Abstract
In this introductory lecture some basic terms used in catalytic literature will be defined and some examples of the experimental techniques (conventional and modern) will be presented.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Fundamental Principles in Heterogeneous Catalysis, NATO A.S.I., Venice, Italy 1971 – lecture by L. Carra
Satterfield C.N., Mass Transfer in Heterogeneous Catalysis, M.I.T. Press, Cambridge, U.S.A. (1970)
Hougen O.A., Ind. Eng. Chem. 53 (1961) 509
Weisz P.B. and Prater C.D., Adv. Catal. 6 (1954) 144
Melville H. and Gowenlock B.G., Experimental Methods in Gas Reactions, McMillan, London (1964)
Comprehensive Chemical Kinetics, ed. C.H. Bamford and C.F.H. Tipper, Vol. 1, Elsevier, Amsterdam (1969)
Temkin M.A., Kinetika i Kataliz 3 (1962) 509
Campbell K.C. and Thomas S.J., Trans. Faraday Soc. 55 (1959) 985
Roberti A., Ponec V. and Sachtler W.M.H, J. Catal. 28 (1973) 381.
Van der Plank P. and Sachtler W.M.H., J. Catal. 12 (1968) 35.
Anderson J.R. and Avery N.R., J. Catal. 8 (1967) 48
Kemball C., Nisbet J.D., Robertson P.J. and Scurell M.S., Proc. Roy. Soc. London A338 (1974) 299
Kokes R.J., Tobin H. and Emmett P.H., J. Am. Chem. Soc. 77 (1955) 5860
Blanton W.A., Byers C.H. and Merrill R.P., Ind. Eng. Chem. 7 (1968) 611
Galeski J.B. and Hightower J.W., Canad. J. Chem. Eng. 48 (1970) 151
Frennet A. and Liénard G., Proc. IVth Int. Congr. Catal., Moscow, 1968; paper 51, p.65 -Akademiai Kiado, Budapest, 1971.Frennet A., Catal. Rev. Vol.10, in press
Ponec V., Preparation of Ultra-clean Surfaces, in Treatese on Adhesion, ed. R.C. Patrick, 1969, M. Dekker, N.Y., p. 485 k17) Shooter D. and Farnsworth H.E., J. Phys. Chem. 66 (1962) 169
Onchi M. and Farnsworth H.E., Surface Sci. 11 (1960) 203
Somorjai G.A., Joyner R.W. and Lang B., Proc. Roy. Soc. London A334 (1972) 335
Kahn D.R., Petersen E.E. and Somorjai G.A., J. Catal. 34 (1974) 294
Merrill R.P., Catal. Rev. 4 (1970) 115
Mc Carroll J.J. and Thomson S.J., J. Catal. 19 (1970) 144
Tamaru K., Trans. Faraday Soc. 59 (1959) 824
Fukuda K., Onishi T. and Tamaru K., Bull. Soc. Chem. Japan 42 (1969) 1192.
Noto Y., Fuduka K., Onishi T. and Tamaru K., Trans. Faraday Soc. 63 (1967) 3081
Fukuda K., Nagashima S., Noto Y., Onishi T. and Tamaru K., Trans. Faraday Soc. 64 (1968) 522
Tajbl D.G., Simons J.B. and Carberry J.J., I. & E.C. Fundamentals 5 (1966) 171
Mahoney J.A., J. Catal. 32 (1974) 247
Emmett P.H., Adv. Catal. 1 (1948) 65
Watson J.H.L., Anal. Chem. 20 (1948) 576
Moss R.L., Platinum Metal Rev. 11 (1967) 141
Renouprez A., Hoang-Van C. and Compagnon P.A., J. Catal. 34 (1974) 411
Flynn P.C., Wanke S.E. and Turner P.S., J. Catal. 33 (1974) 237
Adams C.R., Benesi H.A., Curtis R.M. and Meisenheimer R.G., J. Catal. 1 (1962) 336
Jellinek M.H. and Fankuchen I., Adv. Catal. 1 (1948) 257
Scherer P., Nachr. Ges. Wiss. Göttingen, Math. Phys. k12 (1918) 98
Jones F.W., Proc. Roy. Soc. London A166 (1938) 16
Splindler H., Z. Chemie 13 (1973) 1
Smith W.L., J. Appl. Crystal. 5 (1972) 127
Renouprez A., Hoang-Van C. and Compagnon P.A., J. Catal. 34 (1919) 411
Guinier A., Ann. Phys. 12 (1939) 162;
Guinier A. and Fournet G., Small Angle Scattering, ed. J. Wiley & Son, N.Y., 1955
Beecroft T. and Miller A.W., Preparation and Characterization of Solid Catalysts, in Repts on Progress Appl. Chem. 55 (1970) 385.
Ciapetta F.G. and Plank C.J. in Catalysis, ed. P.H. Emmett, Vol.1, Reinhold, N.Y. (1974)
Prestridge E.B. and Yates D.J.C., Nature 234 (1971) 345
Müller J., Rev. Pure and Appl. Chem. (Austr.) 19 (1969) 151
Sermon P.A. and Bond G.C., Catal. Rev. 8 (1973) 211 Kral H., Z. physik. Chem. NF 48 (1966) 129
Schlosser E.G., Chem. Ing. Technik 39 (1967) 409
Spindler H., Z. Chem. 13 (1973) 1
Stranski I.N., Forms of Equilibrium of Crystals, in Disc. Faraday Soc. 5 (1949) 13
Poltorak 0.M., Zhur. Foz. Khim. 34 (1960) 1
Sachtler W.M.H., Dorgelo G. and Vand der Knapp W., J. Chim. Phys. 5 (1954) 494
Anderson J.R. and Avery N.R., J. Catal. 5 (1966) 446
Anderson J.R., Baker B.G. and Sanders J.V., J. Catal. 1 (1962) 443
Schlosser E.G., Ber. Bunsenges. Physik. Chem. 73 (1969) 358
Van Hardeveld R. and Hartog F., Surface Sci. 15 (1969) 189
Poltorak 0.M. and Boronin V.S., Zhur. Fiz. Kchim. 40 (1966) 1436
Boudart M., Vannice M.A. and Benson J.E., Z. Physik. Chem. NF 64 (1969) 171
Schwab G.M. and Pietch E., Z. Physik. Chem. Abt. B 1 (1928) 385 Taylor H.S., Proc. Roy. Soc. A108 (1925) 105
Van Hardeveld R. and Hartog F., IVth Int. Congr. Catal., Moscow 1968, paper 70; Akademiai Kiado Budapest, 1971, Vol. 2. p. 295
Burton J.J., Catal. Rev.- Sci.Eng. 9 (1974) 209
Allpress J.G. and Sanders J.V., Austr. J. Phys. 23 (1970) 23
Rostrup-Nielsen J.B., J. Catal. 31 (1973) 173
Schwab G.M. and Holz G., Z. Anorg. Allg. Chem. 252 (1944) 305
Schwab G.M., 67 (1955) 433
Schwab G.M., Disc. Faraday Soc. 8 (1950) 166
Proceedings of the IVth International Congress on Catalysis, Moscow, 1968; ed. Akademiai Kiado, Budapest, Hungary, 1971
Kemball C., Proc. Roy. Soc. London A 214 (1952) 413
Dowden D.A., J. Chem. Soc. 1950, 242; Ind. Eng. Chem. 44 (1952) 997
Dowden D.A., Chemisorption, ed. W.E. Garner, Butterworth, London, 1957, p. 3
Beeck 0., Disc. Faraday Soc. 8 (1950) 118
Beeck 0., Rev. Mod. Phys. 17 (1945) 61
Derouane E.G., Mémoires Soc. Roy. Sci. Liège, 6iéme série, tome 1, Fasc. 4, p. 297, 1971
Derouane E.G., Ind. Chim. Belg. 36 (1971) 359
Sabatier P., Berichte 44 (1911) 2001
Balandin A.A., Adv. Catal. 19 (1969) 1
Fahrenfort J.J., Van Reijen L.L. and Sachtler W.M.H., Z. Elektrochem. 64 (1960) 216
Schuit G.C.A., Van Reijen L.L. and Sachtler W.M.H., Act. 2ième Congr. Int. Catal., ed. Technip, Paris, 1961, p. 893
Makishima S., Yoneda Y. and Satto Y., Act.2iéme Congr. Int. Catal., ed. Technip, Paris, 1961, p. 671
Golodetz G.J. and Boiter V.A.•, Ukr. Khim. Zhur. 29 (1963) 667
Tanaka K. and Tamaru K., J. Catal. 2 (1963) 366
Tanaka K. and Tamaru K., Kin. i Kat. 7 (1966) 242
Ponec V. and Schuit G.C.A., Chem. Wkbl. 1974
Ponec V. and Cerny S., Disc. Czechosl. Acad. Sci. 75 (1965) No. 5
Ponec V., Proc. IIIrd Int. Congr. Catal., Amsterdam; Sachtier W.M.H., North-Holland Publ. Comp., 1965, p.544 (Discussion) Knor Z., ibid. p. 545 (Discussion)
Bond G.C., Catalysis by Metals, Acad. Press, London, 1962
Perri B., Disc. Faraday Soc. 41 (1966) 121
Kouskova A., Adamek J. and Ponec V., Coll. Czech. Chem. Commun. 35 (1970) 2538
Bond G.C. and Wells P.B., Adv. Catal. 15 (1964) 91
Wells P.B., Chemistry & Industry (Britain) 1964, 1742
Kemball C., Catal. Rev. 5 (1971) 33
Burnell R.L. Jr, Accounts Chem. Res. 2 (1969) 289; Catal. Rev. 7 (1) (1972) 25.
see e.g. Bond G.C. and Turkevich T.J., Trans. Faraday Soc. 50 (1954) 1335
Addy J. and Bond G.C., Trans. Faraday Soc. 33 (1957) 386, 383, 388
Rooney J.J., Chemistry in Britain 21+2 (1966)
Horrex C., Moyes R.B. and Squire R.C., Proc. IVth. Int. Congr. Catal., Moscow, 1968; ed. Akademiai Kiado, Budapest, (1971) p. 333
Hirota K. and Ueda T., Proc.IIIrd Int. Congr. Catal., Amsterdam, 1964; ed. Sachtler W.M.H. et al., North-Holland Publ. Comp. (1965) p. 1238
Harper R.J. and Kemball C., Proc.IIIrd Int. Congr. Catal., Amsterdam, 1964; ed. Sachtier W.M.H. et al., North-Holland Publ. Comp. (1965), p. 1145
Crawford E. and Kemball C., Trans. Faraday Soc. 58 (1962) 2452
Phillips M.J., Crawford E. and Kemball C., Nature 197 (1963) 487
Van Schaik J.R.H., Dessing R.P. and Ponec V., J. Catal., in press
Kikuchi E. and Morita Y., J. Catal. 15 (1969) 217
Matsumoto H., Saito Y. and Yoneda Y., J. Catal. 22 (1971) 182
Carter J.L., Cusumano J.A. and Sinfelt J.H., J. Catal. 20 (1971) 223
Anderson J.R., Mac Donald R.J. and Shimoyama Y., J. Catal. 20 (1971) 147
Corrolleur C., Tomanova D. and Gault F.G., J. Catal. 24 (1972) 401
Merta R. and Ponec V., Proc. IVth Int. Congr. Catal., Moscow, 1968; Akademiai Kiado, Budapest, Vol.2 (1971) p. 53
Ross J.R.H., Roberts M.W. and Kemball C., J. Chem. Soc., Faraday Trans. I, 68 (1972) 914
Margolis L.Y., Adv. Catal. 14 (1963) 420
Voge H.H. and Adams C.R., Adv. Catal. 17 (1967) 151
Margolis L.Y., Catal. Rev. 8 (1) (1974) 241
Sachtler W.M.H., Catal. Rev. 4 (1970) 277
Cant N.W. and Hall W.K., J. Catal. 16 (1970) 226
Patterson W.R. and Kemball C., J. Catal. 2 (1967) 465
Kilty P.A., Rol N.C. and Sachtler W.M.H., Proc. Vth Congr. Catal., Palm Beach, 1972, North-Holland Publ. Comp. Vol. 2, (1973) 929
Siskova M. and Erdos E., Coll. Czech. Chem. Commun. 25 (1960) 1729
Defay R., Prigogine I., Belleman A. and Everett D.H., Surface Tension and Adsorption, Langman, Green, N.Y., 1966
Gugenheim E.A., Trans. Faraday Soc. 41 (1945) 150
Elovich S.Yu and Larionov C.G., Izv. Akad. Nauk SSSR, Otd. Khim. Nauk 1962, 531
Van Santen R.A. and Boersma M.A.M., J. Catal. 34 (1974) 13
Van Santen R.A. and Sachtler W.M.H., J. Catal. 33 (1974) 202
Williams F. and Nason D., Surface Sci. 45 (1974) 377
Meijering J.L., Acta Metall. 14 (1966) 251
Sachtler W.M.H., Dorgelo G.J.H. and Jongepier R., Basis Problems in Thin Film Physics, Göttingen, VanderHoek & Ruprecht, 1966, p. 218
Van der Plank P. and Sachtler W.M.H., J. Catal. 12 (1968) 35
Elford L., Müller F. and Kubashewski 0., Ber. Bunsenges. 73 (1969) 601
Meijering J.L., Acta Met. 8 (1957) 257
Palczewska W. and Majchrzak S., Bull. Acad. Polon. Sci. Série Chim. 17 (1969) 681
Sachtler W.M.H., Le Vide, No. 164, 1973, p. 67
Results of P.E.C. Franken, this laboratory, will be published soon
Bouwman R. and Sachtler W.M.H., J. Catal. 19 (1970) 127
Helms C.R., J. Catal. 36 (1975) 114
Ertl G. and Köppers J., J. Vac. Sci. Technol. 9 (1972) 829
Quinto D.T., Sundaram V.S. and Robertson W.D., Surface Sci. 28 (1971) 504
Nakayama K., Ono M. and Shimitzu H., J. Vac. Sci. Technol. 9 (1972) 749
Takahassa Y. and Shimizu H., J. Catal. 29 (1973) 479
Ono M., Takasu Y., Nakayama K. and Yamashina T., Surface Sci. 26 (1971) 313
Williams F.L. and Boudart M., J. Catal. 30 (1973) 438
Mathieu H.J. and Landolt D., paper 14; Stoddart G.T.H., Moss R.L. and Pope P., paper 15; Surface Sci. Conference, Warwick, 1975. Will be publised in Surface Sci.
Takasu Y., Konno H. and Yamashina T., Surface Sci. 45 (1974) 321
Hardy W.A. and Linnett J.W., Trans. Faraday Soc. 66 (1970) 487
Franken P.E.C. and Ponec V., J. Catal. 35 (1974) 417
Sachtler W.M.H., Ber. Bunsenges. Phys. Chem. 59, No. 2, (1955) 119
Albrecht H.E., Phys. Stat.Sol. (a) 6 (1971) 135
Lang N.D. and Kohn W., Phys. Rev. B3 (1971) 1215
Lang N.D., Phys. Rev. B4 (1971) 4234
Smith J.R., Phys. Rev. 181 (1969) 522
Mahan G.D. and Schaich W.L., Phys. Rev. B10 (1974) 2647
Rivière J.C., Work Function, Measurements and Results, in Solid State Surface Sci.; ed. Green, M. Dekker, N.Y., 1969, Vol. 1, p. 179
Culver R.V. and Tompkins F.C., Adv. Catal. 11 (1959) 68
Tompkins F.C., The Solid-Gas Interface; ed. Flood E.A., M. Dekker, N.Y. 1967
Mott N.F. and Jones H., Theory and Properties of Metals and Alloys, Oxford, 1936
Dowden D.A., Proc. IVth Int. Congr. Catal., Moscow, 1968; ed. Akademiai Kiado, Budapest, 1971
Van der Plank P. and Sachtler W.M.H., J. Catal. 7 (1967) 300
Cadenhead D.A. and Wagner N.J., J. Phys. Chem. 72 (1968) 2775
Sinfelt J.H., Carter J.L. and Yates D.J.C., J. Catal. 24 (1972) 283
Stephan J.J. and Ponec V., J. Catal. 37 (1975) 81
Brongersma H.H., J. Vac. Sci. Technol 11 (1974) 231
Brongersma H.H., Private Commun. (also an invited paper at the Surface Sci. Conf., Warwick, 1975; will be published in Surface Sci.)
Klemperer D., Private Commun.
a)McKee D.W., Trans. Faraday Soc. 64 (1968) 2200
McKee D.W. and Norton F.J., J. Phys. Chem. 68 (1964) 481
Vlasveld J.L., M. Sc. Thesis, Leiden University, 1975
Cvetanovic R. and Amenomiya J., Catal. Rev. 6 (1972) 12
Ehrlich G., Adv. Catal. 14 (1963) 256
Redhead P.A., Vacuum 12 (1962) 203
Carter G., Vacuum 12 (1962) 245
Smith A.W., J. Coll. Interfaces Sci. 34 (1970) 491
Ponec V. and Sachtler W.M.H., J. Catal. 24 (1972) 250
Stephan J.J., Ponec V. and Sachtler W.M.H., Surface Sci. 47 (1975) 403
Stephan J.J., Thesis, Leiden University, 1975
Nyrop J.E., The Catalytic Action of Surfaces, Levin & Munksgaard, Copenhagen, 1937
Schwab G.M., Disc. Faraday Soc. 8 (1950) 166
Couper A. and Eley D.D., ibid. 81950) 172
Dowden D.A. and Reynolds P.W., ibid. 8 (1950) 184
Wolkenstein Th.Th., The Electronic Theory of Catalysis on Semiconductors, Pergamon Press, Oxford, 1963
Boreskov G.K., Kini Kat. 10 (1969) 5 (in English)
Koutecky J., Trans. Faraday Soc. 54 (1958) 1038;
Z. Elektrochem. 60 (1956) 835
Grimley T.B., J. Vac. Sci. Technol. 8 (1971) 31
Knor Z., J. Vac. Sci. Technol. 8 (1971) 57
Thorpe B.I., Surface Sci. 33 (1972) 306
Newns D.M., Phys. Rev. 178 (1969) 1123
Penn D.R., Surface Sci. 39 (1973) 333
Kelly M., Surface Sci. 43 (1974) 587
Sachtler W.M.H. and Dorgelo G.J.H., Z. Physik. Chem. NF 25 (1960) 69
Sachtler W.M.H., Proc. IIIrd Int. Vac. Congr., Vol. 1, p. 41 (1966)
Hüfner S., Wertheim G.K. and Wernick J.H., Phys. Rev. B 8 (1973) 1973
Lang N.D. and Ehrenreich H., Phys. Rev. 168 (1968) 605
Kouvel J.S. and Comly J.B., Phys. Rev. Letters 24 (1970) 598
Seib D.H. and Spicer W.E., Phys. Rev. Letters 20 (1968) 1441
Stocks G.M., Williams R.W. and Faulkner J.S., J. Phys. F. Metal Physics 3 (1973) 1688
Gibb T.R.P. Jr, McMillan J. and Roy R.J., J. Phys. Chem. 70 (1966) 3024
Wenger A. and Steinemann S., Helv. Phys. Acta 47 (1974) 321
Cooper M.J., Phil. J. Mag. 8 (1963) 811
Mozer B., Keating D.T. and Moss S.C., Phys. Rev. 175 (1968) 868
Hicks T.J., Rainford B., Kouvel J.S., Louw G.G. and Comly J.B., Phys. Rev. Letters 22 (1969) 531
Kidron A., Phys. Letters 30A (1969) 304
Robbins C.G., Claus H. and Beck P.A., Phys. Rev. Letters 22 (1969) 1307;
Vogt E., phys. stat. sol. (b) 50 (1972) 653
Perrier J.P., Tissier B. and Tournier R., Phys. Rev. Letters 24 (1970) 313
Soma-Noto Y. and Sachtler W.M.H., J. Catal. 32 (1974) 315
Ponec V. and Sachtler W.M.H., J. Catal. 24 (1972) 250
Ponec V. and Sachtler W.M.H., Catalysis, Proc. Vth Int. Congr. Catal., Miami Beach, 1972; ed. Hightower, North-Holland Publ. Comp., 1973, p. 645, paper 43
Rushford H.G. and Whan D.A., Trans. Faraday Soc. 67 (1971) 3577
Van Barneveld W.A.A. and Ponec V., Rec. Tray. Chim. 93 (1974) 243
Jongepier R. and Sachtler W.M.H., J. Res. Inst. Catal., Hokkaido Univ. 16 (1968) 69
Ljubarskii G.D., Evzerikhin E.I. and Slinkin A.A., Kin. i Kat. 5 (1964) 311
Bond G.C. and Mann R.S., J. Chem. Soc. 3566 (1959)
Mann R.S. and Khulbe C., Canad. J. Chem. 48 (1970) 2075
Mann R.S. and Khulbe K.C., ibid. 45 (1967) 2755; 47 (1969) 215
Cadenhead D.A. and Masse N.G., J. Phys. Chem. 70 (1966) 3553
Sinfelt J.H., Carter J.L. and Yates D.J.C., J. Catal. 24 (1972) 283
Cadenhead D.A., Wagner N.J. and Thorp R.L., Proc. IVth Int. Congr. Catal., Moscow, 1968; Akademiai Kiado, Budapest, 1971, Vol.1, p. 341, paper 26
The literature not quoted in Ref. 57, relevant for the dicussion on Pd-Au or Pd-Ag alloys:
Hardy W.A. and Linnett J.W., Trans. Faraday Soc. 66 (1970) 447 Inami S.H. and Wise H., J. Catal. 26 (1972) 92
Eley D.D., J. Res. Inst. Catal. Hokkaido Univ. 16 (1968) 101
Joice B.J., Rooney J.J., Wells P.B. and Wilson G.R., Disc. Faraday Soc. 41 (1966) 223
McKee D.W., J. Phys. Chem. 70 (1966) 525
Cinneide A.O. and Clark J.K.A., J. Catal. 26 (1972) 233
Visser C., Zuidwijk J.G.P. and Ponec V., J7-Catal. 35(1974)457
Ponec V., Catal. Rev. - Sci. Eng. 11 (1) (1975) 41
Roberti A., Ponec V. and Sachtler W.M.H., J. Catal. 28 (1973) 381
Beelen J.M., Ponec V. and Sachtler W.M.H., J. Catal. 28 (1973) 376
Sinfelt J.H., J. Catal. 29 (1973) 308
Gray T.J., Masse N.G. and Oswin H.G., Act.2 iéme Congr. Int. Catal., Paris, 1960; ed. Technip Paris, 1961, Vol.2, p.1697, paper 83
Van Schaik J.R.H., M. Sc. Thesis; see also Ref. 69
Dessing R.P., Thesis, Leiden University, 1974
Kemball, C. and Patterson W.R., Proc. Roy. Soc. London A 27n (1962) 219
Gerberich, H.R., Cant, N.W. and Hall, W.K., J. Catal. 16 (1970) 204
for review see: Kilty, R. and Sachtler, W.M.H., Catal. Rev. 10 (1974)
Snel, R., M.Sc.Thesis, Leiden University, 1974
Kuijers, F.J., M.Sc. Thesis, Leiden University, 1973
Pauling, L. Proc. Roy. Soc. London, A 196, 343 (199)
Baker and Jenkins, Adv. Catal. 7, 1 (1955)
Coles and Hume Rothery, Adv. Physics 3, 149 (1954)
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1976 Plenum Press, New York
About this chapter
Cite this chapter
Ponec, V. (1976). Catalysis by Supported and Unsupported Metals and Alloys. In: Derouane, E.G., Lucas, A.A. (eds) Electronic Structure and Reactivity of Metal Surfaces. NATO Advanced Study Institutes Series, vol 16. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2796-7_17
Download citation
DOI: https://doi.org/10.1007/978-1-4684-2796-7_17
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-2798-1
Online ISBN: 978-1-4684-2796-7
eBook Packages: Springer Book Archive