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Adsorption Chromatography: Mechanism and Materials

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Practical Liquid Chromatography

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Abstract

Adsorption may be defined as the concentration of solute molecules at the interface of two immiscible phases. In liquid-solid adsorption chromatography (LSAC) the mobile phase is a liquid while the stationary phase is a finely divided, usually porous solid. The atoms in the bulk of the solid are subjected to equal forces in all directions, whereas the surface atoms experience unbalanced forces which can attract molecules from the surrounding solution to restore the balance.

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References

  1. Giles, C. H., MacEwan, T. H., Nakhwa, S. N., and Smith, D., J, Chem. Soc. 3973 (1960).

    Google Scholar 

  2. Snyder, L. R., Principles of Adsorption Chromatography, Dekker, New York (1968).

    Google Scholar 

  3. Snyder, L. R., J. Chromafog. 5, 430 (1961).

    Article  CAS  Google Scholar 

  4. Snyder L. R. Separation Sci. 1 191 1966

    Article  CAS  Google Scholar 

  5. Hesse, G., and Roscher, G., Z. Anal. Chem. 200, 3 (1964).

    Article  CAS  Google Scholar 

  6. Hagdahl, L., and Holman, R. T., J. Am. Chem. Soc. 72, 701 (1950).

    Article  CAS  Google Scholar 

  7. Snyder, L. R., Advan. Anal. Chem. Inst. 3, 251 (1964).

    CAS  Google Scholar 

  8. Snyder, L. R., J. Chromatog. 23, 388 (1966).

    Article  CAS  Google Scholar 

  9. Hesse, G., Z. Anal. Chem. 211, 5 (1965).

    Article  CAS  Google Scholar 

  10. Bowen, J. N., Bowrey, R., and Malin, A. S., J. Catalysis 1, 209 (1967).

    Article  Google Scholar 

  11. Snyder, L. R., J. Chromatog. 12, 488 (1963).

    Article  CAS  Google Scholar 

  12. Floridin Technical Data and Product Specifications, Floridin Co., Tallahassee, Fla.

    Google Scholar 

  13. Snyder, L. R., J. Chromatog. 28, 300 (1967).

    Article  CAS  Google Scholar 

  14. Stahl, E., and Dumont, E., J. Chromatog. Sci. 7, 517 (1969)

    Article  CAS  Google Scholar 

  15. Urbach, G., J. Chromatog. 12, 196 (1963).

    Article  CAS  Google Scholar 

  16. Gupta, A. S., and Dev. S., J. Chromatog. 12, 189 (1963).

    Article  CAS  Google Scholar 

  17. Chapman L. R., and Kuemmel, D. F., Anal. Chem. 37, 1598 (1965).

    Article  CAS  Google Scholar 

  18. Morris, L. J., J. Chromatog. 12, 321 (1963).

    Article  CAS  Google Scholar 

  19. Berg, A., and Lam, J., J. Chromatog. 16, 157 (1964)

    Article  CAS  Google Scholar 

  20. Klemm, L. H., Reed, D., and Lind, C. D., J. Org. Chem. 22, 739 (1957).

    Article  CAS  Google Scholar 

  21. Harvey, R. G., and Halonen, M., J. Chromatog. 25, 294 (1966).

    Article  CAS  Google Scholar 

  22. Kessler H. and Müller E. J. Chromatog. 24 469 1966

    Article  CAS  Google Scholar 

  23. Adachi, S., J. Chromatog. 17, 295 (1965).

    Article  CAS  Google Scholar 

  24. Cawthorne, M. A., J. Chromatog. 25, 164 (1966).

    Article  CAS  Google Scholar 

  25. Brockmann, H., Disc. Faraday Soc., 7, 58 (1949).

    Article  Google Scholar 

  26. Fogg, A. G., and Wood, R., J. Chromatog. 20, 613 (1965).

    Article  CAS  Google Scholar 

  27. Horvath, C. G., and Lipsky, S. R., J. Chromatog. Sci. 7, 109 (1969).

    Article  CAS  Google Scholar 

  28. Horvath, C. G., Preiss, B. A., and Lipsky, S. R., Anal Chim. 39, 1422 (1967).

    Article  CAS  Google Scholar 

  29. Kirkland, J. J., Anal. Chem. 41, 218 (1969).

    Article  CAS  Google Scholar 

  30. Kirkland, J. J., J. Chromatog. Sci. 7, 361 (1969).

    Article  CAS  Google Scholar 

  31. Majors, R. E., J. Chromatog. Sci. 8, 338 (1970).

    Article  CAS  Google Scholar 

  32. Webster, P. Y., Wilson, J. N., and Franks, M. C., Anal. Chim. Acta 38, 193 (1967).

    Article  CAS  Google Scholar 

  33. Kunin, R., Meitzner, E. F., Oline, J. A., Fisher, S. A., and Frisch, N., Ind. Eng. Chem. Prod. Res. Dev. 1, 140 (1962).

    Article  CAS  Google Scholar 

  34. Heftmann, E., Chromatography, Reinhold, New York (1967).

    Google Scholar 

  35. Hockey, J. E., Chem. Ind. (London) 57 (1965}).

    Google Scholar 

  36. Helfferich, F., Ion-exchange chromatography, Advan. Chromatog. 1, 3 (1966).

    Google Scholar 

Further Reading

  • Giles, C. H., and Easton, I. A., Adsorption chromatography, Advan. Chromatog. 3, 70 (1966). (A discussion of isotherm shape and the nature of adsorption forces on silica, alumina, and carbon.)

    Google Scholar 

  • Young, D. M., and Crowell, A. D., Physical Adsorption of Gases, Butterworths, London (1962). (A comprehensive review which gives an insight into the nature of physical adsorption.)

    Google Scholar 

  • Snyder, L. R., Principles of Adsorption Chromatography, Dekker, New York (1968). (A comprehensive account of separation processes and basic principles of liquid-solid adsorption chromatography together with a systematic generalization of available data on the separation of nonionic organic compounds.)

    Google Scholar 

  • Hayward, D.O., and Trapnell, B. M. W., Chemisorption, Butterworths, London (1964). (A comprehensive review which gives an insight into the nature of chemisorption.)

    Google Scholar 

  • Snyder, L. R., RF values in thin-layer chromatography on alumina and silica, Advan. Chromatog. 4, 3 (1967). (A general theory for the correlation and prediction of RF values in TLC. The theory is tested and confirmed by applying it to literature data.)

    CAS  Google Scholar 

  • Everett, D. H., and Stone, F. S. (eds.), The Structure and Properties of Porous Materials, Butterworths, London (1958). (Contains chapters on the surface characteristics of carbons and silicas.)

    Google Scholar 

  • Hockey, J. A., The surface properties of silica powders, Chem. Ind. (London) 1965, 57

    Google Scholar 

  • Mitchell, S. A., surface properties of amorphous silicas, Chem. Ind. (London) 1966, 924. (Accounts of the effects of different methods of preparation and subsequent thermal or chemical treatment on the nature and properties of the silica surface.)

    Google Scholar 

  • Heftmann, E., Chromatography, Reinhold, New York (1967). (A general review of chromatography.)

    Google Scholar 

  • Coughlin, R. W., Carbon as adsorbent and catalyst, Ind. Eng. Chem. Prod. Res. Dev. 8, 12 (1969). (The structure and surface chemistry of carbon is related to its catalytic and adsorptive behavior.)

    Article  CAS  Google Scholar 

  • Dubinin, M. M., Porous structure and adsorption properties of active carbons, in Chemistry and Physics of Carbon, Walker, P. L., ed., Dekker, New York (1966), vol. 2, p. 51. (Basic studies.)

    Google Scholar 

  • Zettlemoyer, A. C., and Narayan, K. S., Adsorption from solution by graphite surfaces, Ibid., p. 197. (Some basic studies including a comparison of Graphon and Spheron 6.)

    Google Scholar 

  • Amphlett, C. B., Inorganic Ion Exchangers, Elsevier, London (1964). (Covers the recently developed inorganic ion exchangers useful for high-temperature work. Mainly inorganic separations, though possibly applicable to nonaqueous work.)

    Google Scholar 

  • Helfferich, F., Inorganic Ion Exchangers, McGraw-Hill, New York (1962). (A comprehensive account covering basic theory of ion exchangers.)

    Google Scholar 

  • Inczédy, J., Analytical Applications of Ion Exchangers, Pergammon Press, Oxford (1966); Samuelson, C., Ion Exchange Separations in Analytical Chemistry, Wiley, New York (1963). (Useful practical books covering elementary theory and basic techniques of ion-exchange chromatography, including separations of organic mixtures.)

    Google Scholar 

  • Helfferich, F., Ion exchange chromatography, Advan. Chromatog. 1, 3 (1966). (A review of advances in ion-exchange chromatography during 1960–1965. Includes examples of organic separations in nonaqueous media and of ligand-exchange chromatography.)

    Google Scholar 

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Authors and Affiliations

  1. Esso Petroleum Company, Limited Esso Research Centre Abingdon, Berkshire, England

    S. G. Perry, R. Amos & P. I. Brewer

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  1. S. G. Perry
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  2. R. Amos
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  3. P. I. Brewer
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© 1973 Springer Science+Business Media New York

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Perry, S.G., Amos, R., Brewer, P.I. (1973). Adsorption Chromatography: Mechanism and Materials. In: Practical Liquid Chromatography. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-6226-6_3

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  • DOI: https://doi.org/10.1007/978-1-4757-6226-6_3

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-6228-0

  • Online ISBN: 978-1-4757-6226-6

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