third, related option, also involves collision of Gondwana and Eurasia in the west (e.g. Aegean-Balkan region) during the late Carboniferous. This created a broad east-facing Palaeotethyan gulf. Subduction of Palaeotethys became westwards allowing granitic magmatism to intrude both Eurasian crust in the northwest and more locally Gondwana crust (Afyon zone) in the southwest (Okay and Topuz 2017). Options 2 and 3, above fit the available evidence better than option 1. More evidence is needed for the late Carboniferous palaeogeography of the Aegean region to evaluate options 2 and 3.

Late Palaeozoic volcanism along the north-Gondwana borderland
In the light of the above regional discussion, we now consider the implications of the new chemical data for the Binboğa (Malatya) and Feke unit (Tauride autochthon) volcanism. The Binboğa and Feke units could represent remnants of essentially the same Late Palaeozoic extensional magmatic province (Fig. 11). The Binboğa unit volcanism could have been the source of the Çataloturan unit tuffaceous sediments, distributed generally westwards towards the rift depocentre. However, it is also possible that the two alkaline volcanic occurrences relate to eruptions in different 1 3 extensional basins at different times. Late Palaeozoic intraplate volcanism, mostly Devonian, is also widely distributed farther east, in Iran (Ruttner 1991;Romer et al. 2001;Wendt et al. 2002;Gharaire et al. 2004), suggesting that such alkaline volcanism was widespread within the north margin of Gondwana.
In the regional setting, as inferred above, the early Carboniferous (Late Tournaisian-Late Visean; c. 340-350 Ma) alkaline volcanism of the Çataloturan thrust sheet and the Late Palaeozoic less 'enriched' meta-volcanics in the Binboğa metamorphic unit have four potential origins: First, the alkaline volcanics could represent smallscale, relatively shallow-level plume-driven magmatism (e.g. Pik et al. 2006) (Fig. 13a). However, this seems unlikely because the volcanism and tuffs are distributed for > 500 km, generally east-west, approximately parallel to the restored north margin of Gondwana (Fig. 11).
Second, the Devonian-early Carboniferous rifting relates to slab-pull, assuming Palaeotethys subducted northwards beneath Eurasia (Figs. 11, 13b). Slab-pull could have re-activated structural weaknesses within the north margin of Gondwana to form a > 500 km-long east-west volcanically active rift. This is our preferred Fig. 13 Alternative tectonic settings of the early Carboniferous alkaline tuffaceous sediments (Nohutluk Formation; Aladağ unit) and the Late Palaeozoic meta-volcanics of the Binboğa (= Malatya) metamorphic unit. a Small plume with northward subduction beneath Eurasia; b rifting related to northward subduction beneath Eurasia; slab-pull causes extension along the N Gondwana continental margin; c back-arc rift above a southward-dipping subduction zone; b is preferred (see text). Note: the restored positions of the early Carboniferous alkaline tuffaceous sediments and the Late Palaeozoic meta-volcanics are suggested in Fig. 11, implying substantial palaeogeographic and tectonic differences between the central and eastern Taurides option because it is consistent with the regional geological evidence.
Third, the alkaline volcanism could relate to southward subduction beneath Gondwana, possibly as a Carboniferous back-arc basin (Fig. 13c). Both the Binboğa unit metavolcanics and the Tauride autochthon volcanics (Feke unit) commonly exhibit a subduction influence (i.e., negative Nb and Ta anomalies). However, the subduction influence could alternatively have been derived from melting of sub-continental mantle lithosphere (Neoproterozoic-Cambrian), combined with continental crust 'contamination' and variable fractionation. There is evidence of a subduction influence within continental rift volcanics, unrelated to coeval subduction, in many regions of the world (e.g. Fitton et al. 1991;Kempton et al. 1991;Romer et al. 2001;Robertson 2007;Verma 2009;Robertson et al. 2021b). There is no evidence of contemporaneous early Carboniferous arc volcanism, for example arc-derived fallout tuff within the Tauriderelated crust, the Konya Complex, or the Teke Dere unit, located farther north towards Palaeotethys. The obvious candidate for tuff derived from a north-Gondwana continental margin arc, i.e. the Çataloturan unit (Göncüoğlu et al. 2007), is alkaline without subduction influence.
Fourth, the early Carboniferous Çataloturan unit alkaline volcanism might relate to tuff dispersal from seamounts located within Palaeotethys to the north. This would be consistent with the evolved, alkaline volcanism but is otherwise unlikely because of the following: (1) the associated calciturbidites contain detrital volcanic grains pointing to relatively local volcanism; (2) the tuffaceous sediments in the Tauride autochthon in the west (Sultan Dağ) include minor volcanic extrusives that must be in situ (Göncüoğlu et al. 2007); (3) seamounts including the one emplaced within the Teke Dere melange are typically relatively quiescent, without large volumes of regionally dispersed volcanic ash in contrast to felsic arc volcanism (e.g. Fisher and Schmincke 1984).
The alkaline volcanism within the Tauride Çataloturan unit (c. 340-350 Ma; Late Tournaisian-Late Visean) is c. 10 Ma older than the late Carboniferous (320-310 Ma) (Moscovian-Bashkirian) calc-alkaline granitic rocks within the Afyon zone Ustaömer et al. 2020), and is also older than the late Carboniferous-Early Permian subduction-accretion, as inferred from the youngest detrital zircon ages from the sandstone turbidites of the Konya and Karaburun melanges (Löwen et al. 2017(Löwen et al. , 2020Ustaömer et al. 2020). One explanation is that 'normal' rifting took place along the north-Gondwana margin during the Late Devonian-early Carboniferous related to slab-pull towards the Eurasian active margin (Fig. 13b). There was then a switch from extension to contraction during the mid-Carboniferous, which triggered the localized late Carboniferous melange accretion and arc magmatism along the north-Gondwana margin (Fig. 1cii). Based on comparative stratigraphic thickness, sedimentation rates and thus subsidence rates are inferred to have increased markedly within the north-Gondwana platform during the latest Carboniferous (c. 300 Ma), based on evidence from the eastern Tauride autochthon (Geyik Dağ) (Göncüoğlu et al. 2004). Similar subsidence affected the central-Tauride Bolkar and Hadim (Aladağ) nappes (Mackintosh and Robertson 2012a). A possible cause of increased subsidence rate could be flexural loading related to regional suturing of Palaeotethys to the west of Turkey.

Conclusions
-Early Carboniferous (Late Tournaisian-Late Visean; c. 340-350 Ma) tuffaceous sediments, and rarely volcanics, are widely distributed along the northern margin of Gondwana, within both relatively autochthonous (Sultan Dağ) and allochthonous (Aladağ) Tauride units. -Chemical analysis of tuffaceous sediments from the early Carboniferous Çataloturan thrust sheet in the eastern Taurides (Aladağ unit) shows that they represent bimodal alkaline-type volcanism, with variable admixtures of terrigenous and siliceous biogenic material (radiolarians). -Late Palaeozoic meta-basalts from the Binboğa metamorphic unit, part of the regional Malatya-Keban metamorphics (E Taurides) are interpreted to represent within-plate (extensional) volcanism within a shallowwater carbonate platform. -Small outcrops of Late Palaeozoic or early Carboniferous basalts within the eastern Tauride autochthon (Feke unit) are likely to represent a southerly extension of the intra-plate volcanism. -The patchy subduction signature (negative Nb and Ta anomalies) in both the Binboğa meta-volcanic rocks and the unmetamorphosed eastern Tauride autochthon (Feke unit) is likely to have been derived by melting of sub-continental mantle lithosphere (Neoproterozoic-Cambrian), combined with continental crust 'contamination' and variable fractionation, rather than coeval back-arc volcanism because evidence of a related arc is lacking. -The combined sedimentary and igneous data suggest the presence of a relatively deep-water rift (Çataloturan unit) and a shallow-water zone of extension (Binboğa metamorphics) along the northern margin of Gondwana during the Late Palaeozoic. -The early Carboniferous alkaline tuffs of the Çataloturan unit accumulated in a deep-water basin, within a carbonate platform that fringed the north margin of Gondwana, with an open-marine connection to Palaeotethys to the north, which allowed siliceous plankton (radiolarian) productivity. -Regional comparisons suggest that the alkaline volcanism of the Çataloturan unit predated the regional late Carboniferous accretionary melanges of the Konya Complex (Afyon zone), the Teke Dere unit (Lycian nappes) and the Karaburan-Chios melange, and also the 320-310 Ma (Moscovian-Bashkirian)-aged granitic magmatism within the western Afyon zone (Anatolides). -In the light of the regional closure history of the Variscan orogen, late Carboniferous melange accretion and arc magmatism could relate to relatively localized, short-lived subduction beneath Gondwana (Afyon zone). This assumes that the Anatolides remained as part of north-Gondwana. Otherwise, Palaeotethys subducted northwards beneath Eurasia during the Carboniferous-Late Triassic, and was progressively replaced by the İzmir-Ankara-Erzincan ocean (northern Neotethys) related to rifting of the north-Gondwana margin during the Triassic.