Abstract
Tetragonal zirconia quantum dots (t-ZrO2 QDs) in silica matrix with different compositions (x)ZrO2–(100 − x)SiO2 were fabricated by a modified sol–gel protocol. Acetylacetone was added as a chelating agent to zirconium propoxide to avoid precipitation. The powders as well as thin films were given thermal treatment at 650, 875 and 1100 °C for 4 h. The silica matrix remained amorphous after thermal treatment and acted as an inert support for zirconia quantum dots. The tetragonal zirconia embedded in silica matrix transformed into monoclinic form due to thermal treatment ≥ 1100 °C. The stability of tetragonal phase of zirconia is found to enhance with increase in silica content. A homogenous dispersion of t-ZrO2 QDs in silica matrix was indicated by the mapping of Zr, Si and O elements obtained from scanning electron microscope with energy dispersive X-ray analyser. The transmission electron images confirmed the formation of tetragonal zirconia quantum dots embedded in silica. The optical band gap of zirconia QDs (3.65–5.58 eV) was found to increase with increase in zirconia content in silica. The red shift of PL emission has been exhibited with increase in zirconia content in silica.
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References
C.J. Brinker, G.W. Scherrer, S.-G. Science, The Physics and Chemistry of Sol–Gel Processing (Academic Press, San Diego, 1990), pp. 1–18
A.J. Burgraaf, K. Keizer, Synthesis of inorganic membranes, in Inorganic Membranes: Synthesis, Characteristics and Applications, ed. by R. R. Bhave (Van Nordstrand-Reinhold, New York, 1991), pp. 10–63
A.E. Yoldas, Technological significance of sol-gel process and process-induced variations in sol-gel materials and coatings. J. Sol Gel. Sci. Technol. 1, 65–77 (1993)
T. Lopez, M. Asomoza, L. Razo, R. Gomez, Study of the formation of silicoaluminates by the sol-gel method by means IR, DTA and TGA, J. Non-Cryst. Solids 108, 45–48 (1989)
T. Lopez, R. Gomez, Catalyst doped sol-gel materials, in Sol-Gel Optics: Processing and Applications, ed. by L. C. Klein (Kluwer Academic Publishers, Norwell, 1994), pp. 345–371
C. Sanchez, J. Livage, Sol-gel chemistry from metal alkoxide precursors. New J. Chem. 4, 513–521 (1990)
T. Ahmad, O. Mamat, The development and characterization of zirconia-silica sand nanoparticles composites. World J. Nano Sci. Eng. 1, 7–14 (2011)
Z.A. Omran, Crystal structure, surface acidity, surface area, catalytic activity and electrical conductivity behaviour of SiO2–ZrO2 system. Commun. Fac. Scit. Univ. Ank. Ser. C 40, 31–44 (1994)
B. Jongsomjit, S. Kittiruangrayub, P. Praserthdam, Study of cobalt dispersion onto the mixed nano-SiO2–ZrO2 supports and its application as a catalytic phase. Mat. Chem. Phys. 105, 14–19 (2007)
S. Araki, Y. Kiyohara, S. Imasaka, S. Tanaka, Y. Miyake, Preparation and pervaporation properties of silica–zirconia membranes. Desalination 266, 46–50 (2011)
G. Cao, Nanostructured and Nanomaterials (Imperial College Press, London, 2004), pp. 185–195
L.P. Borilo, L.N. Spivakova, Synthesis and characterization of ZrO2 thin films. Am. J. Mater. Sci. 2(4), 119–124 (2012)
G.T. Mamott, P. Barnes, S.E. Tarling, S.L. Jones, C.J. Norman, Dynamic studies of zirconia crystallization. J. Mater. Sci. 26, 4054–4061 (1991)
D.R. Acosta, O. Novaro, T. Lopez, R. Gomez, Crystalline phases of sol–gel ZrO2 in the ZrO2-SiO2 system: differential thermal analysis and electron microscopy studies. J. Mater. Res. 10, 1397–1402 (1995)
D.A. Ward, E.I. Ko, Synthesis and structural transformation of zirconia aerogels. Chem. Mater. 5, 956–969 (1993)
T. Lopez, J. Navarrete, R. Gomez, O. Novaro, F. Figueras, H. Armendariz, Preparation of sol-gel sulfated ZrO2–SiO2 and characterization of its surface acidity. Appl. Catal. A 125, 217–232 (1995)
R. Gomez, T. Lopez, X. Bokhimi, E. Muñoz, J.L. Boldu, O. Novaro, Dehydroxylation and the crystalline phases in sol–gel zirconia. J. Sol Gel. Sci. Technol. 11, 309–319 (1998)
Q. Ge, Qinwen, Synthesis and characterization of mesoporous zirconia nanocomposite using self-assembled block copolymer template. Graduate Theses and Dissertations. 12616 (2012)
A.O. Bianchi, M. Campanati, P. Maireles-Torres, E. Rodríguez Castellon, A. Jimenéz López, A. Vaccari, Si/Zr mesoporous catalysts for the vapour phase synthesis of alkylindoles. Appl. Catal. A 220, 105–112 (2001)
F. Gonella, G. Matter, P. Mazzoldi, Structural and optical properties of silver-doped zirconia and mixed zirconia–silica matrices obtained by sol–gel processing. Chem. Mater. 11, 814–821 (1991)
R. Gomez, F. Tzompantzi, T. Lopez, O. Navaro, ZrO2–SiO2 mixed oxides as supports for platinum catalysts. React. Kinet. Catal. Lett. 53(2), 245–251 (1994)
S. Damyanova, L. Petrov, M.A. Centeno, P. Grange, Characterization of molybdenum hydrodesulfurization catalysts supported on ZrO2–Al2O3 and ZrO2–SiO2 carriers. Appl. Catal. A 224, 271–284 (2002)
K. Kamiya, S. Sakka, Y. Tatemichi, Preparation of glass fibres of the ZrO2–SiO2 and Na2O–ZrO2–SiO2 systems from metal alkoxides and their resistance to alkaline solution. J. Mater. Sci. 15, 1765–1771 (1980)
S. Surbhi, S. Kumar, Thermal evolution of mixed oxides of zirconia-silica prepared by sol-gel route, in Physics of semiconductor devices, (Environmental Science and Engineering, Springer International Publishing, Switzerland, 2014), pp. 749–751
S.M. Reda, Synthesis and optical properties of CdS quantum dots embedded in silica matrix thin films and their applications as luminescent solar concentrators. Acta Mater. 56(2), 259–264 (2008)
A. Samavati, Z. Samavati, A.F. Ismail, M.H.D. Othman, M.A. Rahman, A.K. Zulhairun, Efficient visible photoluminescence from self-assembled Ge QDs embedded in silica matrix. Chin. Phys. Lett. 34(6), 068102 (2017)
V.S. Gorelik, Y.P. Voinov, G.A. Emel’chenko, V.M. Masalov, Optical properties of a carbon-zirconia quantum-dot photonic crystal. Inorg. Mater. 46(5), 505–509 (2010)
X. Xin, Z. Lü, X. Huang, X. Sha, Y. Zhang, K. Chen, N. Ai, R. Zhu, W. Su, Solid oxide fuel cells with dense yttria-stabilized zirconia electrolyte membranes fabricated by a dry pressing process. J. Power Sourc. 160(2), 1221–1224 (2006)
S. Hao, C. Wang, T. Liu, Z. Mao, Z. Mao, J. Wang, Fabrication of nanoscale yttria stabilized zirconia for solid oxide fuel cell. Int. J. Hydrogen Energy 42(50), 29949–29959 (2017)
W.C. Maskell, D.J.L. Brett, N.P. Brandon, Thick-film amperometric zirconia oxygen sensors: influence of cobalt oxide as a sintering aid. Meas. Sci. Technol. 25(6), 065104 (2014)
N. Miura, T. Sato, S. Anggraini, H. Ikeda, S. Zhuiykov, A review of mixed-potential type zirconia-based gas sensors. Ionics 20(7), 901–925 (2014)
S. Surbhi, S. Kumar, Effect of annealing temperature on structural, photoluminescence and thermal properties of nanosized zirconium silicates. Adv. Sci. Lett. 20, 1504–1508 (2014)
D.H. Aguilar, L.C. Torres-Gonzalez, L.M. Torres-Martinez, T. Lopez, P. Quintana, A study of the crystallization of ZrO2 in the sol–gel system: ZrO2–SiO2. J. Solid State Chem. 158, 349–357 (2000)
Y. Ma, P. Jia, X. Li, N. Liu, Y. Ma, Synthesis of the ZrO2–SiO2 microspheres as a mesoporous candidate material. J. Porous Mater. 19, 1047–1052 (2012)
N. Agoudjil, N. Benmouhoub, L. Labot, Synthesis and characterization of inorganic membranes and applications. Desalination 184, 65–69 (2005)
M. Popa, J.M. Claderón-Moreno, L. Popescu, M. Kakihana, R. Torecillas, Crystallization of gel-derived and quenched glasses in the ternary oxide Al2O3–ZrO2–SiO2 system. J. Non-Cryst. Solids 297, 290–300 (2002)
F. Monte, W. Larsen, J.D. Mackenzie, Stabilization of tetragonal ZrO2 in ZrO2–SiO2 binary oxides. J. Am. Ceram. Soc. 83(3), 628–634 (2000)
S.W. Lee, R.A. Condrate, Sr, The infrared and Raman spectra of SiO2–ZrO2 glasses prepared by a sol-gel process. J. Mater. Res. 23, 2951–2959 (1988)
J. Coates, Interpretation of infrared spectra, a practical approach, in Encyclopedia of Analytical Chemistry, ed. by R.A. Meyers (Wiley, Chichester, 2000), pp. 10815–10837
R. Hogg, T.W. Healy, D.W. Fuerstenau, Mutual coagulation of colloidal dispersions. Trans. Faraday Soc. 62, 1638–1651 (1966)
A. García Murillo, F.J. Carrilo Romo, A.M. Torres Huerta, M.A. Domínguez Crespo, E. Ramírez, H. Meneses, A. Terrones, Flores Vela, Microstructural evolution of the system Ni–ZrO2–SiO2 synthesized by the sol–gel process. J. Alloys Compd. 495, 574–577 (2010)
J.C. Garcia, L.M.R. Scolfaro, A.T. Lino, V.N. Freire, G.A. Farias, C.C. Silva, H.W. Leite Alves, S.C.P. Rodrigues, E.F. Da Silva Jr., Structural, electronic, and optical properties of ZrO2 from ab initio calculations. J. Appl. Phys. 100, 104103 (2006)
H.Q. Cao, X.Q. Qiu, B. Luo, Y. Liang, Y.H. Zhang, R.Q. Tan, M.J. Zhao, Q.M. Zhu, Synthesis and room-temperature ultraviolet photoluminescence properties of zirconia nanowires. Adv. Funct. Mater. 14, 243–246 (2004)
A. Emeline, G.V. Kataeva, A.S. Litke, A.V. Rudakova, V.K. Ryabchuk, N. Serpone, Spectroscopic and photoluminescence studies of a wide band gap insulating material: powdered and colloidal ZrO2 sols. Langmuir 14, 5011–5022 (1998)
I. Vaizoğullar, A. Balci, M. Uğurlu, Synthesis of ZrO2 and ZrO2/SiO2 particles and photocatalytic degradation of methylene blue. Indian J. Chem. 54A, 1434–1439 (2015)
A. K. Singh, U.T. Nakate, Microwave synthesis, characterization, and photoluminescence properties of nanocrystalline zirconia. Sci. World J. 2014, Article ID. 349457 (2014)
U.K. Patel, K.H. Patel, K.V. Chauhan, A.K. Chawla, S.K. Rawal, Investigation of various properties for zirconium oxide films synthesized by sputtering. Procedia Technol 23, 336–343 (2016)
S.B. Xie, E. Iglesia, A.T. Bell, Water-assisted tetragonal-to-monoclinic phase transformation of ZrO2 at low temperatures. Chem. Mater. 12(8), 2442–2447 (2000)
M. Stoia, P. Barvinschi, F. Barvinschi, Structural and morphologic characterization of zirconia–silica nanocomposites prepared by a modified sol–gel method. J. Cryst. Growth 401, 462–468 (2014)
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Authors gratefully acknowledge University Grants Commission, New Delhi, Govt. of India, for financial assistance in the form of major research project (File no. 42–803/2013(SR) dated 25.03.2013).
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Verma, S., Rani, S. & Kumar, S. Tetragonal zirconia quantum dots in silica matrix prepared by a modified sol–gel protocol. Appl. Phys. A 124, 387 (2018). https://doi.org/10.1007/s00339-018-1806-z
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DOI: https://doi.org/10.1007/s00339-018-1806-z