Abstract
The demand for stretchable strain sensors is increasing due to their potential applications in emerging fields such as human motion detection, wearable electronics, and electronic skins. This review paper provides an overview of the latest developments and advanced applications of flexible carbonous conductive polymer composite strain sensors. Various sensing mechanisms for strain sensors, including the tunneling effect, the disconnection mechanism, and the cracking effect, are described and analyzed. Additionally, the differences in fabrication methods and sensing performance of different sensors are compared from the perspective of different morphological structures of conductive polymer composite strain sensors. The applications of flexible carbon-based strain sensors in detecting motion signals, vital signs, and other areas, such as elbow and knee flexion, gesture recognition, voice recognition, pulse, respiration, and human–computer interaction, are also discussed. Finally, the paper summarizes the current challenges that need to be overcome in the practical application of flexible conductive polymer composite strain sensors.
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References
Alamusi, Hu N, Fukunaga H, Atobe S, Liu Y, Li J (2011) Piezoresistive strain sensors made from carbon nanotubes based polymer nanocomposites. Sensors 11(11):10691–10723. https://doi.org/10.3390/S111110691
Alexopoulos ND, Bartholome C, Poulin P, Marioli-Riga Z (2010) Damage detection of glass fiber reinforced composites using embedded PVA–carbon nanotube (CNT) fibers. Compos Sci Technol 70(12):1733–1741. https://doi.org/10.1016/J.COMPSCITECH.2010.07.004
Arman Kuzubasoglu B, Kursun Bahadir S (2020) Flexible temperature sensors: a review. Sens Actuators A 315:112282. https://doi.org/10.1016/j.sna.2020.112282
Bai Y, Qin F, Lu Y (2022) Lightweight Ni/CNT decorated melamine sponge with sensitive strain sensing performance for ultrahigh electromagnetic absorption in both GHz and THz bands. Chem Eng J 429:132393. https://doi.org/10.1016/j.cej.2021.132393
Bershtein VA, Egorova LM, Yakushev PN, Pissis P, Sysel P, Brozova L (2002) Conductive mechanism of polymer/graphite conducting composites with low percolation threshold. J Polym Sci Part B: Polym Phys 40(10):954–963. https://doi.org/10.1002/POLB.10141
Bu Y, Shen T, Yang W, Yang S, Zhao Y, Liu H, Zheng Y, Liu C, Shen C (2021) Ultrasensitive strain sensor based on superhydrophobic microcracked conductive Ti3C2T MXene/paper for human-motion monitoring and E-skin. Sci Bull 66(18):1849–1857. https://doi.org/10.1016/j.scib.2021.04.041
Chen J, Yu Q, Cui X, Dong M, Zhang J, Wang C, Fan J, Zhu Y, Guo Z (2019) An overview of stretchable strain sensors from conductive polymer nanocomposites. J Mater Chem C 7(38):11710–11730. https://doi.org/10.1039/c9tc03655e
Chen J, Zhu Y, Guo Z, Nasibulin AG (2020a) Recent progress on thermo-electrical properties of conductive polymer composites and their application in temperature sensors. Eng Sci. https://doi.org/10.30919/es8d1129
Chen J, Zhu Y, Jiang W (2020b) A stretchable and transparent strain sensor based on sandwich-like PDMS/CNTs/PDMS composite containing an ultrathin conductive CNT layer. Compos Sci Technol 186:107938. https://doi.org/10.1016/j.compscitech.2019.107938
Chen J, Zhu Y, Jiang W (2020c) A stretchable and transparent strain sensor based on sandwich-like PDMS/CNTs/PDMS composite containing an ultrathin conductive CNT layer. Compos Sci Technol 186:107938. https://doi.org/10.1016/j.compscitech.2019.107938
Chen L, Chen G, Lu L (2007) Piezoresistive behavior study on finger-sensing silicone rubber/graphite nanosheet nanocomposites. Adv Func Mater 17(6):898–904. https://doi.org/10.1002/ADFM.200600519
Chen Q, Yao Y, Huang X, Liu D, Mao K (2021a) Simulation analysis and experimental verification for sensitivity of IDE-QCM humidity sensors. Sens Actuators B Chem 341:129992. https://doi.org/10.1016/j.snb.2021.129992
Chen Z, Zhao D, Ma R, Zhang X, Rao J, Yin Y, Wang X, Yi F (2021b) Flexible temperature sensors based on carbon nanomaterials. J Mater Chem B 9(8):1941–1964. https://doi.org/10.1039/D0TB02451A
Cui Z, Poblete FR, Zhu Y (2019) Tailoring the temperature coefficient of resistance of silver nanowire nanocomposites and their application as stretchable temperature sensors. ACS Appl Mater Interfaces 11(19):17836–17842. https://doi.org/10.1021/acsami.9b04045
Delipinar T, Shafique A, Gohar MS, Yapici MK (2021) Fabrication and materials integration of flexible humidity sensors for emerging applications. ACS Omega 6(13):8744–8753. https://doi.org/10.1021/acsomega.0c06106
Desai AV, Haque MA (2005) Mechanics of the interface for carbon nanotube–polymer composites. Thin-Walled Struct 43(11):1787–1803. https://doi.org/10.1016/J.TWS.2005.07.003
Du D, Li P, Ouyang J (2016) Graphene coated nonwoven fabrics as wearable sensors. J Mater Chem C 4(15):3224–3230. https://doi.org/10.1039/C6TC00350H
Feng J, Tian Y, Wang S, Xiao M, Hui Z, Hang C, Duley WW, Zhou YN (2021) Femtosecond laser irradiation induced heterojunctions between carbon nanofibers and silver nanowires for a flexible strain sensor. J Mater Sci Technol 84:139–146. https://doi.org/10.1016/j.jmst.2020.12.060
Feng J, Wang X, Lv Z, Qu J, Lu X, Wei Q, Wang Q (2020) Multifunctional wearable strain sensor made with an elastic interwoven fabric for patients with motor dysfunction. Adv Mater Technol 5(11):2000560. https://doi.org/10.1002/ADMT.202000560
Foroughi J, Spinks GM, Aziz S, Mirabedini A, Jeiranikhameneh A, Wallace GG, Kozlov ME, Baughman RH (2016) Knitted carbon-nanotube-sheath/spandex-core elastomeric yarns for artificial muscles and strain sensing. ACS Nano 10(10):9129–9135. https://doi.org/10.1021/ACSNANO.6B04125/SUPPL_FILE/NN6B04125_SI_005.PDF
Fu L, Yu AM (2014) Carbon nanotubes based thin films: fabrication, characterization and applications. Rev Adv Mater Sci 36(1):40–61
Gao Y, Guo F, Cao P, Liu J, Li D, Wu J, Wang N, Su Y, Zhao Y (2020) Winding-locked carbon nanotubes/polymer nanofibers helical yarn for ultrastretchable conductor and strain sensor. ACS Nano 14(3):3442–3450. https://doi.org/10.1021/ACSNANO.9B09533/SUPPL_FILE/NN9B09533_SI_001.PDF
González-Rivera J, Iglio R, Barillaro G, Duce C, Tinè MR (2018) Structural and thermoanalytical characterization of 3D porous PDMS foam materials: the effect of impurities derived from a sugar templating process. Polymers 10(6):616. https://doi.org/10.3390/POLYM10060616
Hu M, Gao Y, Jiang Y, Zeng H, Zeng S, Zhu M, Xu G, Sun L (2021a) High-performance strain sensors based on bilayer carbon black/PDMS hybrids. Adv Compos Hybrid Mater 4(3):514–520. https://doi.org/10.1007/s42114-021-00226-z
Hu N, Karube Y, Yan C, Masuda Z, Fukunaga H (2008) Tunneling effect in a polymer/carbon nanotube nanocomposite strain sensor. Acta Mater 56(13):2929–2936. https://doi.org/10.1016/j.actamat.2008.02.030
Hu X, Yang F, Wu M, Sui Y, Guo D, Li M, Kang Z, Sun J, Liu J (2021b) A super‐stretchable and highly sensitive carbon nanotube capacitive strain sensor for wearable applications and soft robotics. Adv Mater Technol 2100769. https://doi.org/10.1002/admt.202100769
Huang L, Chen J, Xu Y, Hu D, Cui X, Shi D, Zhu Y (2021) Three-dimensional light-weight piezoresistive sensors based on conductive polyurethane sponges coated with hybrid CNT/CB nanoparticles. Appl Surf Sci 548:149268. https://doi.org/10.1016/j.apsusc.2021.149268
Hwang J, Kim Y, Yang H, Oh JH (2021) Fabrication of hierarchically porous structured PDMS composites and their application as a flexible capacitive pressure sensor. Compos B Eng 211:108607. https://doi.org/10.1016/J.COMPOSITESB.2021.108607
Iglio R, Mariani S, Robbiano V, Strambini L, Barillaro G (2018) Flexible polydimethylsiloxane foams decorated with multiwalled carbon nanotubes enable unprecedented detection of ultralow strain and pressure coupled with a large working range. ACS Appl Mater Interfaces 10(16):13877–13885. https://doi.org/10.1021/acsami.8b02322
Jang J, Kim S, Lee K, Park S, Park G-Y, Kim B-J, Oh J, Lee MJ (2021) Knitted strain sensor with carbon fiber and aluminum-coated yarn, for wearable electronics. J Mater Chem C 9(46):16440–16449. https://doi.org/10.1039/D1TC01899J
Ji M, Deng H, Yan D, Li X, Duan L, Fu Q (2014) Selective localization of multi-walled carbon nanotubes in thermoplastic elastomer blends: an effective method for tunable resistivity–strain sensing behavior. Compos Sci Technol 92:16–26. https://doi.org/10.1016/J.COMPSCITECH.2013.11.018
Jung Y, Jung K, Park B, Choi J, Kim D, Park J, Ko J, Cho H (2019) Wearable piezoresistive strain sensor based on graphene-coated three-dimensional micro-porous PDMS sponge. Micro Nano Syst Lett 7(1):1–9. https://doi.org/10.1186/S40486-019-0097-2/FIGURES/6
Kim JH, Cho KG, Cho DH, Hong K, Lee KH (2021) Ultra-sensitive and stretchable ionic skins for high-precision motion monitoring. Adv Func Mater 31(16):2010199. https://doi.org/10.1002/adfm.202010199
Kirubasankar B, Murugadoss V, Lin J, Ding T, Dong M, Liu H, Zhang J, Li T, Wang N, Guo Z, Angaiah S (2018) In situ grown nickel selenide on graphene nanohybrid electrodes for high energy density asymmetric supercapacitors. Nanoscale 10(43):20414–20425. https://doi.org/10.1039/C8NR06345A
Lam TN, Lee GS, Kim B, Dinh Xuan H, Kim D, Yoo SI, Yoon J (2021) Microfluidic preparation of highly stretchable natural rubber microfiber containing CNT/PEDOT:PSS hybrid for fabric-sewable wearable strain sensor. Compos Sci Technol 210:108811. https://doi.org/10.1016/j.compscitech.2021.108811
Lantada AD, Lafont P, Sanz JLM, Munoz-Guijosa JM, Otero JE (2010) Quantum tunnelling composites: characterisation and modelling to promote their applications as sensors. Sens Actuators a: Phys 164(1–2):46–57. https://doi.org/10.1016/j.sna.2010.09.002
Lee S, Shi Q, Lee C (2019) From flexible electronics technology in the era of IoT and artificial intelligence toward future implanted body sensor networks. APL Mater 7(3):031302. https://doi.org/10.1063/1.5063498
Li G, Dai K, Ren M, Wang Y, Zheng G, Liu C, Shen C (2018a) Aligned flexible conductive fibrous networks for highly sensitive, ultrastretchable and wearable strain sensors. J Mater Chem C 6(24):6575–6583. https://doi.org/10.1039/C8TC01924J
Li H, Chen J, Chang X, Xu Y, Zhao G, Zhu Y, Li Y (2021a) A highly stretchable strain sensor with both an ultralow detection limit and an ultrawide sensing range. J Mater Chem A 9(3):1795–1802. https://doi.org/10.1039/D0TA10990H
Li J, Bo X (2022) Laser-enabled flexible electrochemical sensor on finger for fast food security detection. J Hazard Mater 423:127014. https://doi.org/10.1016/j.jhazmat.2021.127014
Li J, Zhao S, Zeng X, Huang W, Gong Z, Zhang G, Sun R, Wong CP (2016a) Highly stretchable and sensitive strain sensor based on facilely prepared three-dimensional graphene foam composite. ACS Appl Mater Interfaces 8(29):18954–18961. https://doi.org/10.1021/ACSAMI.6B05088/SUPPL_FILE/AM6B05088_SI_001.PDF
Li M, Chen X, Li X, Dong J, Zhao X, Zhang Q (2021b) Wearable and robust polyimide hydrogel fiber textiles for strain sensors. ACS Appl Mater Interfaces 13(36):43323–43332. https://doi.org/10.1021/acsami.1c10055
Li Q, Liu H, Zhang S, Zhang D, Liu X, He Y, Mi L, Zhang J, Liu C, Shen C, Guo Z (2019) Superhydrophobic electrically conductive paper for ultrasensitive strain sensor with excellent anticorrosion and self-cleaning property. ACS Appl Mater Interfaces 11(24):21904–21914. https://doi.org/10.1021/acsami.9b03421
Li Q, Yin R, Zhang D, Liu H, Chen X, Zheng Y, Guo Z, Liu C, Shen C (2020a) Flexible conductive MXene/cellulose nanocrystal coated nonwoven fabrics for tunable wearable strain/pressure sensors. J Mater Chem A 8(40):21131–21141. https://doi.org/10.1039/D0TA07832H
Li W, Zhou Y, Wang Y, Jiang L, Ma J, Chen S, Zhou F (2021c) Core-sheath fiber-based wearable strain sensor with high stretchability and sensitivity for detecting human motion. Adv Electron Mater 7(1):2000865. https://doi.org/10.1002/aelm.202000865
Li X, Yang T, Yang Y, Zhu J, Li L, Alam FE, Li X, Wang K, Cheng H, Lin C-T, Fang Y, Zhu H (2016b) Large-area ultrathin graphene films by single-step marangoni self-assembly for highly sensitive strain sensing application. Adv Funct Mater 26(9):1322–1329.https://doi.org/10.1002/ADFM.201504717
Li Y, Zheng C, Liu S, Huang L, Fang T, Li JX, Xu F, Li F (2020b) Smart glove integrated with tunable MWNTs/PDMS fibers made of a one-step extrusion method for finger dexterity, gesture, and temperature recognition. ACS Appl Mater Interfaces 12(21):23764–23773. https://doi.org/10.1021/ACSAMI.0C08114/SUPPL_FILE/AM0C08114_SI_005.MP4
Li Y, Zhou B, Zheng G, Liu X, Li T, Yan C, Cheng C, Dai K, Liu C, Shen C, Guo Z (2018b) Continuously prepared highly conductive and stretchable SWNT/MWNT synergistically composited electrospun thermoplastic polyurethane yarns for wearable sensing. J Mater Chem C 6(9):2258–2269. https://doi.org/10.1039/C7TC04959E
Li Z, Qi X, Xu L, Lu H, Wang W, Jin X, Md ZI, Zhu Y, Fu Y, Ni Q, Dong Y (2020c) Self-repairing, large linear working range shape memory carbon nanotubes/ethylene vinyl acetate fiber strain sensor for human movement monitoring. ACS Appl Mater Interfaces 12(37):42179–42192. https://doi.org/10.1021/ACSAMI.0C12425/SUPPL_FILE/AM0C12425_SI_002.AVI
Lin L, Liu S, Zhang Q, Li X, Ji M, Deng H, Fu Q (2013) Towards tunable sensitivity of electrical property to strain for conductive polymer composites based on thermoplastic elastomer. ACS Appl Mater Interfaces 5(12):5815–5824. https://doi.org/10.1021/AM401402X/SUPPL_FILE/AM401402X_SI_002.PDF
Liu H, Gao H, Hu G (2019) Highly sensitive natural rubber/pristine graphene strain sensor prepared by a simple method. Compos B Eng 171:138–145. https://doi.org/10.1016/j.compositesb.2019.04.032
Liu H, Li Q, Zhang S, Yin R, Liu X, He Y, Dai K, Shan C, Guo J, Liu C, Shen C, Wang X, Wang N, Wang Z, Wei R, Guo Z (2018) Electrically conductive polymer composites for smart flexible strain sensors: a critical review. J Mater Chem C 6(45):12121–12141. https://doi.org/10.1039/C8TC04079F
Liu H, Zhang S, Li Z, Lu TJ, Lin H, Zhu Y, Ahadian S, Emaminejad S, Dokmeci MR, Xu F, Khademhosseini A (2021a) Harnessing the wide-range strain sensitivity of bilayered PEDOT:PSS films for wearable health monitoring. Matter 4(9):2886–2901. https://doi.org/10.1016/j.matt.2021.06.034
Liu Y, Zhang D (2016) The preparation of reduced graphene oxide-TiO2 composite materials towards transparent, strain sensing and photodegradation multifunctional films. Compos Sci Technol 137:102–108. https://doi.org/10.1016/J.COMPSCITECH.2016.10.025
Liu Z, Li Z, Zhai H, Jin L, Chen K, Yi Y, Gao Y, Xu L, Zheng Y, Yao S, Liu Z, Li G, Song Q, Yue P, Xie S, Li Y, Zheng Z (2021b) A highly sensitive stretchable strain sensor based on multi-functionalized fabric for respiration monitoring and identification. Chem Eng J 426:130869. https://doi.org/10.1016/j.cej.2021.130869
Long Y, Zhao X, Jiang X, Zhang L, Zhang H, Liu Y, Zhu H (2018) A porous graphene/polydimethylsiloxane composite by chemical foaming for simultaneous tensile and compressive strain sensing. FlatChem 10:1–7. https://doi.org/10.1016/J.FLATC.2018.07.001
Lou X, Lin C, Luo Q, Zhao J, Wang B, Li J, Shao Q, Guo X, Wang N, Guo Z (2017) Crystal structure modification enhanced FeNb 11 O 29 anodes for lithium-ion batteries. ChemElectroChem 4(12):3171–3180. https://doi.org/10.1002/celc.201700816
Lu L, Zhou Y, Pan J, Chen T, Hu Y, Zheng G, Dai K, Liu C, Shen C, Sun X, Peng H (2019) Design of helically double-leveled gaps for stretchable fiber strain sensor with ultralow detection limit, broad sensing range, and high repeatability. ACS Appl Mater Interfaces 11(4):4345–4352. https://doi.org/10.1021/ACSAMI.8B17666/SUPPL_FILE/AM8B17666_SI_001.PDF
Luo Q, Ma H, Hou Q, Li Y, Ren J, Dai X, Yao Z, Zhou Y, Xiang L, Du H, He H, Wang N, Jiang K, Lin H, Zhang H, Guo Z (2018) All-carbon-electrode-based endurable flexible perovskite solar cells. Adv Func Mater 28(11):1706777. https://doi.org/10.1002/ADFM.201706777
Luo R, Li X, Li H, Du B, Zhou S (2022) A stretchable and printable PEDOT:PSS/PDMS composite conductors and its application to wearable strain sensor. Prog Org Coat 162:106593. https://doi.org/10.1016/j.porgcoat.2021.106593
Lv Z, Huang X, Fan D, Zhou P, Luo Y, Zhang X (2021) Scalable manufacturing of conductive rubber nanocomposites with ultralow percolation threshold for strain sensing applications. Compos Commun 25:100685. https://doi.org/10.1016/j.coco.2021.100685
Ma L, Lu W (2020) Carbon nanotube film based flexible bi-directional strain sensor for large deformation. Mater Lett 260:126959. https://doi.org/10.1016/J.MATLET.2019.126959
Ma Y, Yu M, Liu J, Li X, Li S (2017) Ultralight interconnected graphene-amorphous carbon hierarchical foam with mechanical resiliency for high sensitivity and durable strain sensors. ACS Appl Mater Interfaces 9(32):27127–27134. https://doi.org/10.1021/ACSAMI.7B05636/SUPPL_FILE/AM7B05636_SI_001.PDF
Majerus SJA, Chong H, Ariando D, Swingle C, Potkay J, Bogie K, Zorman CA (2018) Vascular graft pressure-flow monitoring using 3D printed MWCNT-PDMS strain sensors. In: Proceedings of the annual international conference of the IEEE engineering in medicine and biology society, EMBS, July 2018, pp 2989–2992. https://doi.org/10.1109/EMBC.2018.8512997
Mei S, Zhang X, Ding B, Wang J, Yang P, She H, Cui Z, Liu M, Pang X, Fu P (2021) <scp>3D-Printed</scp> thermoplastic polyurethane/graphene composite with porous segregated structure: toward ultralow percolation threshold and great strain sensitivity. J Appl Polym Sci 138(14):50168. https://doi.org/10.1002/app.50168
Meng Q, Liu Z, Han S, Xu L, Araby S, Cai R, Zhao Y, Lu S, Liu T (2019) A facile approach to fabricate highly sensitive, flexible strain sensor based on elastomeric/graphene platelet composite film. J Mater Sci 54(15):10856–10870. https://doi.org/10.1007/S10853-019-03650-1/TABLES/2
Niu S, Chang X, Zhu Z, Qin Z, Li J, Jiang Y, Wang D, Yang C, Gao Y, Sun S (2021) Low-temperature wearable strain sensor based on a silver nanowires/graphene composite with a near-zero temperature coefficient of resistance. ACS Appl Mater Interfaces 13(46):55307–55318. https://doi.org/10.1021/acsami.1c14671
Pang Y, Tian H, Tao L, Li Y, Wang X, Deng N, Yang Y, Ren TL (2016) Flexible, highly sensitive, and wearable pressure and strain sensors with graphene porous network structure. ACS Appl Mater Interfaces 8(40):26458–26462. https://doi.org/10.1021/ACSAMI.6B08172/SUPPL_FILE/AM6B08172_SI_001.PDF
Park H, Song C, Jin SW, Lee H, Keum K, Lee YH, Lee G, Jeong YR, Ha JS (2021) High performance flexible micro-supercapacitor for powering a vertically integrated skin-attachable strain sensor on a bio-inspired adhesive. Nano Energy 83:105837. https://doi.org/10.1016/j.nanoen.2021.105837
Park JJ, Hyun WJ, Mun SC, Park YT, Park OO (2015) Highly stretchable and wearable graphene strain sensors with controllable sensitivity for human motion monitoring. ACS Appl Mater Interfaces 7(11):6317–6324. https://doi.org/10.1021/ACSAMI.5B00695/SUPPL_FILE/AM5B00695_SI_003.AVI
Peng S, Wu S, Yu Y, Sha Z, Li G, Hoang TT, Thai MT, Do TN, Chu D, Wang CH (2021) Carbon nanofiber-reinforced strain sensors with high breathability and anisotropic sensitivity. J Mater Chem A 9(47):26788–26799. https://doi.org/10.1039/D1TA08521B
Pu L, Liu Y, Li L, Zhang C, Ma P, Dong W, Huang Y, Liu T (2021) Polyimide nanofiber-reinforced Ti 3 C 2 T x aerogel with “lamella-pillar” microporosity for high-performance piezoresistive strain sensing and electromagnetic wave absorption. ACS Appl Mater Interfaces 13(39):47134–47146. https://doi.org/10.1021/acsami.1c13863
Qaiser N, Al-Modaf F, Khan SM, Shaikh SF, El-Atab N, Hussain MM (2021) A robust wearable point-of-care CNT-based strain sensor for wirelessly monitoring throat-related illnesses. Adv Func Mater 31(29):2103375. https://doi.org/10.1002/adfm.202103375
Rahimi R, Ochoa M, Yu W, Ziaie B (2015) Highly stretchable and sensitive unidirectional strain sensor via laser carbonization. ACS Appl Mater Interfaces 7(8):4463–4470. https://doi.org/10.1021/am509087u
Ren J, Wang C, Zhang X, Carey T, Chen K, Yin Y, Torrisi F (2017) Environmentally-friendly conductive cotton fabric as flexible strain sensor based on hot press reduced graphene oxide. Carbon 111:622–630. https://doi.org/10.1016/J.CARBON.2016.10.045
Sheng N, Ji P, Zhang M, Wu Z, Liang Q, Chen S, Wang H (2021) High sensitivity polyurethane-based fiber strain sensor with porous structure via incorporation of bacterial cellulose nanofibers. Adv Electron Mater 7(4):2001235. https://doi.org/10.1002/aelm.202001235
Soe HM, Abd Manaf A, Matsuda A, Jaafar M (2021) Performance of a silver nanoparticles-based polydimethylsiloxane composite strain sensor produced using different fabrication methods. Sens Actuators a: Phys 329:112793. https://doi.org/10.1016/j.sna.2021.112793
Sun B, McCay RN, Goswami S, Xu Y, Zhang C, Ling Y, Lin J, Yan Z (2018) Gas-permeable, multifunctional on-skin electronics based on laser-induced porous graphene and sugar-templated elastomer sponges. Adv Mater 30(50):1804327. https://doi.org/10.1002/ADMA.201804327
Sun H, Dai K, Zhai W, Zhou Y, Li J, Zheng G, Li B, Liu C, Shen C (2019) A highly sensitive and stretchable yarn strain sensor for human motion tracking utilizing a wrinkle-assisted crack structure. ACS Appl Mater Interfaces 11(39):36052–36062. https://doi.org/10.1021/ACSAMI.9B09229/SUPPL_FILE/AM9B09229_SI_005.AVI
Sun J, Yuan Y, Lu G, Xue T, Nie J, Lu Y (2022) Highly stretchable and sensitive strain sensor based on Ionogel/Ag synergistic conductive network. Adv Mater Interfaces 2102245.https://doi.org/10.1002/admi.202102245
Suzuki K, Yataka K, Okumiya Y, Sakakibara S, Sako K, Mimura H, Inoue Y (2016) Rapid-response, widely stretchable sensor of aligned MWCNT/elastomer composites for human motion detection. ACS Sens 1(6):817–825. https://doi.org/10.1021/ACSSENSORS.6B00145/SUPPL_FILE/SE6B00145_SI_005.MPG
Tang J, Wu Y, Ma S, Yan T, Pan Z (2022) Flexible strain sensor based on CNT/TPU composite nanofiber yarn for smart sports bandage. Compos B Eng 232:109605. https://doi.org/10.1016/j.compositesb.2021.109605
Tang Z, Jia S, Wang F, Bian C, Chen Y, Wang Y, Li B (2018) Highly stretchable core-sheath fibers via wet-spinning for wearable strain sensors. ACS Appl Mater Interfaces 10(7):6624–6635. https://doi.org/10.1021/acsami.7b18677
Thakur N, Mandal D, Nagaiah TC (2022) A novel NiVP/Pi-based flexible sensor for direct electrochemical ultrasensitive detection of cholesterol. Chem Commun. https://doi.org/10.1039/D1CC07115G
Veeralingam S, Praveen S, Vemula M, Badhulika S (2022) One-step synthesis of carbon-doped PPy nanoparticles interspersed in 3D porous melamine foam as a high-performance piezoresistive pressure, strain, and breath sensor. Mater Chem Front. https://doi.org/10.1039/D1QM01427G
Wan Y, Qin N, Wang Y, Zhao Q, Wang Q, Yuan P, Wen Q, Wei H, Zhang X, Ma N (2020) Sugar-templated conductive polyurethane-polypyrrole sponges for wide-range force sensing. Chem Eng J 383:123103. https://doi.org/10.1016/J.CEJ.2019.123103
Wang C, Li X, Gao E, Jian M, Xia K, Wang Q, Xu Z, Ren T, Zhang Y, Wang CY, Jian MQ, Xia KL, Wang Q, Zhang YY, Li X, Ren TL, Gao EL, Xu ZP (2016a) Carbonized silk fabric for ultrastretchable, highly sensitive, and wearable strain sensors. Adv Mater 28(31):6640–6648. https://doi.org/10.1002/ADMA.201601572
Wang F, Liu S, Shu L, Tao X-M (2017) Low-dimensional carbon based sensors and sensing network for wearable health and environmental monitoring. Carbon 121:353–367. https://doi.org/10.1016/j.carbon.2017.06.006
Wang H, Li J, Yu X, Yan G, Tang X, Sun Y, Zeng X, Lin L (2021a) Cellulose nanocrystalline hydrogel based on a choline chloride deep eutectic solvent as wearable strain sensor for human motion. Carbohyd Polym 255:117443. https://doi.org/10.1016/j.carbpol.2020.117443
Wang H, Zhou R, Li D, Zhang L, Ren G, Wang L, Liu J, Wang D, Tang Z, Lu G, Sun G, Yu H-D, Huang W (2021b) High-performance foam-shaped strain sensor based on carbon nanotubes and Ti 3 C 2 T x MXene for the monitoring of human activities. ACS Nano 15(6):9690–9700. https://doi.org/10.1021/acsnano.1c00259
Wang L, Xu T, Fan C, Zhang X (2021c) Wearable strain sensor for real-time sweat volume monitoring. Iscience 24(1):102028. https://doi.org/10.1016/j.isci.2020.102028
Wang M, Wang T, Luo Y, He K, Pan L, Li Z, Cui Z, Liu Z, Tu J, Chen X, Wang M, Wang T, Luo Y, He K, Pan L, Li Z, Cui Z, Liu Z, Tu J, Chen X (2021d) Fusing stretchable sensing technology with machine learning for human-machine interfaces. Adv Func Mater 31(39):2008807. https://doi.org/10.1002/ADFM.202008807
Wang S, Ning H, Hu N, Liu Y, Liu F, Zou R, Huang K, Wu X, Weng S, Alamusi (2020) Environmentally-friendly and multifunctional graphene-silk fabric strain sensor for human-motion detection. Adv Mater Interfaces 7(1):1901507. https://doi.org/10.1002/ADMI.201901507
Wang S, Xiao P, Liang Y, Zhang J, Huang Y, Wu S, Kuo SW, Chen T (2018a) Network cracks-based wearable strain sensors for subtle and large strain detection of human motions. J Mater Chem C 6(19):5140–5147. https://doi.org/10.1039/C8TC00433A
Wang X, Li Q, Tao X (2021e) Sensing mechanism of a carbon nanocomposite-printed fabric as a strain sensor. Compos A Appl Sci Manuf 144:106350. https://doi.org/10.1016/j.compositesa.2021.106350
Wang X, Sun H, Yue X, Yu Y, Zheng G, Dai K, Liu C, Shen C (2018b) A highly stretchable carbon nanotubes/thermoplastic polyurethane fiber-shaped strain sensor with porous structure for human motion monitoring. Compos Sci Technol 168:126–132. https://doi.org/10.1016/J.COMPSCITECH.2018.09.006
Wang Y, Gao G, Ren X (2021f) Graphene assisted ion-conductive hydrogel with super sensitivity for strain sensor. Polymer 215:123340. https://doi.org/10.1016/j.polymer.2020.123340
Wang Y, Li W, Li C, Zhou B, Zhou Y, Jiang L, Wen S, Zhou F (2021g) Fabrication of ultra-high working range strain sensor using carboxyl CNTs coated electrospun TPU assisted with dopamine. Appl Surf Sci 566:150705. https://doi.org/10.1016/j.apsusc.2021.150705
Wang Y, Wang F, Yazigi S, Zhang D, Gui X, Qi Y, Zhong J, Sun L (2021h) Nanoengineered highly sensitive and stable soft strain sensor built from cracked carbon nanotube network/composite bilayers. Carbon 173:849–856. https://doi.org/10.1016/j.carbon.2020.11.025
Wang Y, Wang L, Yang T, Li X, Zang X, Zhu M, Wang K, Wu D, Zhu H (2014) Wearable and highly sensitive graphene strain sensors for human motion monitoring. Adv Func Mater 24(29):4666–4670. https://doi.org/10.1002/ADFM.201400379
Wang Z, Huang Y, Sun J, Huang Y, Hu H, Jiang R, Gai W, Li G, Zhi C (2016b) Polyurethane/cotton/carbon nanotubes core-spun yarn as high reliability stretchable strain sensor for human motion detection. ACS Appl Mater Interfaces 8(37):24837–24843. https://doi.org/10.1021/ACSAMI.6B08207/SUPPL_FILE/AM6B08207_SI_001.PDF
Wu H, Chen H, Yao P, Wang R (2021) Stretchable and highly sensitive strain sensor based on conductive polymer aerogel for human physiological information detection. Nano Select 2(4):802–809. https://doi.org/10.1002/nano.202000215
Wu J, Wu Z, Wei Y, Ding H, Huang W, Gui X, Shi W, Shen Y, Tao K, Xie X (2020) Ultrasensitive and stretchable temperature sensors based on thermally stable and self-healing organohydrogels. ACS Appl Mater Interfaces 12(16):19069–19079. https://doi.org/10.1021/acsami.0c04359
Xia Q, Wang S, Zhai W, Shao C, Xu L, Yan D, Yang N, Dai K, Liu C, Shen C (2021) Highly linear and low hysteresis porous strain sensor for wearable electronic skins. Compos Commun 26:100809. https://doi.org/10.1016/j.coco.2021.100809
Xiao T, Qian C, Yin R, Wang K, Gao Y, Xuan F (2021) 3D printing of flexible strain sensor array based on UV-curable multiwalled carbon nanotube/elastomer composite. Adv Mater Technol 6(1):2000745. https://doi.org/10.1002/admt.202000745
Xu B, Ye F, Chen R, Luo X, Chang G, Li R (2021) A wide sensing range and high sensitivity flexible strain sensor based on carbon nanotubes and MXene. Ceram Int. https://doi.org/10.1016/j.ceramint.2021.12.235
Xu R, Lu Y, Jiang C, Chen J, Mao P, Gao G, Zhang L, Wu S (2014) Facile fabrication of three-dimensional graphene foam/poly(dimethylsiloxane) composites and their potential application as strain sensor. ACS Appl Mater Interfaces 6(16):13455–13460. https://doi.org/10.1021/AM502208G
Xue P, Chen C, Diao D (2019) Ultra-sensitive flexible strain sensor based on graphene nanocrystallite carbon film with wrinkle structures. Carbon 147:227–235. https://doi.org/10.1016/J.CARBON.2019.03.001
Yan T, Wang Z, Pan ZJ (2018) Flexible strain sensors fabricated using carbon-based nanomaterials: a review. Curr Opin Solid State Mater Sci 22(6):213–228. https://doi.org/10.1016/j.cossms.2018.11.001
Yang Y, Yang YF, Tao LQ, Pang Y, Tian H, Ju ZY, Wu XM, Ren TL (2018) An ultrasensitive strain sensor with a wide strain range based on graphene armour scales. Nanoscale 10(24):11524–11530. https://doi.org/10.1039/C8NR02652A
Yang Z, Wu Z, Jiang D, Wei R, Mai X, Pan D, Vupputuri S, Weng L, Naik N, Guo Z (2021) Ultra-sensitive flexible sandwich structural strain sensors based on a silver nanowire supported PDMS/PVDF electrospun membrane substrate. J Mater Chem C 9(8):2752–2762. https://doi.org/10.1039/D0TC04659K
Yin B, Wen Y, Hong T, Xie Z, Yuan G, Ji Q, Jia H (2017) Highly stretchable, ultrasensitive, and wearable strain sensors based on facilely prepared reduced graphene oxide woven fabrics in an ethanol flame. ACS Appl Mater Interfaces 9(37):32054–32064. https://doi.org/10.1021/ACSAMI.7B09652/SUPPL_FILE/AM7B09652_SI_004.AVI
Yin F, Li X, Peng H, Li F, Yang K, Yuan W (2019) A highly sensitive, multifunctional, and wearable mechanical sensor based on RGO/synergetic fiber bundles for monitoring human actions and physiological signals. Sens Actuators B Chem 285:179–185. https://doi.org/10.1016/J.SNB.2019.01.063
Yu Y, Luo Y, Guo A, Yan L, Wu Y, Jiang K, Li Q, Fan S, Wang J (2017) Flexible and transparent strain sensors based on super-aligned carbon nanotube films. Nanoscale 9(20):6716–6723. https://doi.org/10.1039/C6NR09961K
Yu Y, Peng S, Blanloeuil P, Wu S, Wang CH (2020) Wearable temperature sensors with enhanced sensitivity by engineering microcrack morphology in PEDOT:PSS–PDMS sensors. ACS Appl Mater Interfaces 12(32):36578–36588. https://doi.org/10.1021/acsami.0c07649
Yuan W, Zhou Q, Li Y, Shi G (2015) Small and light strain sensors based on graphene coated human hairs. Nanoscale 7(39):16361–16365. https://doi.org/10.1039/C5NR04312C
Yue X, Jia Y, Wang X, Zhou K, Zhai W, Zheng G, Dai K, Mi L, Liu C, Shen C (2020) Highly stretchable and durable fiber-shaped strain sensor with porous core-sheath structure for human motion monitoring. Compos Sci Technol 189:108038. https://doi.org/10.1016/J.COMPSCITECH.2020.108038
Zeng J, Ma W, Wang Q, Yu S, Innocent MT, Xiang H, Zhu M (2021a) Strong, high stretchable and ultrasensitive SEBS/CNTs hybrid fiber for high-performance strain sensor. Compos Commun 25:100735. https://doi.org/10.1016/j.coco.2021.100735
Zhang D, Jiang C, Tong J, Zong X, Hu W (2018) Flexible strain sensor based on layer-by-layer self-assembled graphene/polymer nanocomposite membrane and its sensing properties. J Electron Mater 47(4):2263–2270. https://doi.org/10.1007/S11664-017-6052-1
Zhang D, Xu S, Zhao X, Qian W, Bowen CR, Yang Y, Zhang D, Xu S, Zhao X, Qian W, Yang Y, Bowen CR (2020a) Wireless monitoring of small strains in intelligent robots via a joule heating effect in stretchable graphene-polymer nanocomposites. Adv Func Mater 30(13):1910809. https://doi.org/10.1002/ADFM.201910809
Zhang K, Zhang J, Liu Y, Wang Z, Yan C, Song C, Gao C, Wu Y (2021a) A NIR laser induced self-healing PDMS/gold nanoparticles conductive elastomer for wearable sensor. J Colloid Interface Sci 599:360–369. https://doi.org/10.1016/j.jcis.2021.04.117
Zhang M, Wang C, Wang Q, Jian M, Zhang Y (2016) Sheath-core graphite/silk fiber made by dry-meyer-rod-coating for wearable strain sensors. ACS Appl Mater Interfaces 8(32):20894–20899. https://doi.org/10.1021/ACSAMI.6B06984/SUPPL_FILE/AM6B06984_SI_001.PDF
Zhang P, Chen Y, Li Y, Zhang Y, Zhang J, Huang L (2020b) A flexible strain sensor based on the porous structure of a carbon black/carbon nanotube conducting network for human motion detection. Sensors 20(4):1154. https://doi.org/10.3390/S20041154
Zhang X-W, Pan YI, Zheng Q, Yi X-S (2000) Time dependence of piezoresistance for the conductor-filled polymer composites. J Polym Sci B: Polym Phys 38:2739–2749. https://doi.org/10.1002/1099-0488
Zhang X, Zhang Y, Zhang W, Dai Y, Xia F (2021b) Gold nanoparticles-deranged double network for Janus adhesive-tough hydrogel as strain sensor. Chem Eng J 420:130447. https://doi.org/10.1016/j.cej.2021.130447
Zhao G, Wang X, Liu G, Thuy NTD (2022) A disposable and flexible electrochemical sensor for the sensitive detection of heavy metals based on a one-step laser-induced surface modification: a new strategy for the batch fabrication of sensors. Sens Actuators B: Chem 350:130834. https://doi.org/10.1016/j.snb.2021.130834
Zhao W, Xu S (2022) A facile structural strategy for a wearable strain sensor based on carbon nanotube modified helical yarns. Nanoscale Adv 4(1):250–257. https://doi.org/10.1039/D1NA00215E
Zhao Y, Deng S, Liu H, Zhang J, Guo Z, Hou H (2018) First-principle investigation of pressure and temperature influence on structural, mechanical and thermodynamic properties of Ti3AC2 (A = Al and Si). Comput Mater Sci 154:365–370. https://doi.org/10.1016/j.commatsci.2018.07.007
Zhao Y, Huang Y, Hu W, Guo X, Wang Y, Liu P, Liu C, Zhang Y (2019) Highly sensitive flexible strain sensor based on threadlike spandex substrate coating with conductive nanocomposites for wearable electronic skin. Smart Mater Struct 28(3):035004. https://doi.org/10.1088/1361-665X/AAF3CE
Zheng H, Lin N, He Y, Zuo B (2021) Self-healing, self-adhesive silk fibroin conductive hydrogel as a flexible strain sensor. ACS Appl Mater Interfaces 13(33):40013–40031. https://doi.org/10.1021/acsami.1c08395
Zheng Y, Li Y, Zhou Y, Dai K, Zheng G, Zhang B, Liu C, Shen C (2020) High-performance wearable strain sensor based on graphene/cotton fabric with high durability and low detection limit. ACS Appl Mater Interfaces 12(1):1474–1485. https://doi.org/10.1021/ACSAMI.9B17173/SUPPL_FILE/AM9B17173_SI_001.PDF
Zhou J, Yu H, Xu X, Han F, Lubineau G (2017) Ultrasensitive, stretchable strain sensors based on fragmented carbon nanotube papers. ACS Appl Mater Interfaces 9(5):4835–4842. https://doi.org/10.1021/ACSAMI.6B15195/SUPPL_FILE/AM6B15195_SI_001.PDF
Zu G, Wang X, Kanamori K, Nakanishi K (2020) Superhydrophobic highly flexible doubly cross-linked aerogel/carbon nanotube composites as strain/pressure sensors. J Mater Chem B 8(22):4883–4889. https://doi.org/10.1039/C9TB02953B
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Wang, Y., Venkataraman, M., Militký, J. (2023). Flexible Carbon-Based Nanocomposites. In: Militký, J., Venkataraman, M. (eds) Advanced Multifunctional Materials from Fibrous Structures. Advanced Structured Materials, vol 201. Springer, Singapore. https://doi.org/10.1007/978-981-99-6002-6_9
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