Ore Mineralogical Study of Cerattepe Au-Cu ( – Zn) VMS Deposit (Artvin-Turkey)

. The Cerattepe mine, one of the volcanogenic massive sul ﬁ de deposits in northeastern Turkey, is hosted within the late Cretaceous volcanic, intrusive and sedimentary rocks. Deposit ’ s main ore body contains high-grade massive copper sul ﬁ des and a gold-silver and barium rich oxide zone, charac-terized by dense alteration stages, is situated on top of it. Replacement, cataclastic, breccia, dissemination, dendritic, concentric growth, colloform, and framboidal textures were identi ﬁ ed. Pyrite, sphalerite, marcasite, chalcopyrite, bornite, galena, tennantite-tetrahedrite, gold, covellite, digenite, chalcocite, cuprite and cubanite constitute the mineral paragenesis where quartz, calcite and barite account for the gangue minerals. Limonite, hematite, lepidocrocite, malachite, azurite and jarosite developed in the oxidation zone.


Introduction
The eastern Pontide orogenic belt of Turkey is an important segment of the Tethyan-Eurasian Metallogenic Belt. This belt carries a special importance in metallogeny of Turkey and hosts numerous VMS deposit. (Akıncı 1984;Çiftçi and Hagni 2005;Güven 1993;Revan et al. 2013;Zaykov et al. 2006;Yiğit 2005). The most of the eastern Pontide VMS deposits show some similarities in many aspects to the Kuroko deposits of Japan (Çiftçi and Hagni 2005;Ciftci 2000;Pejatoviç 1979). The Cerattepe Deposit is a Kuroko-type VMS deposit located in late Cretaceous age volcanic, intrusive and sedimentary rocks. It is distinguished by an unusual basal zone of highgrade copper sulfides and an overlying Au-rich oxide zone from the other VMS deposits of northeastern Pontides.

Methods and Approaches
A total of 46 samples representing oxide (14), sulfide (28) and stringer zones (4) of Cerattepe ore deposit were collected from drill cores, underground audits and surface outcrops. Polished sections were prepared and Nikon Eclipse LV100 reflected light microscopy was employed for examination. The ore minerals and the paragenesis were identified on the basis of their petrographical features and their textural relationships, respectively. Electron Probe Micro Analysis (EPMA) and Secondary Electron Microscopy-Energy Dispersive Spectroscopy (SEM-EDS) were used for chemistry of sulfide minerals.
Gangue minerals include barite, quartz, gypsum, anhydrite and calcite. Hematite, limonite, lepidocrocite, malachite and azurite, and jarosite are the oxidation minerals. Four generation of pyrite is specified. Pyrite I is represented by colloform-concentric textured (Fig. 2) grains formed from initial solution reached the seafloor from the chimney. The colloform textured pyrites are progressively overgrown later coarse crystalline grains, which are the second generation pyrites.
These are later extensively altered to marcasite. The framboidal-pelletal textured collomorphic grains, seen sometimes coeval with sphalerite and galena, are the third generation pyrites. The fourth generation pyrites are small sized euhedral, subhedral grains observed on transition zone of sulfide ore-footwall rock and veinlets of stringer zone. Most of the minerals are small -fine grained, and the larger grains of the major minerals are in the order of 100-800 µm up to 1.2-2 mm in size and some rare pyrite grains have a size of 5 mm. Most of the minor and trace minerals are much smaller, typically in the order of 1-20 µm in size. Majority of ore minerals are anhedral with the exception of pyrite, quartz, barite and some sphalerite and galena occur as euhedral to subhedral crystals. Observed ore textures are dissemination and veinlet textures in the stockwork and siliceous ore zones, whereas replacement, overgrowth, concentric and colloform textures become prevalent in the massive ore, particularly in the center of main deposit.
Banded textures of black and yellow ore are seen with polymetallic sulfides. In the outer part of the main ore body, at lateral zones, clastic or fragmental ore textures are present.

Conclusions
It is concluded that the ore mineral assemblage and textures observed in Cerattepe VMS deposit are comparable to those of other VMS deposits occur in north eastern Pontide region, Kuroko deposits of Japan and also comparable modern seafloor-seamount VMS deposits in the world.