Abstract
The selective catalytic reduction (SCR) of NOx with NH3 has been investigated with coal ash. Coal samples from different regions of the People Republic of China are taken and processed to be used as the SCR catalysts. The influences of different coal ash catalysts, as well as the influences of calcination temperatures on the NOx conversion of catalysts, are analyzed. The methods of XRF, XRD, and BET are used to characterize the materials. It is found that the calcined sample at 800 °C with Ca: Fe: Al: Si ratio of 0.051: 0.123: 0.511: 1, exhibited good NH3-SCR activity in a broad temperature range of 200–500 °C. As well, the influences of [NH3]/[NO] molar ratio and oxygen concentration on the SCR activity are also studied.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Ahonen M (1997) Long-time experience in catalytic flue gas cleaning and catalytic NOx reduction in biofueled boilers. Fuel Energy Abstr 38(3):164
Boyano A, Lombardo N, Gálvez ME, Lázaro MJ, Moliner R (2008) Vanadium-loaded carbon-based monoliths for the on-board NO reduction: experimental study of operating conditions. Chem Eng J 144(3):343–351
Chmielarz L, Kustrowski P, Lasocha AR, Dziembaj R (2005) Selective oxidation of ammonia to nitrogen on transition metal containing mixed metal oxides. Appl Catal B 58:235–244
Gao R, Zhang D, Liu X, Shi L, Maitarad P et al (2013) Enhanced catalytic performance of V2O5–WO3/Fe2O3/TiO2 microspheres for selective catalytic reduction of NO by NH3. Catal Sci Technol 3:191
Itoh M, Saito M, Takehara M, Motoki K, Iwamoto J et al (2009) Influence of supported-metal characteristics on deNOx catalytic activity over Pt/CeO2. J Mol Catal A Chem 304:159–165
Lázaro MJ, Gálvez ME, Ruiz C, Juan R, Moliner R (2006) Vanadium loaded carbon-based catalysts for the reduction of nitric oxide. Appl Catal B Environ 68(3–4):130–138
Lee JH, Schmieg SJ, Oh SH (2008) Improved NOx reduction over the staged Ag/Al2O3 catalyst system. Appl Catal A Gen 342:78–86
Li J, Zhu R, Cheng Y, Lambert CK, Yang RT (2010) Mechanism of propene poisoning on Fe-ZSM-5 for selective catalytic reduction of NO(x) with ammonia. Environ Sci Technol 44:1799–1805
Li X, Li X, Chen J, Li J, Hao J (2016) An efficient novel regeneration method for Ca-poisoning V2O5-WO3/TiO2 catalyst. Catal Commun 87:45–48
Li X, Li X, Yang R, Mo J, Li J, Hao J (2017) The poisoning effects of calcium on V2O5-WO3/TiO2 catalyst for the SCR reaction: comparison of different forms of calcium. Molecular Catal 434:16–24
Liu F, Asakura k, He H, Liu Y, Shan W (2011) Influence of calcination temperature on iron titanate catalyst for the selective catalytic reduction of NOx with NH3. Catal Today 164:520–527
Liu F, He H, Zhang C, Shan W, Shi X (2011) Mechanism of the selective catalytic reduction of NOx with NH3 over environmental-friendly iron titanate catalyst. Catal Today 175:18–25
Long RQ, Yang RT (2000) Characterization of Fe-ZSM-5 catalyst for selective catalytic reduction of nitric oxide by ammonia. J Catal 194:80–90
Mochida I, Shirahama N, Kawano S, Korai Y, Yasutake A et al (2000) NO oxidation over activated carbon fiber (ACF). Part 1. Extended kinetics over a pitch based ACF of very large surface area. Fuel 79(14):1713–1723
Ruan HD, Frost RL, Kloprogge JT (2001) The behavior of hydroxyl units of synthetic goethite and its dehydroxylated product hematite. Spectrochim Acta Part A Mol Biomol Spectrosc 57(13):2575–2586
Schneider H, Maciejewski M, Kohler K, Wokaun A, Baiker A (1995) Chromia supported on Titania: VI. Properties of different chromium oxide phases in the catalytic reduction of NO by NH3 studied by in Situ diffuse reflectance FTIR spectroscopy. J Catal 157(2):312–320
Shi YN, Chen S, Sun H, Shu Y, Quan X (2013) Low-temperature selective catalytic reduction of NOx with NH3 over hierarchically macro-mesoporous Mn/ TiO2. Catal Commun 42:10–13
Singh A, Sharma V, Mittal S, Pandey G, Mudgal D, Gupta P (2018) An overview of problems and solutions for components subjected to fireside of boilers. Int J Indus Chem 9:1–15
Steenbruggen G, Hollman GG (1998) The synthesis of zeolites from fly ash and the properties of the zeolite products. J Geochem Explor 62(1–3):305–309
Tang X, Hao J, Xu W, Li J (2007) Low temperature selective catalytic reduction of NOx with NH3 over amorphous MnOx catalysts prepared by three methods. Catal Commun 8:329–334
Wan YP, ZhaoWR, Tang Y, Li L, Wang HJ, Cui YL et al (2014) Ni-Mn bi-metal oxide catalysts for the low temperature SCR removal of NO with NH3. Appl Catal B Environ 148:114–122
Wang X, Gui K (2013) Fe2O3 particles as superior catalysts for low temperature selective catalytic reduction of NO with NH3. J Environ Sci 25(12):2469–2475
Xuan X, Yue C, Li S, Yao Q (2003) Selective catalytic reduction of NO by ammonia with fly ash catalyst. Fuel 82:575–579
Yao Z, Ji X, Sarker P, Tang J, Ge L et al (2015) A comprehensive review on the applications of coal fly ash. Earth Sci Rev 141:105–121
Zhang X, Lv S, Jia X, Wu X, Meng F (2015) Low-temperature selective catalytic reduction of NO with NH3 over manganese oxides supported on fly ash-palygorskite. J Thermodyn Catal 6:3
Zhao Q, Xiang J, Sun L, Su S, Hu S (2009) Adsorption and oxidation of NH3 and NO over sol-gel-derived CuO-CeO2-MnOx/y-Al2O3 catalysts. Energy Fuels 23(3):1539–1544
Acknowledgements
This work was supported by National Natural Science Foundation of China (Grant no. 50676057).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2022 Tsinghua University Press.
About this paper
Cite this paper
Fareed, S., Wang, E., Husnain, N., Li, K., Li, D. (2022). Selective Catalytic Reduction of NOx with NH3 Using Coal Ash Catalyst. In: Lyu, J., Li, S. (eds) Clean Coal and Sustainable Energy. ISCC 2019. Environmental Science and Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-16-1657-0_63
Download citation
DOI: https://doi.org/10.1007/978-981-16-1657-0_63
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-16-1656-3
Online ISBN: 978-981-16-1657-0
eBook Packages: EnergyEnergy (R0)