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Effect of variable conditions on the adsorption selectivity of molecularly imprinted polymers

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Abstract

This work mainly studied the separation performance of quercetin molecularly imprinted polymer (Qu-MIP) on quercetin (Qu) in the presence of other flavonoids which possessed similar structures partially at least under different variable conditions. Results documented that Qu-MIP exhibited a special selectivity to Qu in all conditions, and the special selectivity would be enlarged obviously when the total concentration and temperature increased. Besides, quantitative analysis of the degree of separation (D) and concentration (C) (or temperature (T)) displayed a well linear relationship between lnD and C (or T), and the intercept of line, which we defined as the Napierian logarithm of eigen separation degree, increased with the increase of molecular size, which meant MIP could separation target compounds from complex solution system well if impurities with similar contracture but larger molecular size; D increased with the increase of concentration and temperature, but the slope showed an inverse variation trend with the size of Xn. Slope almost showed an increase trend with the increase of Xn molecule size. With the elevation of temperature, slope presented a decline trend with the increase of Xn molecule size. Based on the basic principal of physical and chemical, related reasons were analyzed in detail.

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Funding

This work was supported by the Doctoral Program Funds of the Lanzhou University of Technology (Grant No. SB01200806), the Natural Science Foundation of China (Grant No. 51563015), and supercomputing center of Gansu province.

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Authors and Affiliations

  1. State Key Laboratory of Gansu Advanced Non-ferrous Metal Materials, Lanzhou University of Technology, Lanzhou, 730050, Gansu, China

    Ke Li, Zhenbin Chen, Dong Lei Liu & Xin Yu Zhang

  2. School of Material Science and Engineering, Lanzhou University of Technology, Lanzhou, 730050, Gansu, China

    Ke Li, Zhenbin Chen, Dong Lei Liu & Xin Yu Zhang

  3. Soft Matter and Molecular Biophysics Group, Department of Applied Physics, University of Santiago de Compostela, 15782, Santiago de Compostela, Spain

    Juan M. Ruso

  4. Guangzhou Key Laboratory for Surface Chemistry of Energy Materials, New Energy Research Institute, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou, 510006, China

    Zhenghua Tang

  5. Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, Guangdong Provincial Engineering and Technology Research Center for Environmental Risk Prevention and Emergency Disposal, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou, 510006, China

    Zhenghua Tang

  6. Department of Physics and Engineering, Frostburg State University, Frostburg, MD, 21532, USA

    Zhen Liu

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  1. Ke Li
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  2. Zhenbin Chen
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  3. Dong Lei Liu
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  4. Xin Yu Zhang
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Correspondence to Zhenbin Chen or Zhen Liu.

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Li, K., Chen, Z., Liu, D.L. et al. Effect of variable conditions on the adsorption selectivity of molecularly imprinted polymers. Adv Compos Hybrid Mater 1, 777–784 (2018). https://doi.org/10.1007/s42114-018-0064-z

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  • DOI: https://doi.org/10.1007/s42114-018-0064-z

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