Skip to main content
Log in

Effect of nitrogen-containing shielding and backing gas on the pitting corrosion resistance of welded lean duplex stainless steel LDX 2101® (EN 1.4162, UNS S32101)

  • Research Paper
  • Published:
Welding in the World Aims and scope Submit manuscript

Abstract

Factors which can have a detrimental effect on the corrosion performance of welded duplex stainless steel are discussed together with applicable countermeasures. The main focus is on pitting corrosion resistance on the root side and how this can be improved by adequate backing gas protection and post-weld cleaning (acid pickling). The positive effect of nitrogen in the shielding and backing gas on the austenite formation and pitting corrosion resistance of welds in the lean duplex stainless steel LDX 2101® (EN 1.4162, UNS S32101) is demonstrated. On the rootside, welding with nitrogen-based backing gas significantly increased the critical pitting resistance compared to welding with argon. The highest values, close to that of the base metal, were obtained using 90 % N2 + 10 % H2 as backing gas. The results are compared to the values reported in the literature and the differences between the ASTM G150 and ASTM G48 corrosion test methods highlighted.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Johansson E, Prosek T (2009) Outokumpu corrosion handbook, 10th edn. Sandvikens Tryckeri, Sandviken

    Google Scholar 

  2. Tsuge H, Tarutani Y, Kudo T (1988) Corrosion 44(5):305–314.1

    Article  CAS  Google Scholar 

  3. Pettersson C-O, Böllinghaus T, Kannengieser T (2007) Weld World 51, 7/8 79–106

    Google Scholar 

  4. Holmberg B, Bergqvist A (2008) Suitable corrosion test methods for stainless steel welded joints. Weld World 52, No. 3/4 17–21

  5. Ogawa T, Koseki T (1989) Weld J 68(5):181s–191s

    Google Scholar 

  6. Gooch T.G. (1984) in Proceedings Duplex Stainless Steels ‘82, St. Louis, MO, ASM 573–602

  7. Liljas M, Qvarfort R (1986) Proc. Duplex Stainless Steels ‘86, The Hague, NL, NIL 244-256/acom

  8. Mundt R, Hoffmeister H (1985) Proc. Stainless Steels ‘84, Gothenburg, Sweden, CTH 315–322

  9. Varol I, Baeslack WA III, Lippold JC (1992) Key Eng Mater 69–70:217–251

    Article  Google Scholar 

  10. Hertzman S, Roberts W, Lindenmo M (1986) Proc. Duplex Stainless Steels ‘86, The Hague, NL, NIL 257–263

  11. Hertzman S (2001) ISIJ Int 41(6):580–589

    Article  CAS  Google Scholar 

  12. Hertzman S, Ferreira PJ, Brolund B (1997) Metall Mater Trans 28A(2):277–285

    Article  CAS  Google Scholar 

  13. Jargelius-Pettersson RFA, Hertzman S, Szakalos P, Ferreira PJ (1995) Proc. Duplex Stainless Steels ‘94, Glasgow, Scotland, TWI, 2 461–472

  14. Liou H-Y, Hsieh R-I, Tsai W-T (2002) Corros Sci 44(12):2841–2856

    Google Scholar 

  15. Omura T, Kushida T, Komizo Y (2000) Welding Int 14(4):257–260

    Google Scholar 

  16. Sridhar N, Kolts J (1987) Corrosion 43(11):646–651

    Article  CAS  Google Scholar 

  17. Matsunaga H, Sato YS, Kokawa H, Kuwana T (1998) Sci Technol Weld Joi 3(5):225–232

    Article  CAS  Google Scholar 

  18. Nilsson J-O (1992) Mater Sci Tech 8(8):685–700

    CAS  Google Scholar 

  19. Sridhar N, Flasche LH, Kolts J (1984) Mater Perform 23(12):52–55

    CAS  Google Scholar 

  20. Jonsson O, Liljas M, Stenvall P (1991) The role of nitrogen in longitudinal welding of tubing in duplex stainless steels, in: Proceedings of the Duplex Stainless Steels’ 91, vol. 1, Beaune, France, pp 461–468

  21. Westin EM (2010) Weld World 54(11/12):R308–R321

    Article  CAS  Google Scholar 

  22. Pettersson C-O, Fager S-Å (1994) Welding practice for the Sandvik stainless steels SAF 2304, SAF 2205 and SAF 2507, Sandvik Steel, S-811 81 Sandviken, Sweden, Phone +446 26–26 30 00, S-91-57-ENG, April 1994, Revised August 1995, Printed in Sweden, Icoprint ab, 15 pp. www.smt.sandvik.com

  23. Blom K-J (1987) Improving properties of weld joints in duplex stainless steel by welding with shielding as containing nitrogen, Stainless Steels ‘87, York, Institute of Metals 123–125

  24. Pettersson C-O, Holmquist M, Mårtensson C (1996) Proc. Stainless Steels ‘96, Dusseldorf/Neuss, 184–191

  25. Westin EM, Serrander D (2012) Weld World 56(5/6):14pp

    Google Scholar 

  26. B. Josefsson (1991) Properties of welded joints in the super duplex stainless steel 2507, Proc. Stainless Steels ‘91, Chiba, ISIJ (1991) 1069–1076

  27. Saggau R, Pries H, Finke M (2001) Z Metallkd 92(3):286–292

    CAS  Google Scholar 

  28. Vagn Hansen J, Nielsen TS, Aastrup P (1995) Proc. Duplex Stainless Steels ‘94, Glasgow, Scotland, TWI, 2, 13 pp

  29. Westin EM (2010) Microstructure and properties of welds in the lean duplex stainless steel LDX 2101®, PhD Thesis, Royal Institute of Technology, Stockholm, Sweden, ISBN 978-91-7415-801-4

  30. Solomon HD, Devine TM (1984) Proc. Duplex Stainless Steels ‘82, St. Louis, MO, ASM, 693–756

  31. Charles J (1991) Proc. Duplex Stainless Steels ‘91, Beaune, France, 1, 151–168

  32. Karlsson L, Ryen L, Pak S (1995) Weld J 74(1):28s–40s

    Google Scholar 

  33. Karlsson L (1999) Weld World 43(5):20–41

    CAS  Google Scholar 

  34. Azuma S, Miyuki H, Murayama J, Kudo T (1990) Corros Eng 39:667–676

    Google Scholar 

  35. Ödegård L, Fager SA (1991) Duplex stainless steels ‘91, Beaune, France. Editions de Physique 1:451–460

    Google Scholar 

  36. Tuthill AH, Avery R (1992) Adv Mater Process 142(6):34–38

    CAS  Google Scholar 

  37. Coates GE (1991) Mater Perform 29(8):61–65

    Google Scholar 

  38. Ericsson R, Schön L, Wallén B (1978) Effect of some oxide removal treatments on the corrosion resistance of 316 stainless steel, Proc. Scand. Corr. Congress, NKM 8, Helsinki, 321–329

  39. ASTM G48-03 (2009) Standard test methods for pitting and crevice corrosion resistance of stainless steels and related alloys by use of ferric chloride solution. ASTM International, West Conshohocken, 11 pp

    Google Scholar 

  40. ASTM A 923-08 (2008) Standard test methods for detecting detrimental intermetallic phase in duplex austenitic/ferritic stainless steels. ASTM International, West Conshohocken, 10 pp

    Google Scholar 

  41. NORSOK Standard M-601 Edition 5, April 2008, Welding and inspection of piping, Standards Norway, 20 pp

  42. NORSOK Standard M-630 Edition 5, September 2010, Material data sheets and element data sheets for piping, Standards Norway, 133 pp

  43. Holloway GB, Zhang Z, Gough PC (2010) Corrosion testing of duplex and superduplex weld metal, Beaune Duplex 2010, 10 pp

  44. Jonsson JY, Canderyd C, Pettersson R (2011) Optimisation of a qualification test method for lean duplex stainless steels, in Proc. 7th European Stainless Steel Conference Como, Italy, 21–23 September 2011

  45. Pettersson R, Jonsson JY, Canderyd C, Arnvig P-E(2012) Qualification testing of lean duplex stainless steels for the process industry, in Proc. NACE Corrosion 2012, Salt Lake City, 11–15 March 2012

  46. ASTM G150-99 (2004) Electrochemical critical pitting temperature testing of stainless steels. ASTM International, West Conshohocken, 13 pp

    Google Scholar 

  47. ISO 17864:2005(E) Corrosion of metals and alloys—determination of the critical pitting temperature under potentiostatic control, ISO copyright office, Geneva, Switzerland, 20 pp

  48. Qvarfort R (1988) Corros Sci 28(2):135–140

    Article  CAS  Google Scholar 

  49. Qvarfort R (1989) Corros Sci 29(8):987–993

    Article  CAS  Google Scholar 

  50. Walker RA, Gooch TG (1991) Brit Corros J. ASTM International, West Conshohocken, 26(1):51–59

  51. Miyuki T, Kudo, M. Koso, M. Miura, T. Moroishi, Proc. Duplex Stainless Steels ‘82, St Louis, MO, ASM (1984) 95–112

  52. Holmberg B (1997) Stainless steel world 9; 2, 28–33/ACOM 13 (1997) 3 1–7

  53. Hertzman S, Pettersson R, Blom K, Kivineva E, Eriksson J (1996) ISIJ Int 36(7):968–976

    Article  CAS  Google Scholar 

  54. Rabensteiner G, Tosch J (1994) The specific effect of nitrogen in the fabrication of a super duplex stainless steel weld, duplex stainless steel ‘94, vol. 2, Paper 44, 11 pp

  55. Hessenbrügge H, Poweleit B, Scheller W (1999) Schweißtechnische Verarbeitung von Superduplex- und anderen hochlegierten Werkstoffen. DVS 204:51–59

    Google Scholar 

  56. ASTM G 61-86 (2009) Standard test method for conducting cyclic potentiodynamic polarization measurements for localized corrosion susceptibility of iron-, nickel-, cobalt-based alloys. ASTM International, West Conshohocken, 5 pp

  57. Johansson MM, Westin EM, Oliver J, Pettersson RFA (2011) Weld World 55(9/10):19–27

    Article  CAS  Google Scholar 

  58. Posch G, Tosch J (2005) Weld World 49(9/10):58–67

    Article  CAS  Google Scholar 

  59. Saggau R (2005) Untersuchungen zum Einfluss gelber Anlauffarben auf das Lochkorrosionsverhalten geschweißter nichtrostender Stähle, PhD Dissertation, Braunschweig Technical University, 2005. Shaker Verlag, Aachen, 188 pp

    Google Scholar 

Download references

Acknowledgments

Henrik Ahrman and Hans-Erik Peth at Outokumpu Avesta Research Centre are acknowledged for mechanized welding and corrosion testing, respectively, and Ole Öhrn at Böhler Welding Group Nordic AB for the manual welding.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. M. Westin.

Additional information

Doc. IIW-2358, recommended for publication by Commission II “Arc Welding and Filler Metals.”

Rights and permissions

Reprints and permissions

About this article

Cite this article

Westin, E.M., Johansson, M.M. & Pettersson, R.F.A. Effect of nitrogen-containing shielding and backing gas on the pitting corrosion resistance of welded lean duplex stainless steel LDX 2101® (EN 1.4162, UNS S32101). Weld World 57, 467–476 (2013). https://doi.org/10.1007/s40194-013-0046-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40194-013-0046-2

Keywords

Navigation