Linear polyurethanes with imidazoquinazoline rings: preparation and properties evaluation

In this work, research concerning the synthesis and properties of linear polyurethanes (PUs) with the imidazoquinazoline rings was represented. Reaction conditions of 2,6-bis(2-hydroxyethyl)-1-phenylimida-zo[1,5-c]quinazoline-3,5-dione (BHPIQ) with 1,6-hexamethylene diisocyanate were determined and optimized. These conditions are adapted to reaction of BHPIQ with 4,4′-diphenylmethane diisocyanate and 2,4-toluene diisocyanate. New PUs with imidazoquinazoline rings were characterized by spectral methods (1H-NMR and IR spectroscopies), which confirm their structures. Their molar masses and dispersity index were measured by size exclusion chromatography method. The wide-angle X-ray scattering and differential scanning calorimetry (DSC) studies have shown that all PUs based on BHPIQ are amorphous. Moreover, thermal properties of PUs were investigated by thermogravimetry analysis, standard DSC, and temperature-modulated DSC methods. During thermogravimetric measurements, the exhaust gases were analyzed by FTIR method. Incorporation of imidazoquinazoline ring into the PU chains escalates their glass transition temperature; thus, their heat resistance was enhanced. Furthermore, their degradation rate and the amount of released degradation products were reduced. The investigated properties of the obtained PUs with imidazoquinazoline rings were compared with those ones of suitable PUs based on 1,4-butanediol. Linear polyurethanes were obtained in reaction of 1-phenyl-2,6-bis(2-hydroxyethylimidazo[1,5-c]quinazoline-3,5-dione with hexamethylene 1,6-diisocyanate, 4,4′-diphenylmethane diisocyanate and toluene 2,4-diisocyanate. Their composition and structure were confirmed. The phase contents and thermal properties were investigated

reduced. The investigated properties of the obtained PUs with imidazoquinazoline rings were compared with those ones of suitable PUs based on 1,4-butanediol.

Introduction
Polyurethanes (PUs) are one of the most significant industrial polymers. They are applied in the furniture, footwear, textiles, automotive and construction industries as well as in medicine [1][2][3][4][5][6][7][8][9]. From a chemical composition perspective, the PUs -NH-(CO)O-can be seen as a hybrid of polyamides -NH-(CO)-and polyesters -(CO)O-. The urethane group includes both the amide group and the ester group, simultaneously. Nevertheless, the behavior of PUs is closer to polyamides due to their ability to form hydrogen bonds using the urethane "amide moiety." In fact, linear aliphatic PUs may be considered as derivatives of polyamides with the same number of atoms in the main chain in which one methylene group has been replaced by an oxygen atom.
However, the polyurethane's response to a water attack is much weaker than polyester or polyamide. This high hydrolysis resistance can be a disadvantage in those applications where self-destructive material is desirable. In particular, it refers the use of PUs in biomedicine, due to their very good biocompatibility [5][6][7][8][9][10].
Linear PUs are formed as a result of the polyreaction of bifunctional organic diisocyanates with diols. Linear PUs were first obtained in 1940 under the name Perlon. They have been used as foils, fibers and technical products [11]. Today, the linear PUs are one of the most important products with the large commercial tonnage production due to their physic-chemical properties and versatile applications, universal operating characteristics, ecological safety, and the ability to use new design materials with anticipated features [12][13][14][15][16][17].
Linear PUs exhibit small shrinkage, high dimensional stability, low water absorption, good chemical resistance, good abrasion resistance and high resistance to boiling water exposure. Furthermore, linear PUs characterize higher thermal stability than crosslinked ones [18][19][20]. On the other side, the linear PU materials obtained by the prepolymer method undergo thermal decomposition much more easier than their counterparts produced by the one-stage method [21]. Generally, hard segments (HS) in a polyurethane are usually the first to decompose. For equivalent amounts of HS, the polyurethane obtained by the prepolymer method will display longer hard segments than that obtained by the one-stage method; but if these HS are long enough to be semicrystalline they could be more stable than the amorphous HS of the one-stage sample. Thermal stability is highly dependent on the degree of microphase separation.
Unfortunately, PUs do not show too very high thermal stability. Urethane bonds start to decompose at temperature range 180-200 °C [22,23]. Therefore, the properties studies including thermal properties of linear PUs are very important.
It was investigated that an incorporation of aromatic or heteroaromatic rings in the polyurethane backbone leads to higher glass transition temperature and higher time of their thermal stability [24][25][26].
Introduction of heterocyclic moieties into the main chain of the polyurethane has a significant impact on the electric properties and molecular dynamics of the polymer [40,41]. Heterocycles containing nitrogen have been widely investigated due to their unique properties, with possible application in building electronic devices [42,43]. Also, nitrogen heterocyclic rings have long been in use in biomedical research as delivery vectors for bioactive applications due to their ability to form hydrogen bonds with drugs and proteins [44].
Polyurethane elastomer films with pyridine moieties in the main chain form photosensitive materials, which change their color over time in direct relation to storing conditions [45].
PUs with highly functional pyridine rings had substantially improved thermal stability and mechanical properties [30,46,47].
On the other hand, PUs based on hydroxylated polyethers prepared form aromatic diacids have increased hardness and chemical resistance as well as higher glass transition temperature. However, phenyl rings are responsible for absorption of UVlights. It results in photo-oxidative degradation and yellowing of PU coatings upon outdoor exposure [51].
It was also supposed that polyurethanes with imidazoquinazoline rings will exhibit interesting properties. In particular, thermal or thermomechanical properties due to the presence of condensed rings.

Determination of the isocyanate group content
Isocyanate group content was determined by the standard [64].

IR spectroscopy
IR spectra of PUs were recorded on PARAGON 1000 FTIR apparatus. Spectra were made with the resolution of the order of 0.01 cm −1 . Samples were prepared in the form of potassium bromide disks. 1 H-NMR spectra of PUs were recorded on 500 MHz spectrometer (Bruker, Germany). Deuterated dimethyl sulfoxide (d 6 -DMSO) was used as solvent and hexamethyldisiloxane (HMDS) as reference.

Elemental analysis
Elemental analysis (C, H, N) of PUs was performed on an elemental analyser EA 1108, produced by Carlo-Erba.

Determination of molar mass of PUs by size exclusion chromatography (SEC)
The molar mass (number-aver-age ( M n ), weight-average ( M w ) and dispersity index DI = M w × M n −1 ) of the PUs were determined using HT-GPC 220 chromatographic system (Agilent), equipped with a dual detection set-up (refractive index and viscometric response detectors). The samples were dissolved in DMF (∼ 3 mg ml −1 ) overnight. Separation and detection took place on PL gel-mixed bed columns (1 × Mixed-A, 300 × 7.8 mm, 15 μm particles + 1 × Mixed-B, 300 × 7.8 mm, 10 μm particles + 1 × Mixed-D, 300 × 7.8 mm, 5 μm particles) at 50 °C in DMF; the flow rate equaled 1.0 ml min −1 and injection volume was 100 μl. The GPC system was calibrated through universal calibration, with narrow polystyrene standards ranging 580-271,000 g mol −1 (Polymer Laboratories Ltd., UK). All data processing was carried out in Cirrus software.

TG-FTIR analysis
Thermogravimetric analyses of PUs were performed using a Mettler Toledo TGA/ DSC1 apparatus. The experiments have been carried out in the nitrogen atmosphere in the temperature range from 25 to 700 °C at a heating rate of 10 °C min −1 . The measurement conditions were as follows: sample weight ~ 10 mg, gas flow 50 ml min −1 , 150 μl open alumina pan.
TG-FTIR-MS analyses of PUs were performed with the use of Mettler Toledo TGA/DSC1 instrument, which was online coupled with FTIR apparatus Nicolet iZ10 (Thermo Scientific) by a transfer line heated at 220 °C. The FTIR spectra of the evolved gases were acquired in the range of 400-4000 cm −1 with the resolution of 4 cm −1 .

DSC and TMDSC analysis
Measurements were carried out using the standard differential scanning calorimetry (DSC) and temperature-modulated differential scanning calorimetry (TMDSC) of a TA Q1000™ and a TA 2920 from TA Instruments, Inc. (New Castle, DE, USA). These calorimeters are the heat-flux type and use a mechanical refrigerator to cool the sample. All experiments were performed in a nitrogen atmosphere with a constant flow rate of around 50 ml min [65].
The series of experimental heat flow rates were obtained by standard DSC at a heating rate of 10 deg min after previous cooling also at 10 deg min. The temperature and heat flow rate calibration in the DSC apparatus was performed using parameters of melting indium [T m (onset) = 156.6 °C, ΔH f = 28.45 J g (3.281 kJ mol)] [65]. Heating process for the TMDSC measurements was performed using the underlining heating rate equals 3 deg min, and temperature modulation conditions as following: modulation amplitude, A = 1.5 deg and period of modulation, p = 60 s [65,66].
The masses of the samples used for the DSC measurements were 10-30 mg and 3-5 mg for the TMDSC measurements. The thermal data were collected from the second heating run after controlled cooling. By the standard DSC measurements, total heat flow rate and by standard TMDSC total, reversing, and non-reversing heat flow rates as a function of time and temperature were obtained for investigated samples. All processes which are accidental and those which are irreversible are disregarded in this method and belong to non-reversing contributions of the heat flow rate [65,66].

X-ray analysis
Phase composition of the polymer samples was identified using an X-ray diffractometer ARL X'TRA from Thermo Fisher company. Filtered copper lamp with a voltage of 40 kV, range 2θ = 10°-100° and step size 0.02° 3 s was used. Phase

Preparation of linear PUs with imidazoquinazoline rings
In a 50 cm 3 three-necked round-bottom flask equipped with a magnetic stirrer and a reflux condenser, 1.825 g (5 mol) BHPIQ, 10 cm 3 anhydrous N,N-dimethylformamide (DMF) and 0.15 g of DBTL were placed and heated to 90 °C. The reaction was carried out under nitrogen atmosphere. After reaching a temperature of 90 °C, 0.42 g (2.5 mol) of HDI dissolved in 2.5 cm 3 of DMF was added dropwise over 5 min, and after 30 min, the operation was repeated. The reaction mixture was kept at constant temperature for 5 h, i.e., until the reaction was completed. The reaction progress was monitored by checking of NCO groups contents. During the reaction, when the solution viscosity was too high, more solvent (about 5 cm 3 ) was added. The sticky solution was poured into 200 cm 3 of cold ether. Then, it was washed with several portions of water and solvents were evaporated to dryness with the use of toluene. The product was dried to constant weight in a vacuum oven at 190 °C. Table 1 shows the sample codes of all PUs. The synthesis conditions were optimized on the example of reaction with HDI. Finally, it was found that it is the best to introduce the diisocyanate in two portions into reaction mixture. The reactions of BHPIQ with aromatic isocyanates (MDI, TDI) were carried out in analogues conditions ( Table 2). The syntheses of the rest PUs were conducted with the use of 1.25 g (5 mol) of MDI and 0.20 g of DBTL or 0.87 g of TDI (5 mol) and 0.50 g drops of DBTL, respectively ( Table 1). The products were purified by pouring, viscous solutions to 200 cm 3 of cold acetone. The precipitates were filtered off and then washed with several portions of acetone and dried. The reaction conditions are given in Tables 1 and 2    100 cm 3 round-bottom flask equipped with mechanical stirrer, reflux condenser and thermometer. Reaction was carried out in the nitrogen atmosphere. Temperature of the solution was maintained app. 50 °C. Progress of reaction was monitored by determination of isocyanate group content. When reaction was completed, the solvent was evaporated and solid residue was dried to constant mass (t = 60 °C, p = 2 × 10 −3 MPa = 15 mm Hg).
It has been observed that BHPIQ had the shortest reaction time with HDI. Aromatic isocyanates reacted more slowly, in the following order: MDI and then TDI ( Table 2, entry 1-3). The reactivity of diisocyanates with BHPIQ was the opposite of the typical reactivity of diisocyanates with alcohols. Typically, aromatic diisocyanates exhibit higher reactivity than aliphatic ones and TDI is more reactive than MDI [67,68]. In the case of BHPIQ reactions with isocyanates, the reverse reactivity of diisocyanates was observed in relation to the expected. It was due to spatial reasons, and precisely due to the construction of the diol used. The presence of an imidazoquinazoline ring with a phenyl substituent located at a strictly defined angle to the plane of the imidazoquinazoline ring resulted in a high stiffening of the diol molecule. Therefore, BHPIQ reacted easier with an aliphatic diisocyanate, which did not contain aromatic rings and did not cause additional steric hindrance, which could interfere with the reacting hydroxyethyl groups with the isocyanate. A higher reactivity MDI than TDI could be also explained by the increased steric hindrance. The arrangement of the isocyanate groups on the opposite sides of the MDI molecule allowed the reaction to be easier than the location of the two isocyanate groups at one benzene ring of TDI.

Fig. 1 Synthesis scheme of linear PUs with imidazoquinazoline rings
Simultaneously, in order to compare the imidazoquinazoline rings presence on the polyurethane properties, PUs based on BU with the use of HDI, MDI and TDI were prepared ( Table 2, entry 4-6).
All PUs were obtained as powdered cream products. Their composition was confirmed by elemental analysis which results are juxtapositioned in Table 3. The calculated contents of carbon, hydrogen and nitrogen were in accordance with the found ones.

Spectral characterization of linear PUs with imidazoquinazoline rings
The structure of the obtained products was analyzed by 1 H-NMR and IR spectroscopies. The structure characterization of PUs with imidazoquinazoline rings was discussed on the example of the reaction product of BHPIQ with MDI which structure is presented in Fig. 2. Its 1 H-NMR spectrum was illustrated in Fig. 3.
In the 1 H-NMR spectrum of the PU-MDI (Fig. 3), low-intensity signals were observed at 4.8 and 4.9 ppm, i.e., within the proton range of the diol hydroxyl groups. These signals derived from the hydroxyl groups forming the ends of the polymer chains. The presence of two signals was related to the magnetic inequality of the hydroxyl groups of the starting diol.
Protons of carbamate groups were also unequal and appeared in the form of two signals at 9.50 and 9.55 ppm, proton h and g, respectively. The proton signal of the methylene groups a linked to oxygen atoms of the carbamate groups appeared at 4.30 ppm. The remaining methylene groups-protons b and c derived   The IR spectrum of the resulting PU-MDI polyurethane shown in Fig. 4 confirmed the complete conversion of the isocyanate. No band was observed at 2270 cm −1 from the valence vibration of isocyanate groups in the spectrum.
In addition, the band shape in the range of 3600-3100 cm −1 was varied compared to the IR spectrum of BHPIQ because the N-H carbamate valence band appeared (Fig. 4). A valence vibration band of carbonyl groups was at 1754 cm −1 . The symmetrical and asymmetrical vibration bands of the C-O bonds of the carbamate groups were observed at 1218 and 1073 cm −1 , respectively.
The exact spectral characteristics of the remaining PUs with imidazoquinazoline rings were described in the Experimental part. Here, it has been only mentioned that the carbamate protons of the PU-TDI were visible in the 1 H-NMR spectrum in a similar range of δ ppm like in the PU-MDI spectrum (Fig. 3), i.e., at about 9.0 and 9.5 ppm. In the 1 H-NMR spectrum of PU-HDI, the carbamate proton signals overlapped with the quinazoline ring protons in the range of 7.0-7.5 ppm.
The structure of PUs based on BU was confirmed by spectroscopic methods, but it was not described in the work because it is generally known.

Molar masses of linear PUs
In order to evaluate the polymerization degree, SEC measurements were carried out and the molar masses distribution for the obtained PUs were measured and compared. It was illustrated in Fig. 5a, b. Two PUs with imidazoquinazoline ringsaliphatic and aromatic polyurethane PU-HDI and PU-MDI possessed a narrow unimodal and moderately symmetrical distribution with a molar mass dispersity of about 1.7-1.9 [−]. In turn, PU-TDI performed bimodal shape of the distribution shifted to lower values of molar masses and a bit smaller molar mass dispersity of about 1.6 [−] ( Table 4). PU-HDI and PU-MDI had higher molar masses (M w = 21,500 g/mole, and M n = 11,400 and 12,500 g/mole, respectively), what allowed to belong them to polymers (Table 4) [61,[69][70][71]. In turn, molar masses of PU-TDI were smaller (M w = 6200 g/mole and M n = 3900 g/mole); thus, it had to be treated as oligourethane.
In . PUs based on BU and HDI or MDI had also higher molar masses (M w higher than 20,000 g/mole). BU-TDI had smaller molar mass, M w = 11,400 g/mole, and thus also higher than 10,000 g/mole (Table 4).

WAXS studies of linear PUs
Most linear PUs according to the literature [72] have been semicrystalline polymers with high molar masses, high degree crystallinity, and high melting point. Generally, HDI and MDI have had a symmetrical structure, which made HDI-and MDI-based PUs easily crystallized [73][74][75]. In turn, TDI-based PUs have been expected to be amorphous materials.
The X-ray diffraction data, shown in Fig. 6, indicated a distinct crystalline structure only BU-HDI and BU-MDI. In Fig. 6a, we could see the appearance of very sharp Introduction of 1-phenylimidazo [1,5-c]quinazoline rings in the polyurethane structure has disturbed the symmetry of the molecule. Two broad peaks were observed in diffractograms of all PUs based on BHPIQ as shown in Fig. 6b. First one was visible in the region of 2θ = 13°-30° with high intensity and second one with much lower intensity in the region of 30°-60°. The X-ray diffraction pattern all of them was the same. Thus, all PUs based on BHPIQ and polyurethane BU-TDI showed amorphous character.
The X-ray diffraction data of the PUs were further confirmed by DSC and TMDSC studies.

Thermal properties of polyurethane materials
Thermal properties of the obtained linear PUs based on the BU and BHPIQ were studied by DSC and TMDSC methods. Figures 7, 8, 9 and 10 presented the comparison of heat flow rate versus temperature for the obtained PUs based on BHPIQ and the following diisocyanates, i.e., HDI, MDI, and TDI with the typical PUs obtained based on the 1,4-butanediol and the same abovementioned diisocyanates. Figure 7 shows the results obtained based on the standard DSC and TMDSC methods for PU-HDI and BU-HDI. In the case of BU-HDI, the semicrystalline material was observed from DSC measurement. There was visible the glass transition and melting processes. The glass transition occurred at T g = 32.2 °C and the change of heat capacity ΔC p at T g equaled 12.11 J °C −1 mol −1 . Melting was characterized using the following thermal parameters: heat of fusion, ΔH f = 4.15 kJ mol −1 and melting temperature, T m (onset) = 109.6 °C, T m (peak) = 169.4 °C. In the case of the BHPIQ application in the PU matrix instead of 1,4-butanediol, the change in ordering of material was observed. The amorphous material was visible for PU-HDI. The change in ordering between BU-HDI and PU-HDI was related to easy crystallization in the case of the symmetrical particles [39]. Figure 7 shows the glass transition together with the overlapping enthalpy relaxation in T g for PU-HDI_DSC obtained based on the DSC. In order to eliminate the influence of the physical aging process, the TMDSC method was applied for PU-HDI sample. Based on this result, total heat flow rate was separated into reversing and non-reversing components. From reversing heat flow rate presented in Fig. 7, thermal parameters of glass transition were estimated, i.e., temperature of glass transition, T g = 118.3 °C, and the change of heat capacity, ΔC p = 156.41 J mol −1 °C −1 at T g . In Fig. 7, it could see that the presence of BHPIQ in the linear PUs caused elevation of the glass transition temperature of full amorphous sample in reference to semicrystalline BU-HDI. Figure 8 presented the DSC thermogram of amorphous PU-MDI and semicrystalline BU-MDI. Inability to crystallization of PU-MDI compared to PU-HDI resulted from too high rigidity of the chain in the case of polyurethane based on BHPIQ and MDI. Rigidity was caused by the presence of imidazoquinazoline rings and phenyl groups in the PU structure. Furthermore, repeating unit of PU-MDI was also asymmetrical because of phenylimidazoquinazoline ring.
For semicrystalline BU-MDI (see Fig. 8) in glass transition region, the value of T g = 117 °C and the change of heat capacity at T g equaled 58.67 J mol −1 °C −1 . For the melting process, the heat of fusion, ΔH f = 4.46 kJ mol −1 and onset melting temperature, T m (onset) = 202 °C were estimated. Increased the glass transition temperature of PU-MDI compared to BU-MDI, additionally confirmed higher stiffness of PUs with imidazoquinazoline rings. Figure 9 shows the comparison of dependence of the reversing heat flow rate on temperature for PU-HDI, PU-MDI, and PU-TDI obtained by TMDSC. In all cases, there only were visible the glass transitions. This kind of phase transition indicated amorphous nature of materials and confirmed results obtained by WAXS (Fig. 6).
Results of the reversing heat flow rate versus temperature were carried out using TMDSC because this method allowed to eliminate the physical aging in the glass transition region as it was mentioned early. In Table 5, the comparison of the thermal parameters (temperature of glass transition (T g ) and changed of heat capacity ΔC p at T g ) for obtained PUs based on BHPIQ was listed. The highest value of T g was visible for PU-MDI, and this is result of the presence of two phenylene groups in the MDI particles. The lowest glass transition temperature was noted for PU-HDI, and this is due to the presence of the flexible aliphatic chain in the HDI segment. The biggest jump of heat capacity, ΔC p at T g was noted for PU-MDI and was related with the presence of the biggest number of groups able to conformation (rotation) in the repeating units of investigated PU. According to Wunderlich [65,76], each mobile unit in the chain of a polymer macromolecule contributes around 11 J °C −1 mol −1 to the change of heat capacity at T g . The value of 11 J °C −1 mol −1 was an average value and depends on the bonds which were naturally different between different kinds of atoms. The ratio of our measured heat capacity increment (ΔC p ) to the contribution of a single mobile unit (11 J °C −1 mol −1 ) allowed an estimation to be made of the total number of mobile units ("beads") in amorphous materials [65,77,78]. This ratio gave a total of 15-16 mobile units ("beads") of PU-MDI, which start to become mobile at the glass transition. In other cases, the number of beads equaled 14-15 (see Table 5).
In Fig. 10, two amorphous materials (BU-TDI, PU-TDI) were presented. The BU-TDI was unable to crystallization because it was characterized by irregular structure of chain (asymmetrical structure of TDI). Additionally, increased rigidity of the PU-TDI chains was also observed in relation to BU-TDI. The change heat capacity (ΔC p ) of BU-TDI equaled 126.38 J mol −1 °C −1 at T g = 81.8 °C.
Results of thermal analysis of amorphous PU-TDI are also presented in Fig. 9 and Table 5.   both samples is provided in Tables 6 and 7.
Comparing the thermal stability of PUs obtained with the BHPIQ modifier, it was noted that the temperature of 5% of mass loss is the highest for PU-MDI (T 5% = 274 °C). This indicated the highest thermal stability of this sample. The remaining PUs with imidazoquinazoline ring, i.e., PU-HDI and PU-TDI, exhibited a lower temperature of 5% weight loss amounting to 251 and 236 °C, respectively.
It should be noted that the temperature of 20% weight loss is always higher in the case PUs with imidazoquinazoline rings than PUs based on 1,4-butanediol. It is connected with the imidazoquinazoline ring presence. The first stage of PUs degradation is connected with the urethane bond decomposition; therefore, the influence of imidazoquinazoline ring is not visible.
Decomposition of PU-MDI occurred in at least two stages, but the presence of the plateau at the initial stage of degradation could indicate a more complex mechanism. The first stage of degradation occurs in the temperature range of 180-365 °C and was accompanied by Δm 1 = 30.8% of mass loss. This stage was related to the cleavage of the weakest bond in the molecule, which was undoubtedly a urethane bond. It was accompanied by the emission of carbon dioxide, as evidenced by the presence of characteristic CO stretching bands in the range of 2300-2400 cm −1 and 689 cm −1 in the FTIR spectrum of evolved gases (Fig. 13).
In the second stage, which occurred at 365-600 °C, the more thermally stable rings of imidazoquinazoline decomposed. This decomposition was accompanied by releasing of some additional gases such as: ammonia, which was evidenced by the presence of vibration bands at about 3333, 1626, 966 and 930 cm −1 , methane-band at 3016 cm −1 or nitrogen oxides (N=O at 1820 cm −1 ). Aliphatic and aromatic compounds were also found as the decomposition products, as evidenced by the vibration in -CH 3 , > CH 2 groups in the range of 2750-3000 cm −1 and in the C=C group at ca. 691 cm −1 as well as broadening of the band over 3000 cm −1 (C=CH). Vibrations occurring at about 1513 cm −1 could originate from the N-H bond in amines, while those at about 2252 cm −1 could be associated with the presence of -NCO groups in degradation products. The presence of residue at 600 °C was probably related to the formation of non-volatile complex structures composed of condensed aromatic rings.
The identification of degradation products of the obtained polyurethanes with imidazoquinazoline rings was carried out on the basis of NIST Mass Spectral Database [79]. The degradation products of polyurethanes were previously examined in the work [80] and the compound with the imidazoquinazoline ring in the work [81].
PU-TDI was characterized by the lowest thermal stability of all studied samples, as evidenced by the lowest T 5% = 236 °C. This could be related to among others three times less molar mass of PU-TDI compared to the other samples. The decomposition of PU-TDI took place in three stages. The temperature of maximum mass loss rate at the first degradation step was T max1 = 274 °C.
The presence of aliphatic (2800-3000 cm −1 ) and aromatic (1636 cm −1 ) derivatives was observed in addition to the carbon dioxide which derives from the decomposition of urethane bonds at the first stage of PU-TDI degradation occurring in the temperature range of 160-340 °C. Above the 340 °C, there was a split peak, indicating the complex mechanism of this stage. At the temperature of T max2 = 387 °C, FTIR spectra of evolved gases, ammonia (3333, 965 and 930 cm −1 ) and probably methane (3016 cm −1 ), were found. The intensity of the identified bands was reduced in the third step at T max3 = 421 °C (Fig. 14).
The decomposition of the aliphatic polyurethane with the imidazoquinazoline ring-PU-HDI took place in at least three stages, as evidenced by the presence of three peaks on the DTG curve. The first stage of degradation occurred in the range of 180-315 °C and was accompanied by 25.4% of mass loss. The second stage was observed in the range of 315-350 °C with a mass loss of 15.4%.
In the first stage apart from the releasing carbon dioxide (stretching vibrations in the range of 2300-2400 cm −1 and 689 cm −1 ), ammonia was additionally observed, as evidenced by vibrations at ca. 965 and 930 cm −1 . There were also aliphatic structures which were confirmed by vibration of -CH 3 , CH 2 groups in the range of 2900-3000 cm −1 . Additionally, a band at about 1820 cm −1 was found, which may be associated with the presence of nitrogen oxides (Fig. 15a).
In the second stage at T max3 = 326 °C, an increase in the intensity of the bands was observed, which were identified in the first stage (Fig. 15b), which could indicate a similar mechanism of both stages.
The third stage of degradation was in the range of 350-500 °C and was related to the decomposition of the diol modifier. The temperature of maximum mass loss rate at this stage was 433 °C, and the mass loss was Δm 3 = 52.9%. The presence of the plateau at the initial stage of decomposition could indicate the complex mechanism of this stage. In this step (Fig. 15c), the presence of carbonyl group vibrations at about 1700 cm −1 and the vibration of the C=C group at ca. 1620 cm −1 was additionally found. Broadening of the band in the range of 3000-3200 cm −1 and the presence of vibration at approx. 747 cm −1 could indicate the presence of aromatic rings in degradation products. In addition, the band at 3016 cm −1 could indicate the presence of methane. The residue at 600 °C of 6.3% was the smallest of all the studied samples.
Samples of unmodified PUs were generally characterized by a two-stage thermal decomposition in the range of 200-600 °C. The highest temperature of 5% of the mass loss of 285 °C shown, as expected [82], a sample synthesized from an aliphatic HDI. However, this sample was characterized by the lowest amount of char. This could be due to the specific aliphatic structure of the PU chain. There were not any aromatic moieties which could more easily condense.

T max3
A 5% weight loss of the remaining BU-MDI and BU-TDI took place at 261 and 270 °C, respectively. It indicated that only the modified PU obtained with MDI show higher thermal stability than unmodified ones (see Tables 6 and 7). In the other cases, we observed the opposite phenomenon. This was due to the fact that at the beginning of degradation less thermally stable urethane groups decomposed, and latter imidazoquinazoline ring degraded. Ultimately, the effect of the presence of imidazoquinazoline rings in the polymer structure on the increase of its thermal stability could be noted. It should be emphasized that imidazoquinazoline ring-modified PUs exhibited lower mass losses in the first decomposition stage than non-modified PUs. The temperature ranges of the first stage of decomposition of modified and unmodified PUs differed slightly from each other, which made the comparison difficult. However, it was possible to compare the mass loss of all PUs at e.g. 350 °C. They amount to: BU-HDI 58.9%; PU-HDI 40.8%; BU-MDI 56.2%; PU-MDI 30.8%; BU-TDI 52.4% PU-TDI 37.4%.

Conclusions
Linear polyurethanes with imidazoquinazoline rings were obtained with the use of diol -1-phenyl-2,6-bis(2-hydroxyimidazo[1,5-c]quinazoline-3,5-dione. The synthesis conditions of these polyurethanes with selected aliphatic and aromatic diisocyanates have been developed. It was found that the reaction with hexamethylene 1,6-diisocyanate was the fastest, while the aromatic isocyanates reacted more slowly, in the order of 4,4′-diphenylmethane diisocyanate and toluene 2,4-diisocyanate. This was conditioned by the spatial course of the reactions. The composition (elemental analysis) and structure ( 1 H-NMR and IR spectra) of the resulting linear polyurethanes with imidazoquinazoline rings were confirmed by instrumental methods. The determined molar masses indicate that the use of hexamethylene 1,6-diisocyanate and diphenylmethane 4,4′-diisocyanate resulted in the polymers formation. In turn, the product obtained by reaction of diol with toluene 2,4-diisocyanate was an oligourethane.
All obtained modified polyurethanes were amorphous. It was connected with the asymmetrical structure of BHPIQ.
The presence of imidazoquinazoline rings in polyurethane chains has a stabilizing effect. It makes the polymer is more stable at elevated temperatures, its initial degradation rate is reduced and the amount of released degradation products is also reduced.
Introduction of the imidazoquinazoline ring into the chain of the polyurethanes increases their glass transition temperature, which increases the heat resistance of the polymer. Thus, the modified polyurethanes retain their better properties at higher temperatures.
It should be emphasized that the glass transition temperature of the resulting modified polyurethane based on MDI exceeds 150 °C, which is characteristic of only a few plastics.
These new polyurethanes can be used as additives to modify the thermal and or mechanical properties of other polymers, polymer composites with in hybrid nanocomposites. The last ones will be the subject of next paper.