Processability approach for laser powder bed fusion of metallic alloys

Processability refers to the ease of achieving the required component while maintaining mechanical performance and processing schedules, which are critical for determining the cost and efficiency of using a given material, from the raw condition to the final product of any manufacturing process. Components built using the laser powder bed fusion with metallic alloys (LPBF-M) process show variability in their mechanical performance, which can be attributed to a range of process parameters and characteristics of the powder material employed by each type of machine. These variations are currently hindering the adoption of this technology at the industrial level. This paper presents a processability approach that could be applied in the LPBF-M to evaluate the possibility of speeding up productivity and minimising the effect on the mechanical properties and relative density and is defined based on the process parameters and powder material characteristics that generate the melting pool and meet bonding criteria at a specific build rate. A case study is carried out with stainless steel 316 (SS316), although this processability analysis could be applied to any other alloy. The results show that a wide range of process parameters generates a suitable processability interval with different values of the build rate. It is also found that slow build rates give rise to less variability in the mechanical properties, while faster rates produce more variability; this is caused by a fast-growing melt pool due to the use of high scan velocities for the SS316 alloy under study.


Introduction
Additive manufacturing (AM) enables the fabrication of parts by reducing the number of fabrication steps due to the use of a layerwise construction process, unlike conventional manufacturing processes.The process of powder bed fusion (PBF), a type of AM technology, allows for the fabrication of complex components such as lattice structures, topology-optimised structures, and personalised organic shapes [1,2].Depending on the material being processed (polymer or metallic alloys) and the manufacturing machine used, PBF offers different mechanisms for processing the material, which include solidstate sintering, chemically induced binding, liquid phase sintering, and full melting.Most commercial processes primarily utilise liquid phase sintering, such as selective laser sintering (SLS), to process polymers, whereas full melting is used to process metallic alloys, for example, via laser powder bed fusion (LPBF) or electron powder bed fusion (EPBF) [3,4].
When the LPBF process is applied to metallic alloys (LPBF-M), a source of laser energy with power (P) and scan speed (v) is selectively used to melt micrometric particles of a powder, which are spread over a build plate.The absorbed energy is conducted from the surface to the interior of the powder, forming a hot liquid volume known as a melting pool.In this process, which is based on the conduction, radiation, and convection heat transfer processes, the following thermal phenomena occur: (a) Single melt pools bond with the build plate, which then solidifies and cools rapidly (at a rate 10 6 to 10 8 K/s) [5,6].The distance between adjacent laser tracks is referred to as the hatch distance (h d ).(b) These solidified melt pools are adjacent to each other and form a layer.(c) Once a complete layer has melted, the build plate is lowered by a predefined distance (known as the layer thickness, l t ), and more powder is spread over the melted layer.This is repeated until a complete component has been built.
In LPBF-M, a laser is used to melt powder contained in a chamber with inert gas.This process involves spot sizes (σ spot ) of approximately 50-100 µm, a typical P of 50-400 W, a value for v of 200-2500 mm/s, a value of l t of 30-60 µm, and particle powder sizes of 20-40 µm.Other technologies use an electron beam rather than a laser as a source of energy to process the material in a vacuum chamber (EPBF-M).In EPBF-M, the σ spot size, P, v, l t , and powder size are approximately 120-140 µm, up to 3000 W, 3000-42000 mm/s, 50-200 µm, and 40-100 µm, respectively (i.e., higher than those in LPBF [7][8][9][10][11]).
There are a variety of custom-made and commercially available systems for LPBF-M, each with its own manufacturing capabilities that depend on the process parameters used by the system and the characteristics of the powder alloy [12].The powder alloy shows changes in the temperature gradients, cooling rates, thermal stresses, and dimensions of the melt pool, which could induce defects such as pores and balls that compromise the manufacturing performance of the part.To achieve parts that are free of defects, it is necessary to generate layers consisting of continuous melt pool tracks and healthy thermal conditions.This is achieved by studying the effects of changing the parameters, such as P, v, h d , and l t ; whenever these parameters are changed, the characteristics of the constructed parts, such as their density, mechanical performance, and surface finish, are modified [12][13][14][15][16].
Additionally, P vs. v diagrams have been created, which allow the identification of different regions.A region free of defects occurs when appropriate values of P vs. v are selected.However, a region of balling defects arises when high values of P and v are chosen, as shown in Fig. 1.When a high P and low v are used, the boiling point temperature is achieved, and the keyhole mode arises, while a low P and high v result in a region with a lack of fusion [20][21][22][23][24].
The energy density (ED), which is defined as ED = P/v*h d *l t , has been widely studied in regard to LPBF-M with the aim of relating the process parameters to the characteristics of the final components.The ED relation helps in understanding the process in terms of the amount of energy employed, regardless of the material characteristics at different machine parameters.However, it does have some disadvantages, as a given value of ED may be obtained for different combinations of P and v.For example, an h d of 100 µm and a v of 50 mm/s result in the same value for the linear volumetric ED v as an h d of 50 µm and a v of 100 mm/s, where P and l t are constant, but these ED V values will give melt pools of different sizes.Another disadvantage is that the mechanical properties resulting from a given ED value are not replicated in another system, even with the same alloy and process parameters but different powder characteristics, meaning that identifying when defects will appear is very difficult [12,17,20,25].
Material characteristics are not included in the ED relation, but they are key in performance variability in terms of the mechanical properties, density, and surface finishing with LPFB-M.For example, Fig. 2 shows the parameters that have been employed by different authors [18,19,26] with different types of equipment and the corresponding mechanical property performance of SS316 alloy.It should be noted that with different process parameters, relative densities of up to 98% could be achieved; however, the ED and the mechanical property behaviour were very different in each case, as well as the build rate (BR), which is a measure of the amount of material melted per unit time (defined as BR = v*h d *l t ) [27,28]. Figure 2 shows that when a given combination of process parameters is applied to the same alloy, the results show variations that depend on the conditions generated during manufacture, such as the ED, making it difficult to determine whether that combination is the best for the processability of the material.
As shown, LPBF-M is a complex manufacturing technology that involves linking material characteristics and selected process parameters by generating intermediate stages, such as melt pools with corresponding temperatures and dimensions, that determine the performance of the built components (i.e., mechanical properties, relative density, roughness, etc.).The process parameters also modify the processing time.
Sisanth et al. [29] defined processability for polymers as "the behaviour and interactions of polymer, filler, oil and other additives during various processing stages, such as mixing, extrusion, calendaring, and moulding process".It has been measured based on parameters such as the cure time, scorch time, viscosity, and extrusion rate.[17][18][19] In regard to LPBF-M, a similar concept was proposed by Mukherjee et al. [30].This author defined printability as "the ability of an alloy to resist distortion, compositional changes and lack of fusion defects" for powder-based AM processes.This concept can be compared with weldability, which is the possibility and ease of welding two alloys [31].Metallurgic welding technologies, which form the basis of LPBF, have been used to study the LPBF process and to improve it [32]; however, certain differences, such as the use of a higher energy and a continuous medium in welding, make it difficult to apply this approach to a technique such as LPBF, in which a discontinuous material powder alloy is used.Characteristics such as the powder size distribution and morphology have impacts on the laser absorptivity, dynamics and dimensions of the melt pool, cooling rates, and defects and have consequences in terms of the final characteristics of the part, such as its rugosity, relative density, microstructure, and mechanical properties [5,[33][34][35][36][37][38].
Research studying processability for LPBF-M has been conducted to establish a relationship between densification behaviours, such as defect formation mechanisms, and specific processing parameters [39].Gu et al. [5] studied the processability of Inconel 718 alloy in terms of the influence of the particle size on the flow behaviour of the powder and the melting and solidification characteristics.They found that smooth melt pool tracks could be created with a powder size of 25 µm, and defects such as balling could be avoided in this way.Engeli et al. [33] studied the processability of IN738LC alloys with different powder sizes in terms of the size of the melt pool, width, porosity, and cracking and concluded that small changes in the composition and size distribution of the powder could strongly affect cracking.Recently, Balba et al. [38] studied processability in relation to density, surface quality, microhardness, and dimensional accuracy with both a fine powder (D50 = 9 µm) and a coarse powder (D50 = 40 µm).They found that with coarse powder, it was possible to achieve higher densities, lower rugosity, finer microstructures, and higher microhardness.Cosma et al. [40] analysed SS316 via experiments and proposed evaluating the processability based on the quality of construction (i.e., unstable, relatively unstable, and stable processability).
In general, the term processability refers to how easily the required processing schedules can be achieved, as stable processing is needed to make production feasible, which is important for determining the cost and efficiency of a given material, from the raw condition to the final product of any manufacturing process.As material processing methods differ considerably from one material to another, the measures used to evaluate these processing methods also vary [41].For a given material, processability is a performance factor that not only determines the efficiency of industrial production but also plays an essential role in product quality [42].To the best of our knowledge, processability has not been fully defined and studied in relation to LPBF-M.
In this article, we explore a processability approach and qualitative analysis based on the interaction between the process parameters and the powder material and propose a quantitative approach to processability to ensure that components are free from defects.We also present a case study to validate our approach.

Processability
Previous studies of processability have included the interaction between the material characteristics and the process parameters (together or separately) to determine their impacts on density, lack of defects, surface quality, microhardness, and dimensional accuracy.However, no quantitative measurements of this quantity have been proposed; the impact between the process parameters and material characteristics and its impact on productivity have not been considered.

Proposal of processability for LPBF-M
We consider that once the metallic powder alloy is able to be melted and solidified, there is a wide range of combinations of process parameters that would allow for an increase in the build rate.We therefore propose a definition of the processability for LPBF with metallic alloys as the estimated build rate resulting for free-of-defect components built based on the interaction between the powder metallic alloy and the process parameters, verifying that it meets the application quality requirements.
The authors propose the following steps for quantifying the processability: 1. Identify a safe range of temperatures for free-of-defect construction, which must be between the melting and boiling temperatures, based on the intrinsic properties of the alloy employed.2. Estimate the temperature that will be reached based on the available machine process parameters (v, P, and spot size) and the material characteristics (such as absorptivity, thermal diffusivity, and thermal conductivity).3. Estimate the dimensions of the melt pool to propose a suitable hatch distance according to W to calculate the BR based on the v, l t , and h d parameters.4. Verify if the component meets the application quality requirements (such as the mechanical properties, roughness, and relative density) at the selected BR values.

Analytical background
At the start of the LPBF-M process, a laser spot hits the metal powder; the temperature (T) then rises, and a melting pool is generated as long as the temperature is higher than the melting temperature (T m ).The temperature continues to rise until the maximum value is achieved for the P and v parameters, and it is recommended that T does not exceed the boiling temperature (T b ).Once the maximum temperature is reached, the material begins to cool down, and the melt pool begins to solidify until the temperature falls below the liquidus temperature [43,44], as shown in Fig. 3a.Depending on the process parameters, the melting pools achieve a certain depth (D), width (W), and length (L), as shown in Fig. 3b.To estimate the closeness between the generated melt pool and the surrounding solidified material, relations such as D/l t and h d /W are used [30,31,45].
The melt pool that results from the interaction between the powder metallic alloy and the laser power and scan speed can reach different sizes and temperatures, which define the amount of material that can be melted in a unit of time.The analytical equations utilised in this document for calculating T and melt pool dimensions take into consideration material characteristics, providing a straightforward and efficient implementation.Productivity is determined using a build rate equation that incorporates various process parameters.

Temperature model
There are several models in the research literature for estimating the temperature during the process of melting a powder by a laser [46][47][48].In this work, we use the analytical model presented by King et al. [49], which estimates the temperature reached at the centre of the melt pool as a function of a specific beam size σ spot as follows: where I is the laser intensity and is calculated as I = P 2 2 ; A is the absorptivity of the powder material; α is the thermal diffusivity; k is the thermal conductivity; and σ is the laser spot size.This expression can be used to estimate the geometrical dimensions of the Gaussian stationary laser, the limits of the free-of-defect temperature in the LPBF-M process, and the resulting geometrical dimensions of the melt pool. (1)

Models for the dimensions of the melt pool
There are models in the literature that can be used to obtain the dimensions of the melt pool based on the size of the laser spot and the thermophysical properties of the material.The model proposed by Tang et al. [50] based on the Rosenthal equation can be employed to predict the melt pool dimensions that, when compared with experimental results, gives an adequate W for the melt pool [45].This model [50,51] gives an estimate of the thermal characteristics of the melt pool as follows: (2) where T (K) is the local temperature, T 0 (K) is the temperature inside the chamber, P is the power of the laser (W), v is the scan speed (m/s), k (W/mK) is the thermal conductivity, and α is the thermal diffusivity.R is defined as R = ξ 2 + y 2 + z 2 [m] and is the radial distance from the position of the laser, where ξ is the distance from the laser along the direction of travel, y is the distance parallel to the workpiece, and z is the depth below the surface of the workpiece.Simplified approximate expressions were derived from Rosenthal's equation to calculate the width (W) and depth (D) (µm) of the melt pool, as follows [45,52]: There are many other models [53,54] that could be used to predict the size of the melt pool.A suitable selection should be considered to find adequate values of the process parameter h d and the melt pool relation D/l t .

Build rate
Based on the process parameters v, l t , and h d , the BR is calculated using (cm 3 /h) [27,28] and is evaluated through

Processability chart
Based on the steps proposed in Sect.2.1 for quantifying the processability and the equations introduced in Sect.2.2, processability charts can be generated, as shown in Fig. 4.These charts show the relationship between temperature and BR and indicate the limits defined by the metallic powder  The value of T, a consequence of the powder alloy characteristics (such as absorptivity, thermal diffusivity, and thermal conductivity) when interacting with the process parameters (such as P, v, and spot size), is plotted vs. BR for fixed values of h d and l t , and it should be greater than T m but lower than T b .The processability chart shows the material temperature limits and the parameters that could be used to build a component and their impact on the achievable productivity, but every processability value should be reviewed at different mechanical tests to verify the application quality requirement.
3 Case study

Materials and methods
To validate the concept of processability proposed in this work, an experimental dataset and results from the literature [55] were used.In this study, a discontinuous laser LPFB-M machine (Renishaw AM250) with a laser spot (σ spot ) of 70 µm and wavelength of ƛ = 1064 nm was employed under an argon atmosphere with leftover oxygen of 100 ppm in the build chamber.Multiple stainless steel 316 cubes of 10 × 10 × 10 mm were manufactured by Zhu et al. [55] to measure density based on Archimedes' principle using a 0.1 mg electronic balance (Sartorius BSA124S); for this test, the measurement was repeated three times.Based on density measures, the relative density is estimated as the ratio between the measured density and the literature-reported stainless steel 316 density.Hardness was measured using the same cubes on the top of the surface using a hardness tester (NDT-TIME TMVS-1) applying a load of 500 g.The tensile strength was determined with an electronic universal tester (CMT5305) according to Chinese Standard No. GB/T 228-2002.The test specimen had a gauge length of 25, and the length, width, and thickness were 50 mm, 4 mm, and 2 mm, respectively.Flexural strength was tested using a CMT4204 universal testing machine according to Chinese Standard No. GB/T 14452-93.Samples had dimensions of 40 × 6 × 3 mm, torsional strength was carried out using a torsion testing machine (NJ-100B), the gauge length was 30 mm, and the overall length and diameter gauge cross sections were 54 mm and 6 mm, respectively.The wear rate was tested using a pin-on-disk rig (Langz-hou Zhongkekeihua Tech.Co., China) using head pins 6 mm in diameter.According to Zhu et al. [55], discs made of 38CrMoAl were employed in wear tests, and these discs hardened to 0.5 mm depth through iron nitriding (1000 HV hardness).Contact surfaces of pins and discs were polished to an RMS value of Ra ¼ 0.02 mm.Each 30-min test was repeated three times, using a speed of 400 rpm and a rotation radius of 8 mm, with an applied load of 8 N. The Archard equation was used to calculate the wear rate, while pin mass loss was determined by pre-and posttest weighing.Samples were cleaned using acetone after testing.The complete procedures are described in [55].The mechanical properties were plotted against T for three values of BR.  thermal diffusivity α = 0.0000039 m 2 /s; and heat capacity 450 W/mK [56].The powder particles were spherical, with sizes in the range of 15 to 45 µm.Processability charts were created based on the BRs against T values.For the process parameters listed above, processability calculations are presented in Table 1.In addition, estimates of the melt pool dimensions and the relations D/l t and h d /W are presented.
The processability results are plotted in Fig. 5, and two regions that are suitable for processability are shown.The processability for the process parameters used by Zhu et al. [55] is plotted in magenta, while the potential processing region is highlighted in cyan.

Results and discussion
The mechanical properties for the different values of T reached are presented in Figs. 6 and 7 for three different values of BR (BR 1 = 14.85 cm 3 /h, BR 2 = 16.97 cm 3 /h, BR 3 = 19.80 cm 3 /h).It can be seen from the figure that the performance in terms of the relative density, torsional strength, hardness, and wear rate improves as T increases for each value of BR evaluated.
The tensile strength and flexural strength behaviour reach a maximum value (at approximately 55% and 75% of the difference between T b and T m ) but decrease as the boiling temperature is approached.
It can be observed that the highest tensile strength is achieved for BR 3 (the coldest and fastest conditions of the three).BR 1 and BR 2 operate at a higher T than BR 3 , and the tensile strength diminishes as T b is approached.Reports in the literature [23] note that operation at higher ED values and beyond the boiling temperature is not recommended for the LPBF-M process, as this generates the keyhole mode and increases porosity in the component.
Figure 6a, b illustrate that the highest relative density is attained when BR1 and BR2 are at their hottest near T b .However, this does not correspond to higher tensile strength values.Excessive energy increases the thermal gradient and then promotes cracking and microstructural changes, according to Niendorf et al. and Montero et al. [57,58], who carried out experimental tests for SS316 with P of 400 and 1000 W, showing that the ultimate tensile strength was reduced due to the crystallographic textured columnar coarse grains produced by high P.While the results were dense up to 99%, the mechanical performance of components built at Fig. 7 Behaviour of mechanical properties for varying T and different values of BR: a temperature vs. hardness, b temperature vs. torsional strength, and c temperature vs. wear rate low P was superior to those built at higher P values regarding elongation, tensile strength, yield strength, and hardness; Montero also stated that this decay was due to excessive energy input that promoted cracks propagated in the tensile test direction.
We can see that when T is approximately 2500 K, all of the BRs give similar values for the tensile strength; this suggests that at this temperature, it is possible to increase BR with similar tensile strength as BR 1 and BR 2 .At this value of T, which represents 55% of the range from T m to T b , it is possible to explore using a high BR (e.g., BR 3 ) without compromising the tensile strength performance.Higher temperatures could be employed, but high cooling rates would then be present, which would induce cracking behaviour and, hence, a reduction in mechanical performance, as noted by Xiang et al. and Gao et al. [59,60].
Table 2 shows that low scan speeds (e.g., BR 1 ) are associated with smaller variations in mechanical properties than higher scan speeds (e.g., BR 2 and BR 3 ), with the exception of the wear rate.
The model proposed by Tang et al. [50] includes the material properties, and the calculations are simplified compared to finite element and computational fluid simulations; however, at higher linear energy densities, W is narrower than in the experimental results due to the thermal losses that occur during convection and radiation, which are neglected in this model [61].Hence, another analytical model or scaling law should be used.
Processability involves a complex interplay between several factors, including the T b and T m related to the powder alloy and the processing parameters selected, considering and evaluating the potential interactions and trade-offs on mechanical property performance.

Conclusions
We have proposed a method of quantifying the processability based on the BR for the LPBF-M process.This metric depends on the process parameters employed and the characteristics of the material.The results presented here suggest that it is necessary to identify the impact of modifying BR on the mechanical properties.All alloys have different temperature gradients, cooling rates, thermal stresses, and melt pool dimensions due to the variations in the process parameters.
The proposed strategy estimates the temperature of the melt pool during the process based on the characteristics of the metallic alloy powder for particular process parameters (i.e., a particular machine).
Our study of processability suggests that it is possible to speed up the construction by 30% while maintaining similar mechanical properties (hardness, torsional strength, and wear rate) and even improving some properties, such as tensile strength.The concept and analysis of processability presented in this work contribute to the field of LPBF-M by allowing manufacturers to select from a wide range of process parameters and monitor productivity and mechanical property performance.Future work will be required to validate this concept for other alloys and process parameters.We have identified the opportunity to study a widespread of P, v, and h d combinations, considering the potential of decreasing the build time during manufacturing and the impact on the mechanical properties.

Fig. 3 a
Fig. 3 a Temperature behaviour according to time and b resulting melting pool

Fig. 4
Fig. 4 Processability chart, showing build rate and temperature for different values of P. The areas shown in cyan represent a suitable region for processability

Fig. 5
Fig. 5 Processability chart showing relations between T and BR for different process parameters Zhu et al. experiments region Samples were processed by Zhu et al. [55] with five different levels of laser power (120, 140, 160, 180, and 200 W) and three different exposure times (e t ) of 60, 70, and 80 µs.The process parameters were a hatch distance (h d ) of 110 µm, a point distance p d of 60 µm, and a l t of 50 µm.A meander scan strategy was used.v was calculated based on the relation v = p d /e t .Table 1 shows the calculated BRs based on the estimated scan speeds.The properties of the SS316 alloy used by the authors of the present paper were as follows: absorptivity A = 0.35; melting temperature T m = 1678 K; boiling temperature T b = 3090 K; density ρ = 7800 kg/m 3 ; thermal conductivity k = 14 W/mK;

Fig. 6
Fig. 6 Behaviour of mechanical properties for varying T and different values of BR: a temperature vs. tensile strength, b temperature vs. relative density, c temperature vs. flexural strength, d temperature vs. hardness, e temperature vs. torsional strength, and f temperature vs. wear rate

Table 1
Calculations of BR, T, alloy.The potential processing region is highlighted in cyan.

Table 2
Variability in mechanical performance with BR