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Volume of Liquid Water and Amorphous Ices

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Liquid-Phase Transition in Water

Part of the book series: NIMS Monographs ((NIMSM))

Abstract

Experimental data on the volumes of low-density amorphous ice, high-density amorphous ice, and liquid water were compared to discuss their phase relationships. It was suggested that liquid water becomes low-density amorphous ice when cooled at low pressure and becomes high-density amorphous ice when cooled at high pressure. It was also suggested that the two amorphous ices are distinctly different. Experiments on the amorphous-amorphous transition, vitrification, and glass transition supported the suggested phase relationships and indicated existence of a discontinuous first-order liquid–liquid transition.

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    Osamu Mishima

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Mishima, O. (2021). Volume of Liquid Water and Amorphous Ices. In: Liquid-Phase Transition in Water. NIMS Monographs. Springer, Tokyo. https://doi.org/10.1007/978-4-431-56915-2_2

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