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Valorization of Printed Circuit Boards from Waste Electrical and Electronic Equipment by Pyrolysis

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Abstract

Waste electrical and electronic equipment waste generated in the European Union (EU27) has been identified as one of the fastest growing waste streams in the EU, such that by 2020 annual arisings of waste electrical and electronic equipment will be 12.3 million tonnes. The EU have introduced the Waste Electrical and Electronic Equipment (WEEE) Directive which aims to promote the re-use, recycling and other forms of recovery of electrical and electronic waste. Printed circuit boards represent a particular category of WEEE that has attracted wide attention for treatment by pyrolysis technology. Printed circuit boards are composed of mainly a glass fibre reinforced polymer resin board onto which are manufactured components containing a wide variety of metals such as copper, iron, tin and lead. But also a range of very high value metals including gold, silver, and palladium. In this paper, the use of pyrolysis to treat waste printed circuit boards as a means to recover valuable materials, including the metals, an oil and gas product from the polymeric resin and glass fibre is reviewed.

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References

  1. EC Review of Directive 2002/96/EC: Waste Electrical and Electronic Equipment (WEEE). Final Report (Contract No. 07010401/2006/442493/ETU/G4 ENV.G.4/ETU/2006/0032). Brussels, August (2007)

  2. Kang, H.Y., Schoenung, J.M.: Electronic waste recycling: a review of US infrastructure and technology options. Resour. Conserv. Recycl. 45, 368–400 (2005)

    Article  Google Scholar 

  3. EC Directive 2002/96/EC: Waste Electrical and Electronic Equipment, L27/34. European Union, Brussels (2003)

  4. EC Directive 2002/95/EC: Restriction of the Use of Certain Hazardous Substances in Electrical and Electronic Equipment. European Union, Brussels (2003)

  5. EC Report 30-CE-0095296/00-09: Study on RoHS and WEEE Directives. European Commission, Brussels (2008)

  6. Barba-Gutierrez, Y., Adenso-Diaz, B., Hopp, M.: An analysis of some environmental consequences of European electrical and electronic waste regulation. Resour. Conserv. Recycl. 52, 481–495 (2008)

    Article  Google Scholar 

  7. Chancerel, P., Rotter, S.: Recycling-orientated characterization of small waste electrical and electronic equipment. Waste Manag. 29, 2336–2352 (2009)

    Article  Google Scholar 

  8. Goosey, M., Kellner, R.: A Scoping Study: End-of-Life Printed Circuit Boards. Intellect and the Department of Trade and Industry, London (2002)

    Google Scholar 

  9. Hall, W.J., Williams, P.T.: Separation and recovery of materials from scrap printed circuit boards. Resour. Conserv. Recycl. 51, 691–709 (2007)

    Article  Google Scholar 

  10. Li, H., Yu, L., Sheng, G., Fu, J., Peng, P.A.: Severe PCDD/F and PBDD/F pollution in air around an electronic waste dismantling area in China. Environ. Sci. Technol. 41, 5641–5646 (2007)

    Article  Google Scholar 

  11. Menad, N., Bjorkman, B., Allain, E.G.: Combustion of plastics contained in electric and electronic scrap. Resour. Conserv. Recycl. 24, 65–85 (1998)

    Article  Google Scholar 

  12. Tasaki, T., Takasuga, T., Osaka, M., Sakai, S.I.: Substance flow analysis of brominated flame retardants and related compounds in waste TV sets in Japan. Waste Manag. 24, 571–580 (2004)

    Article  Google Scholar 

  13. Grause, G., Furusawa, M., Okuwaki, A., Yoshioka, T.: Pyrolysis of tetrabromobisphenol-A containing paper laminated printed circuit boards. Chemosphere 71, 872–878 (2008)

    Article  Google Scholar 

  14. Buekens, A.: Chapter 1: Introduction. In: Schiers, J., Kaminsky, W. (eds.) Feedstock Recycling and Pyrolysis of Waste Plastics, pp. 285–314. Wiley, Chichester (2006)

    Google Scholar 

  15. Das, A., Vidyadhar, A., Mehrotra, S.P.: A novel flowsheet for the recovery of metal values from waste printed circuit boards. Resour. Conserv. Recycl. 53, 464–469 (2009)

    Article  Google Scholar 

  16. Ogunniyi, I.O., Vermaak, M.K.G., Groot, D.R.: Chemical composition and liberation characterization of printed circuit board comminution fines for beneficiation investigations. Waste Manag. 29, 2140–2146 (2009)

    Article  Google Scholar 

  17. Schlummer, M., Gruber, L., Maurer, A., Wolz, G., van Eldik, R.: Characterisation of polymer fractions from waste electrical and electronic equipment (WEEE) and implications for waste management. Chemosphere 67, 1866–1876 (2007)

    Article  Google Scholar 

  18. Li, J., Shrivastava, P., Gao, Z., Zhang, H.C.: Printed circuit board recycling: a state-of-the-art survey. IEEE Trans. Electron. Packag. Manuf. 27, 33–42 (2004)

    Article  Google Scholar 

  19. Jawitz, M.W.: Printed Circuit Board Materials Handbook. McGraw-Hill, New York (1997)

    Google Scholar 

  20. Eswaraiah, C., Kavitha, T., Vidyasagar, S., Narayanan, S.S.: Classification of metals and plastics from printed circuit boards (PCB) using air classifier. Chem. Eng. Proc. 47, 565–576 (2008)

    Google Scholar 

  21. Park, Y.J., Fray, D.J.: Recovery of high purity precious metals from printed circuit boards. J. Hazard. Mater. 164, 1152–1158 (2009)

    Article  Google Scholar 

  22. Rahman, F., Langford, K.H., Scrimshaw, M.D., Lester, J.N.: Polybrominated diphenyl ether (PBDE) flame retardants. Sci. Total Environ. 275, 1–17 (2001)

    Article  Google Scholar 

  23. Guo, J., Guo, J., Xu, Z.: Recycling of non-metallic fractions from waste printed circuit boards: a review. J. Hazard. Mater. 168, 567–590 (2009)

    Article  Google Scholar 

  24. Molto, J., Font, R., Galvez, A., Conesa, J.A.: Pyrolysis and combustion of electronic wastes. J. Anal. Appl. Pyrolysis 84, 68–78 (2009)

    Article  Google Scholar 

  25. Chien, Y.C., Wang, H.P., Lin, K.S., Huang, Y.J., Yang, Y.W.: Fate of bromine in pyrolysis of printed circuit board wastes. Chemosphere 40, 383–387 (2000)

    Article  Google Scholar 

  26. Barontini, F., Cozzani, V.: Formation of hydrogen bromide and organobrominated compounds in the thermal degradation of electronic boards. J. Anal. Appl. Pyrolysis 77, 41–55 (2006)

    Article  Google Scholar 

  27. Blazso, M., Czegeny, Z., Csoma, C.: Pyrolysis and debromination of flame retarded polymers of electronic scrap studied by analytical pyrolysis. J. Anal. Appl. Pyrolysis 64, 249–261 (2002)

    Article  Google Scholar 

  28. Lee, C.H., Chang, C.T., Fan, K.S., Chang, T.C.: An overview of recycling and treatment of scrap computers. J. Hazard. Mater. B114, 93–100 (2004)

    Article  Google Scholar 

  29. Kinoshita, T., Akita, S., Kobayashi, N., Nii, S., Kawaizumi, F., Takahashi, K.: Metal recovery from un-mounted printed wiring boards via hydrometallurgical processing. Hydrometallurgy 69, 73–79 (2003)

    Article  Google Scholar 

  30. Zhang, S., Forssberg, E.: Mechanical separation-orientated characterisation of electronic scrap. Resour. Conserv. Recycl. 21, 247–269 (1997)

    Article  Google Scholar 

  31. Zhang, S., Forssberg, E.: Intelligent liberation and classification of electronic scrap. Powder Technol. 105, 295–301 (1999)

    Article  Google Scholar 

  32. Cui, J., Forssberg, E.: Mechanical recycling of waste electric and electronic equipment: a review. J. Hazard. Mater. B99, 243–263 (2003)

    Article  Google Scholar 

  33. Williams, P.T.: Waste Treatment and Disposal, 2nd edn. Wiley, Chichester (2005)

    Google Scholar 

  34. de Marco, I., Caballero, B.M., Chomon, M.J., Laresgoiti, M.F., Torres, A., Fernandez, G., Arnaiz, S.: Pyrolysis of electrical and electronic wastes. J. Anal. Appl. Pyrolysis 82, 179–183 (2008)

    Article  Google Scholar 

  35. Jie, G., Li, Y.S., Lu, M.X.: Product characterisation of waste printed circuit board by pyrolysis. J. Anal. Appl. Pyrolysis 83, 185–189 (2008)

    Article  Google Scholar 

  36. Vasile, C., Brebu, M.A., Totolin, M., Yanik, J., Karayildirim, T., Darie, H.: Feedstock recycling from the printed circuit boards of used computers. Energy Fuel 22, 1658–1665 (2008)

    Article  Google Scholar 

  37. Chiang, H.L., Lin, K.H., Lai, M.H., Chen, T.C., Ma, S.Y.: Pyrolysis characteristics of integrated circuit boards at various particle sizes and temperatures. J. Hazard. Mater. 149, 151–159 (2007)

    Article  Google Scholar 

  38. Kowalska, E., Radomska, J., Konarski, P., Diduszko, R., Oszczudlowski, J., Opalinska, T., Wiech, M., Duszyc, Z.: Thermogravimetric investigation of wastes from electrical and electronic equipment (WEEE). J. Therm. Anal. Calorim. 86, 137–140 (2006)

    Article  Google Scholar 

  39. Antonetti, P., Flitris, Y., Flamant, G., Hellio, H., Gauthier, D., Granier, B.: Degradation products of the process of thermal recovery of copper from lamina scraps in lab-scale fluidized bed reactor. J. Hazard. Mater. B108, 199–206 (2004)

    Article  Google Scholar 

  40. Scharnhorst, W., Ludwig, C., Wochele, J., Jolliet, O.: Heavy metal partitioning from electronic scrap during thermal end-of-life treatment. Sci. Total Environ. 373, 576–584 (2007)

    Article  Google Scholar 

  41. Williams, P.T., Williams, E.A.: Recycling plastic waste by pyrolysis. J. Inst. Energy 71, 81–93 (1998)

    Google Scholar 

  42. Williams, P.T., Williams, E.A.: Interaction of plastics in mixed plastics pyrolysis. Energy Fuel 13, 188–196 (1999)

    Article  Google Scholar 

  43. Liu, Y., Qian, J., Wang, J.: Pyrolysis of polystyrene waste in a fluidised bed reactor to obtain styrene monomer and gasoline fraction. Fuel Proc. Technol. 63, 45–55 (2000)

    Article  Google Scholar 

  44. de Marco, I., Caballero, B., Torres, A., Laresgoiti, M.F., Chomon, M.J., Cabrero, M.A.: Recycling polymeric wastes by means of pyrolysis. J. Chem. Technol. Biotechnol. 77, 817–824 (2002)

    Article  Google Scholar 

  45. Schiers, J., Kaminsky, W.: Feedstock Recycling and Pyrolysis of Waste Plastics. Wiley, Chichester (2006)

    Book  Google Scholar 

  46. Balabanovich, A.I., Hornung, A., Merz, D., Seffert, H.: The effect of a curing agent on the thermal degradation of fire retardant brominated epoxy resins. Polym. Degrad. Stab. 85, 713–723 (2004)

    Article  Google Scholar 

  47. Luda, M.P., Balabanovich, A.I., Zanetti, M., Guaratto, D.: Thermal decomposition of fire retardant brominated epoxy resins cured with different nitrogen containing hardeners. Polym. Degrad. Stab. 92, 1088–1100 (2007)

    Article  Google Scholar 

  48. Bradna, P., Zima, J.: The use of pyrolysis-gas chromatography mass-spectroscopy in the analysis of cured polyfunctional epoxy-resins. J. Anal. Appl. Pyrolysis 21, 207–220 (1991)

    Article  Google Scholar 

  49. Blazso, M.: Thermal decomposition of polymers modified by catalytic effects of copper and iron chlorides. J. Anal. Appl. Pyrolysis 51, 73–88 (1999)

    Article  Google Scholar 

  50. Sivalingam, G., Madras, G.: Effect of metal oxides/chlorides on the thermal degradation of poly(vinyl chloride), poly(bisphenol A carbonate), and their blends. Ind. Eng. Chem. Res. 43, 7716–7722 (2004)

    Article  Google Scholar 

  51. Barontini, F., Marsanich, K., Petarca, L., Cozzani, V.: Thermal degradation and decomposition products of electronic boards containing BFRs. Ind. Eng. Chem. Res. 44, 4186–4199 (2005)

    Article  Google Scholar 

  52. Lassen, C., Locke, S.: Brominated Flame Retardant Substance Flow Analysis and Assessment of Alternatives. Danish Environmental Protection Agency, Copenhagen (1999)

    Google Scholar 

  53. Luda, M.P., Balabanovich, A.I., Camino, G.: Thermal decomposition of fire retardant brominated epoxy resins. J. Anal. Appl. Pyrolysis 65, 25–40 (2002)

    Article  Google Scholar 

  54. Balabanovich, A.L., Luda, M.P., Operti, L.: GC/MS identification of pyrolysis products from fire-retardant brominated epoxy resin. J. Fire Sci. 23, 227–245 (2005)

    Article  Google Scholar 

  55. Vasile, C., Brebu, M.A., Karayildirim, T., Yanik, J., Darie, H.: Feedstock recycling from plastics and thermosets fractions of used computers. II Pyrolysis oil upgrading. Fuel 86, 477–485 (2007)

    Article  Google Scholar 

  56. Bockhorn, H., Hornung, A., Hornung, U., Jakobstromoer, P., Kraus, M.: Dehydrochlorination of plastic mixtures. J. Anal. Appl. Pyrolysis 49, 97–106 (1999)

    Article  Google Scholar 

  57. Brebu, M., Bhaskar, T., Murai, K., Muto, A., Sakata, Y., Uddin, M.A.: Thermal degradation of PE and PS mixed with ABS-Br and debromination of pyrolysis oil by Fe and Ca-based catalysts. Polym. Degrad. Stab. 84, 459–467 (2004)

    Article  Google Scholar 

  58. Brebu, M., Bhaskar, T., Murai, K., Muto, A., Sakata, Y., Uddin, M.A.: Removal of nitrogen, bromine, and chlorine from PP/PE/PS/PVC/ABS-Br pyrolysis liquid products using Fe- and Ca-based catalysts. Polym. Degrad. Stab. 87, 225–230 (2005)

    Article  Google Scholar 

  59. Bhaskar, T., Kaneko, J., Muto, A., Sakata, Y., Jakab, E., Matsui, T., Uddin, M.A.: Pyrolysis studies of PP/PE/PS/PVC/HIPS-Br plastics mixed with PET and dehalogenation (Br, Cl) of the liquid products. J. Anal. Appl. Pyrolysis 72, 27–33 (2004)

    Article  Google Scholar 

  60. Brebu, M., Bhaskar, T., Muto, A., Sakata, Y.: Alkaline hydrothermal treatment of brominated high impact polystyrene (HIPS-Br) for bromine and bromine-free plastic recovery. Chemosphere 64, 1021–1025 (2006)

    Article  Google Scholar 

  61. Brebu, M., Jakab, E., Sakata, Y.: Effect of flame retardants and Sb2O3 synergist on the thermal decomposition of high-impact polystyrene and on its debromination by ammonia treatment. J. Anal. Appl. Pyrolysis 79, 346–352 (2007)

    Article  Google Scholar 

  62. Luda, M.P., Euringer, N., Moratti, U., Zanetti, M.: WEEE recycling: pyrolysis of fire retardant model polymers. Waste Manag. 25, 203–208 (2005)

    Article  Google Scholar 

  63. Blazso, M., Czegeny, Z.: Catalytic destruction of brominated aromatic compounds studied in a catalyst microbed coupled to gas chromatography/mass spectrometry. J. Chromatogr. A 1130, 91–96 (2006)

    Article  Google Scholar 

  64. Hall, W.J., Williams, P.T.: Removal of organobromine compounds from the pyrolysis oils of flame retarded plastics using zeolite catalysts. J. Anal. Appl. Pyrolysis 81, 139–147 (2008)

    Article  Google Scholar 

  65. Mitan, N.M.M., Brebu, M., Bhaskar, T., Muto, A., Sakata, Y.: Individual and simultaneous degradation of brominated high impact polystyrene and brominated acrylonitrile-butadiene-styrene and removal of heteroelements (Br, N and O) from degradation oil by multiphase catalytic systems. J. Mater. Cycles Waste Manag. 9, 56–61 (2007)

    Article  Google Scholar 

  66. Jakab, E., Uddin, M.A., Bhaskar, T., Sakata, Y.: Thermal decomposition of flame-retarded high-impact polystyrene. J. Anal. Appl. Pyrolysis 68, 83–99 (2003)

    Article  Google Scholar 

  67. Mitan, N.M.M., Bhaskar, T., Hall, W.J., Muto, A., Williams, P.T., Sakata, Y.: Effect of decabromodiphenyl ether and antimony trioxide on controlled pyrolysis of high-impact polystyrene mixed with polyolefins. Chemosphere 72, 1073–1079 (2008)

    Article  Google Scholar 

  68. Hall, W.J., Bhaskar, T., Mitan, N.M.M., Muto, A., Sakata, Y., Williams, P.T.: Pyrolysis of waste electrical and electronic equipment: effect of antimony trioxide on the pyrolysis of styrenic polymers. Environ. Technol. 28, 1045–1054 (2007)

    Article  Google Scholar 

  69. Iji, M., Kiuchi, Y.: Flame resistant glass-epoxy printed wiring boards with no halogen or phosphorus compounds. J. Mater. Sci. Mater. Electron. 15, 175–182 (2004)

    Article  Google Scholar 

  70. Fukushima, K., Yonezawa, M., Rengakuji, S., Nakamura, Y., Ono, S., Yoshimura, T., Morita, H., Shimasaki, C.: Pyrolysis of triphenyl (diphenoxyphosphinyl)phosphorimidate. J. Anal. Appl. Pyrolysis 45, 41–58 (1998)

    Article  Google Scholar 

  71. Shimasaki, C., Muto, Y., Takashima, N., Tsukurimichi, E., Yoshimura, T., Hasegawa, K.: Pyrolysis of tetraphenyl imidodiphosphate. J. Anal. Appl. Pyrolysis 23, 217–227 (1992)

    Article  Google Scholar 

  72. de Marco, I., Legretta, J.A., Laresgoiti, M.F., Torres, A., Cambra, J.F., Chomon, M.J., Caballero, B., Gondra, K.: Recycling of pyrolysis products of an SMC. J. Chem. Technol. Biotechnol. 69, 187–192 (1997)

    Article  Google Scholar 

  73. Cunliffe, A.M., Williams, P.T.: Characterisation of products from the recycling of glass fibre reinforced polyester waste by pyrolysis. Fuel 82, 2223–2230 (2003)

    Article  Google Scholar 

  74. Williams, P.T., Cunliffe, A.M., Jones, N.: Recovery of value added products from the pyrolytic recycling of glass-fibre-reinforced composite plastic waste. J. Energy Inst. 78, 51–61 (2005)

    Article  Google Scholar 

  75. Cunliffe, A.M., Jones, N., Williams, P.T.: Recycling of fibre-reinforced polymeric waste by pyrolysis: thermo-gravimetric and bench-scale investigations. J. Anal. Appl. Pyrolysis 70, 315–338 (2003)

    Article  Google Scholar 

  76. Zheng, Y., Shen, Z., Ma, S., Cai, C., Zhao, Z., Xing, Y.: A novel approach to recycling of glass fibres from nonmetal materials of printed circuit boards. J. Hazard. Mater. 170, 978–982 (2009)

    Article  Google Scholar 

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Williams, P.T. Valorization of Printed Circuit Boards from Waste Electrical and Electronic Equipment by Pyrolysis. Waste Biomass Valor 1, 107–120 (2010). https://doi.org/10.1007/s12649-009-9003-0

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