Abstract
Factors which can have a detrimental effect on the corrosion performance of welded duplex stainless steel are discussed together with applicable countermeasures. The main focus is on pitting corrosion resistance on the root side and how this can be improved by adequate backing gas protection and post-weld cleaning (acid pickling). The positive effect of nitrogen in the shielding and backing gas on the austenite formation and pitting corrosion resistance of welds in the lean duplex stainless steel LDX 2101® (EN 1.4162, UNS S32101) is demonstrated. On the rootside, welding with nitrogen-based backing gas significantly increased the critical pitting resistance compared to welding with argon. The highest values, close to that of the base metal, were obtained using 90 % N2 + 10 % H2 as backing gas. The results are compared to the values reported in the literature and the differences between the ASTM G150 and ASTM G48 corrosion test methods highlighted.
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References
Johansson E, Prosek T (2009) Outokumpu corrosion handbook, 10th edn. Sandvikens Tryckeri, Sandviken
Tsuge H, Tarutani Y, Kudo T (1988) Corrosion 44(5):305–314.1
Pettersson C-O, Böllinghaus T, Kannengieser T (2007) Weld World 51, 7/8 79–106
Holmberg B, Bergqvist A (2008) Suitable corrosion test methods for stainless steel welded joints. Weld World 52, No. 3/4 17–21
Ogawa T, Koseki T (1989) Weld J 68(5):181s–191s
Gooch T.G. (1984) in Proceedings Duplex Stainless Steels ‘82, St. Louis, MO, ASM 573–602
Liljas M, Qvarfort R (1986) Proc. Duplex Stainless Steels ‘86, The Hague, NL, NIL 244-256/acom
Mundt R, Hoffmeister H (1985) Proc. Stainless Steels ‘84, Gothenburg, Sweden, CTH 315–322
Varol I, Baeslack WA III, Lippold JC (1992) Key Eng Mater 69–70:217–251
Hertzman S, Roberts W, Lindenmo M (1986) Proc. Duplex Stainless Steels ‘86, The Hague, NL, NIL 257–263
Hertzman S (2001) ISIJ Int 41(6):580–589
Hertzman S, Ferreira PJ, Brolund B (1997) Metall Mater Trans 28A(2):277–285
Jargelius-Pettersson RFA, Hertzman S, Szakalos P, Ferreira PJ (1995) Proc. Duplex Stainless Steels ‘94, Glasgow, Scotland, TWI, 2 461–472
Liou H-Y, Hsieh R-I, Tsai W-T (2002) Corros Sci 44(12):2841–2856
Omura T, Kushida T, Komizo Y (2000) Welding Int 14(4):257–260
Sridhar N, Kolts J (1987) Corrosion 43(11):646–651
Matsunaga H, Sato YS, Kokawa H, Kuwana T (1998) Sci Technol Weld Joi 3(5):225–232
Nilsson J-O (1992) Mater Sci Tech 8(8):685–700
Sridhar N, Flasche LH, Kolts J (1984) Mater Perform 23(12):52–55
Jonsson O, Liljas M, Stenvall P (1991) The role of nitrogen in longitudinal welding of tubing in duplex stainless steels, in: Proceedings of the Duplex Stainless Steels’ 91, vol. 1, Beaune, France, pp 461–468
Westin EM (2010) Weld World 54(11/12):R308–R321
Pettersson C-O, Fager S-Å (1994) Welding practice for the Sandvik stainless steels SAF 2304, SAF 2205 and SAF 2507, Sandvik Steel, S-811 81 Sandviken, Sweden, Phone +446 26–26 30 00, S-91-57-ENG, April 1994, Revised August 1995, Printed in Sweden, Icoprint ab, 15 pp. www.smt.sandvik.com
Blom K-J (1987) Improving properties of weld joints in duplex stainless steel by welding with shielding as containing nitrogen, Stainless Steels ‘87, York, Institute of Metals 123–125
Pettersson C-O, Holmquist M, Mårtensson C (1996) Proc. Stainless Steels ‘96, Dusseldorf/Neuss, 184–191
Westin EM, Serrander D (2012) Weld World 56(5/6):14pp
B. Josefsson (1991) Properties of welded joints in the super duplex stainless steel 2507, Proc. Stainless Steels ‘91, Chiba, ISIJ (1991) 1069–1076
Saggau R, Pries H, Finke M (2001) Z Metallkd 92(3):286–292
Vagn Hansen J, Nielsen TS, Aastrup P (1995) Proc. Duplex Stainless Steels ‘94, Glasgow, Scotland, TWI, 2, 13 pp
Westin EM (2010) Microstructure and properties of welds in the lean duplex stainless steel LDX 2101®, PhD Thesis, Royal Institute of Technology, Stockholm, Sweden, ISBN 978-91-7415-801-4
Solomon HD, Devine TM (1984) Proc. Duplex Stainless Steels ‘82, St. Louis, MO, ASM, 693–756
Charles J (1991) Proc. Duplex Stainless Steels ‘91, Beaune, France, 1, 151–168
Karlsson L, Ryen L, Pak S (1995) Weld J 74(1):28s–40s
Karlsson L (1999) Weld World 43(5):20–41
Azuma S, Miyuki H, Murayama J, Kudo T (1990) Corros Eng 39:667–676
Ödegård L, Fager SA (1991) Duplex stainless steels ‘91, Beaune, France. Editions de Physique 1:451–460
Tuthill AH, Avery R (1992) Adv Mater Process 142(6):34–38
Coates GE (1991) Mater Perform 29(8):61–65
Ericsson R, Schön L, Wallén B (1978) Effect of some oxide removal treatments on the corrosion resistance of 316 stainless steel, Proc. Scand. Corr. Congress, NKM 8, Helsinki, 321–329
ASTM G48-03 (2009) Standard test methods for pitting and crevice corrosion resistance of stainless steels and related alloys by use of ferric chloride solution. ASTM International, West Conshohocken, 11 pp
ASTM A 923-08 (2008) Standard test methods for detecting detrimental intermetallic phase in duplex austenitic/ferritic stainless steels. ASTM International, West Conshohocken, 10 pp
NORSOK Standard M-601 Edition 5, April 2008, Welding and inspection of piping, Standards Norway, 20 pp
NORSOK Standard M-630 Edition 5, September 2010, Material data sheets and element data sheets for piping, Standards Norway, 133 pp
Holloway GB, Zhang Z, Gough PC (2010) Corrosion testing of duplex and superduplex weld metal, Beaune Duplex 2010, 10 pp
Jonsson JY, Canderyd C, Pettersson R (2011) Optimisation of a qualification test method for lean duplex stainless steels, in Proc. 7th European Stainless Steel Conference Como, Italy, 21–23 September 2011
Pettersson R, Jonsson JY, Canderyd C, Arnvig P-E(2012) Qualification testing of lean duplex stainless steels for the process industry, in Proc. NACE Corrosion 2012, Salt Lake City, 11–15 March 2012
ASTM G150-99 (2004) Electrochemical critical pitting temperature testing of stainless steels. ASTM International, West Conshohocken, 13 pp
ISO 17864:2005(E) Corrosion of metals and alloys—determination of the critical pitting temperature under potentiostatic control, ISO copyright office, Geneva, Switzerland, 20 pp
Qvarfort R (1988) Corros Sci 28(2):135–140
Qvarfort R (1989) Corros Sci 29(8):987–993
Walker RA, Gooch TG (1991) Brit Corros J. ASTM International, West Conshohocken, 26(1):51–59
Miyuki T, Kudo, M. Koso, M. Miura, T. Moroishi, Proc. Duplex Stainless Steels ‘82, St Louis, MO, ASM (1984) 95–112
Holmberg B (1997) Stainless steel world 9; 2, 28–33/ACOM 13 (1997) 3 1–7
Hertzman S, Pettersson R, Blom K, Kivineva E, Eriksson J (1996) ISIJ Int 36(7):968–976
Rabensteiner G, Tosch J (1994) The specific effect of nitrogen in the fabrication of a super duplex stainless steel weld, duplex stainless steel ‘94, vol. 2, Paper 44, 11 pp
Hessenbrügge H, Poweleit B, Scheller W (1999) Schweißtechnische Verarbeitung von Superduplex- und anderen hochlegierten Werkstoffen. DVS 204:51–59
ASTM G 61-86 (2009) Standard test method for conducting cyclic potentiodynamic polarization measurements for localized corrosion susceptibility of iron-, nickel-, cobalt-based alloys. ASTM International, West Conshohocken, 5 pp
Johansson MM, Westin EM, Oliver J, Pettersson RFA (2011) Weld World 55(9/10):19–27
Posch G, Tosch J (2005) Weld World 49(9/10):58–67
Saggau R (2005) Untersuchungen zum Einfluss gelber Anlauffarben auf das Lochkorrosionsverhalten geschweißter nichtrostender Stähle, PhD Dissertation, Braunschweig Technical University, 2005. Shaker Verlag, Aachen, 188 pp
Acknowledgments
Henrik Ahrman and Hans-Erik Peth at Outokumpu Avesta Research Centre are acknowledged for mechanized welding and corrosion testing, respectively, and Ole Öhrn at Böhler Welding Group Nordic AB for the manual welding.
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Doc. IIW-2358, recommended for publication by Commission II “Arc Welding and Filler Metals.”
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Westin, E.M., Johansson, M.M. & Pettersson, R.F.A. Effect of nitrogen-containing shielding and backing gas on the pitting corrosion resistance of welded lean duplex stainless steel LDX 2101® (EN 1.4162, UNS S32101). Weld World 57, 467–476 (2013). https://doi.org/10.1007/s40194-013-0046-2
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DOI: https://doi.org/10.1007/s40194-013-0046-2