Summary
A new coating technique based on the so-called lower critical solution temperature (LCST) phase transition phenomena known from polymer solutions has been studied. Contrary to the commonly-known features that precipitation from solution occurs upon cooling (or solvent evaporation) or by a precipitant, LCST behaviour means a coagulation and precipitation of the polymer from solution upon heating, once a critical temperature is exceeded. This technology not only allows a controlled surface modification of pigments or flat substrates by an organic polymer coating layer, but also allows one to introduce specific surface features of nanoscopic to mesoscopic dimensions. The surface topology may be reversibly varied from a regular, almost close-packed, mesoscopic hemisphere texture to a nanoscopic roughness or rendered evenly smooth.
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References
Prucker O, T Stöhr, H Murata, R Toomey, M T van Os, R Förch, W Knoll and J Rühe, Proceedings from the 7th Nürnberg Congress, ‘Creative advances in coatings technology’, 403, Vincentz Network, Hannover 2003
Matyjaszewski K, S Coca, Y Nakagwa and S Jo, PCT/WO Patent 98/01480 to Carnegie Mellon University, 15th January 1998
Martin R W, US Patent 4,608,401 to Union Carbide Corporation, 28th August 1986
Tiarks F, K Landfester and M Antonietti, ‘Encapsulation of carbon black by miniemulsion polymerization’,Macromol Chem Phys,202, 51, 2001
Schauer Th, M Entenmann and C D Eisenbach, PCT/WO Patent 01/60926, Forschungsinstitut für Pigmente und Lacke eV, 23rd August 2001
Schauer Th and C D Eisenbach, ‘Organic Polymer Treatment — the Way to Modern pigments’,Europ Coat J,03/03, 114, 2003
Schauer Th, M Entenmann, C D Eisenbach and W Ph Öchsner, PCT/WO Patent 03/014229, Forschungsinstitut für Pigmente und Lacke eV, 20th February 2003
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Eisenbach, C.D., Entenmann, M. & Schauer, T. Novel procedure for polymer coatings of nanoscopic surface topology. Surface Coatings International Part B: Coatings Transactions 88, 213–216 (2005). https://doi.org/10.1007/BF02699575
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DOI: https://doi.org/10.1007/BF02699575