Skip to main content

Advertisement

SpringerLink
Log in

Influence of vanadium nanoclusters in hydrogen uptake using hybrid nanostructured materials

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

In this work, we report the synthesis and characterization of vanadium oxide nanoclusters (V2O5) supported in silica nanostructured material (SBA-15) and nanostructured carbon (CMK-3). This material is promising in hydrogen adsorption and storage application for energy harvesting. The materials with vanadium oxide nanoclusters (VxOy-SBA-15 and VxOy-CMK-3) were successfully synthesized and characterized by X-ray diffraction, textural properties, UV–Vis-DRS, X-ray photoelectron spectroscopy, temperature programmed reduction and transmission electron microscopy analyses. VxOy-SBA-15 and VxOy-CMK-3 improved significantly the H2 storage behavior (1.33 wt% and 3.43 wt% at 77 K and 10 bar) compared with their respective supports SBA-15 and CMK-3. The materials synthesized are promising in hydrogen uptake by weak link forces (physisorption). A mechanism of hydrogen adsorption was proposed and V5+ cation roll in hydrogen uptake was discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. G.W. Crabtree, M.S. Dresselhaus, Mat. Res. Bull. 33, 421–428 (2008)

    Article  CAS  Google Scholar 

  2. P. Dibandjo, C. Zlotea, R. Gadiou, C.M. Ghimbeu, F. Cuevas, M. Latroche, E. Leroy, C. Vix-Guterl, Int. J. Hydrog. Energy 38, 952–965 (2013)

    Article  CAS  Google Scholar 

  3. Office of Energy Efficiency & Renewable Energy: https://energy.gov/eere/fuelcells/hydrogen-storage

  4. M. Bastos-Neto, C. Patzschke, M. Lange, J. Mollmer, A. Moller, S. Fichtner, C. Schrage, D. Lassig, J. Lincke, R. Staudt, H. Krautscheid, R. Glaser, Energy Environ. Sci. 5, 8294–8303 (2012)

    Article  CAS  Google Scholar 

  5. S. Satyapal, J. Petrovic, C. Read, G. Thomas, G. Ordaz, Catal. Today 120, 246–256 (2007)

    Article  CAS  Google Scholar 

  6. T.H. Fang, W.J. Chang, C.C. Huang, W.L. Sun, Int. J. Hydrog. Energy 41, 13771–13776 (2016)

    Article  CAS  Google Scholar 

  7. S. Schaefer, V. Fierro, M.T. Izquierdo, A. Celzard, Int. J. Hydrog. Energy 41, 12146–12156 (2016)

    Article  CAS  Google Scholar 

  8. W. Zhao, V. Fierro, C. Zlotea, E. Aylon, M.T. Izquierdo, M. Latroche, A. Celzarda, Int. J. Hydrog. Energy 36, 11746–11751 (2011)

    Article  CAS  Google Scholar 

  9. D. Saha, S. Deng, Int. J. Hydrog. Energy 34, 2670–2678 (2009)

    Article  CAS  Google Scholar 

  10. S.N. Klyamkin, S.V. Chuvikov, N.V. Maletskaya, E.V. Kogan, V.P. Fedin, K.A. Kovalenko, D.N. Dybtsev, Int. J. Energy Res. 38, 1562–1570 (2014)

    Article  CAS  Google Scholar 

  11. H. Kajiura, S. Tsutsui, K. Kadono, M. Kakuta, M. Ata, Y. Murakami, Appl. Phys. Lett. 82, 1105–1107 (2003)

    Article  CAS  Google Scholar 

  12. N.T. Mandoki, J. Dentzer, T. Piquero, S. Saadallah, P. David, C.V. Guterl, Carbon 42, 2744–2747 (2004)

    Article  CAS  Google Scholar 

  13. W.Y. Pan, X.F. Zhang, S. Li, D.H. Wu, Z.Q. Mao, Int. J. Hydrog. Energy 30, 719–722 (2005)

    Article  CAS  Google Scholar 

  14. A.D. Lueking, R.T. Yang, N.M. Rodriguez, R.T.K. Baker, Langmuir 20(3), 714–721 (2004)

    Article  CAS  PubMed  Google Scholar 

  15. R. Ströbel, J. Garche, P.T. Moseley, L. Jörissen, G. Wolf, J. Power Sources 159(2), 781–801 (2006)

    Article  CAS  Google Scholar 

  16. M.R. Smith, E.W. Bittner, W. Shi, J.K. Johnson, B.C. Bockrath, J. Phys. Chem. B 107, 3752–6370 (2003)

    Article  CAS  Google Scholar 

  17. J.M. Blackman, J.W. Patrick, A. Arenillas, W. Shi, C.E. Snape, Carbon 44, 1376–1385 (2006)

    Article  CAS  Google Scholar 

  18. J.P. Singer, A. Mayergoyz, C. Portet, E. Schneider, Y. Gogotsi, J.E. Fischer, Microporous Mesoporous Mater. 116, 469–472 (2008)

    Article  CAS  Google Scholar 

  19. E. Poirier, R. Chahine, T.K. Bose, Int. J. Hydrog. Energy 26, 831–835 (2001)

    Article  CAS  Google Scholar 

  20. H. Yang, D. Zhao, J. Mater. Chem. 15, 1217–1231 (2005)

    CAS  Google Scholar 

  21. M. Anbia, A. Ghaffari, Appl. Surf. Sci. 255, 9487–9492 (2009)

    Article  CAS  Google Scholar 

  22. M. Anbia, Z. Parvin, Chem. Eng. Res. Des. 89, 641–647 (2011)

    Article  CAS  Google Scholar 

  23. R. Schmidt, M. Stöcker, E.W. Hansen, D. Akporiaye, O.H. Ellestadab, Microporous Mater. 3, 443–448 (1995)

    Article  CAS  Google Scholar 

  24. G. Soler-Illia, C. Sanchez, B. Lebeau, J. Patarin, Chem. Rev. 102, 4093–4138 (2002)

    Article  CAS  PubMed  Google Scholar 

  25. S. Kumar, A. Jain, T. Ichikawa, Y. Kojima, G.K. Dey, Renew. Sust. Energy Rev. 72, 791–800 (2017)

    Article  CAS  Google Scholar 

  26. S. Giraudet, Z. Zhu, Carbon 49, 398–405 (2011)

    Article  CAS  Google Scholar 

  27. U. Suryavanshi, T. Iijima, A. Hayashia, Y. Hayashi, M. Tanemura, Chem. Eng. J. 179, 388–393 (2012)

    Article  CAS  Google Scholar 

  28. J.S. Im, O. Kwon, Y.H. Kim, S.-J. Park, Y.-S. Lee, Microporous Mesoporous Mater. 115, 514–521 (2008)

    Article  CAS  Google Scholar 

  29. J.M. Juárez, M.B. Gómez Costa, O.A. Anunziata, Int. J. Energy Res. 39, 128–139 (2015)

    Article  CAS  Google Scholar 

  30. J.M. Juárez, M.B. Gómez Costa, O.A. Anunziata, Int. J. Energy Res. 39, 941–953 (2015)

    Article  CAS  Google Scholar 

  31. M.B. Gómez Costa, J.M. Juárez, G. Pecchi, O.A. Anunziata, Bull. Mater. Sci. 40, 271–280 (2017)

    Article  CAS  Google Scholar 

  32. M. Konni, A.S. Dadhich, S.B. Mukkamala, Int. J. Hydrog. Energy 42, 953–959 (2017)

    Article  CAS  Google Scholar 

  33. V. Meynen, P. Cool, E.F. Vansant, Microporous Mesoporous Mater. 125, 170–223 (2009)

    Article  CAS  Google Scholar 

  34. W. Ding, W. Zhu, J. Xiong, L. Yang, A. Wei, M. Zhang, H. Li, Chem. Eng. J. 266, 213–221 (2015)

    Article  CAS  Google Scholar 

  35. S. Chaliha, K.G. Bhattacharyya, Catal. Today 141, 225–233 (2009)

    Article  CAS  Google Scholar 

  36. J. Goscianska, A. Olejnik, I. Nowak, M. Marciniak, R. Pietrzak, Eur. J. Pharm. Biopharm. 94, 550–555 (2015)

    Article  CAS  PubMed  Google Scholar 

  37. M.B. Gómez Costa, J.M. Juárez, M.L. Martínez, A.R. Beltramone, J. Cussa, Mat. Res. Bull. 48, 661–667 (2013)

    Article  CAS  Google Scholar 

  38. M.A. Larrubia, G. Busca, Mater. Chem. Phys. 72, 337–346 (2001)

    Article  CAS  Google Scholar 

  39. P. Concepción, M.T. Navarro, T. Blasco, J.M. López Nieto, B. Panzacchi, F. Rey, Catal. Today 96, 179–186 (2004)

    Google Scholar 

  40. K. Chen, E. Iglesia, A.T. Bell, J. Catal. 192, 197–203 (2000)

    Article  CAS  Google Scholar 

  41. M. Baltes, K. Cassiers, P. Van der Voort, B.M. Weckhuysen, R.A. Schoonheydt, E.F. Vansant, J. Catal. 197, 160–171 (2001)

    Article  CAS  Google Scholar 

  42. J.L. Male, H.G. Niessen, A.T. Bell, T.D. Tilley, J. Catal. 194, 431–444 (2000)

    Article  CAS  Google Scholar 

  43. O.A. Anunziata, A.R. Beltramone, J. Cussa, Catal. Today 133–135, 891–896 (2008)

    Article  CAS  Google Scholar 

  44. J. Fang, X. Bi, D. Si, Z. Jiang, W. Huang, Appl. Surf. Sci. 253, 8952–8961 (2007)

    Article  CAS  Google Scholar 

  45. M.D. Soriano, J.A. Cecilia, A. Natoli, J. Jiménez, J.M. López Nieto, E. Rodríguez-Castellón, Catal. Today 254, 36–42 (2015)

    Article  CAS  Google Scholar 

  46. S. Chen, Z. Qin, X. Xu, J. Wang, Appl. Catal. A-Gen. 302, 185–192 (2006)

    Article  CAS  Google Scholar 

  47. H. Dai, A.T. Bell, E. Iglesia, J. Catal. 221, 491–499 (2004)

    Article  CAS  Google Scholar 

  48. F. Gao, Y. Zhang, H. Wan, Y. Kong, X. Wu, L. Dong, B. Li, Y. Chen, Microporous Mesoporous Mater. 110(2–3), 508–516 (2008)

    Article  CAS  Google Scholar 

  49. E. Tsivion, J.R. Long, M. Head-Gordon, J. Am. Chem. Soc. 136(51), 17827–17835 (2014)

    Article  CAS  PubMed  Google Scholar 

  50. Y. Takasu, R. Unwin, B. Tesche, A.M. Bradshaw, M. Grunze Surf. Sci. 77, 219–232 (1978)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Juliana M. Juárez, Marcos B. Gómez Costa, Oscar A. Anunziata, NANOTEC, CONICET, National Technology University, Cordoba Faculty, Maestro Lopez y Cruz Roja Argentine. We acknowledge the financial support of CONICET Argentina, PIP CONICET 11220120100218CO. 2014–2018 and PICT-Foncyt RES 475/2015; 2017–2021.

Author information

Authors and Affiliations

  1. Centro de Investigación en Nanociencia y Nanotecnología (NANOTEC), Facultad Regional Córdoba, Universidad Tecnológica Nacional, Maestro López y Cruz Roja Argentina, 5016, Córdoba, Argentina

    Juliana M. Juárez, Marcos B. Gómez Costa, María L. Martínez & Oscar A. Anunziata

Authors
  1. Juliana M. Juárez
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Marcos B. Gómez Costa
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. María L. Martínez
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Oscar A. Anunziata
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Oscar A. Anunziata.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Juárez, J.M., Gómez Costa, M.B., Martínez, M.L. et al. Influence of vanadium nanoclusters in hydrogen uptake using hybrid nanostructured materials. J Porous Mater 26, 951–959 (2019). https://doi.org/10.1007/s10934-018-0689-x

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-018-0689-x

Keywords

Search

Navigation