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Derivatives ofβ- chlorosulfenylcarboxylic acids and their reactions with nucleophilic reagents

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction ofβ-chlorosulfenylcarboxylic acids with CH3COSH gave the correspondingβ-(acetyldithio) carboxylic acids, reaction with H2S gave di-(β-carboxy) andβ-carbomethoxyethyl)trisulfides, while reaction with C6H5MgBr gave the methyl esters ofβ-Cphenylthio)- andα-chloro-β-(phenylthio)propionic acids.

  2. 2.

    The presence of chlorine atomsα-, and especiallyβ-) in theβ-cblorosulfenylcarboxylic acids lowers the reactivity of the SCI group toward weak nucleophiles.

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Literature cited

  1. T. P. Vasil'eva, M. G. Lin'kova, O. V. Kil'disheva, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 209 (1973).

  2. I. L. Knunyants, M. G. Lin'kova, and N. L. Veller, Izv. Akad. Nauk SSSR, Ser. Khim., 1075 (1966).

  3. W. H. Mueller, J. Org. Chem.,34, 2955 (1969).

    Google Scholar 

  4. M. G. Lin'kova, L. P. Parshina, Z. K. Stumbrevichute, O. V. Kil'disheva, and I. L. Knunyants, Dokl. Akad. Nauk SSSR,196, 1089 (1971).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    T. P. Vasil'eva, M. G. Lin'kova, O. V. Kil'disheva & I. L. Knunyants

Authors
  1. T. P. Vasil'eva
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  2. M. G. Lin'kova
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  3. O. V. Kil'disheva
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  4. I. L. Knunyants
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2379–2382, October, 1973.

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Vasil'eva, T.P., Lin'kova, M.G., Kil'disheva, O.V. et al. Derivatives ofβ- chlorosulfenylcarboxylic acids and their reactions with nucleophilic reagents. Russ Chem Bull 22, 2327–2329 (1973). https://doi.org/10.1007/BF01199651

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  • DOI: https://doi.org/10.1007/BF01199651

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