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Chia oil performance as healing agent for epoxy resin-based smart coatings

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Abstract

The drying properties and the performance of the chia oil (CO) as a novel healing agent for self-healing coatings are reported in this work, in comparison with linseed oil (LO). The drying properties of both oils were estimated by their respective drying rates (D.R.) between 0 and 500 h by Fourier-transform infrared spectroscopy. The D.R. of CO at 216 h was 47% higher than LO, which was attributed to its higher polyunsaturated fatty acids content. CO and LO were encapsulated in poly(urea–formaldehyde) microcapsules by in situ polymerization in oil-in-water emulsion, showing mean diameters of 20 and 23 µm, respectively. Coatings loaded with 10 wt% of microcapsules were applied onto AISI 1020 steel surfaces. The effect of these drying oils as healing agents for self-healing coatings was evaluated by artificial scratches and measured by potentiodynamic polarization test (PPT) and electrochemical impedance spectroscopy (EIS) techniques. Scratched samples showed an increasing corrosion potential of only 4 h after the scratch simulation, according to the PPT. EIS results showed that coatings containing CO as a healing agent had lower double-layer capacitance (QPE2-Q), suggesting a slight improved self-healing effect compared to LO.

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Acknowledgements

The authors are grateful to company POLIKINI Ind. & Comércio for providing AISI 1020 steel samples and for the support from the Materials Engineering and Mechanical Engineering laboratories at the UNIFEI-Campus Itabira. R.L.Lavall would like to thank the Brazilian Institute of Science and Technology (INCT) in Carbon Nanomaterials. A. M. P. Sakita also acknowledges the scholarships received from CAPES and CNPq. R.L. Lavall is a recipient of a fellowship from CNPq (Grant Number 315179/2020-1).

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Authors and Affiliations

  1. Laboratório Interdisciplinar de Materiais Compósitos e Poliméricos (LIMCOP), Instituto de Engenharias Integradas (IEI) da Universidade Federal de Itajubá, Itabira, Minas Gerais, 35903-087, Brazil

    Ana Carolina Moreira Silva, Reny Angela Renzetti, Andreza de Sousa Andrada & Mercês Coelho da Silva

  2. Departamento de Química (DQ) da Universidade Federal de Minas Gerais, Belo Horizonte, Minas Gerais, 31270-901, Brazil

    Alan Massayuki Perdizio Sakita & Rodrigo Lassarote Lavall

  3. College of Engineering and Applied Science, University of Wisconsin-Milwaukee, Milwaukee, WI, 53211, USA

    Pradeep Kumar Rohatgi

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  1. Ana Carolina Moreira Silva
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Correspondence to Ana Carolina Moreira Silva or Mercês Coelho da Silva.

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Silva, A.C.M., Renzetti, R.A., Sakita, A.M.P. et al. Chia oil performance as healing agent for epoxy resin-based smart coatings. Polym. Bull. 79, 8517–8533 (2022). https://doi.org/10.1007/s00289-021-03924-2

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