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Organic–inorganic bismuth (III)-based material: A lead-free, air-stable and solution-processable light-absorber beyond organolead perovskites

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Abstract

Methylammonium bismuth (III) iodide single crystals and films have been developed and investigated. We have further presented the first demonstration of using this organic–inorganic bismuth-based material to replace lead/tin-based perovskite materials in solution-processable solar cells. The organic–inorganic bismuth-based material has advantages of non-toxicity, ambient stability, and low-temperature solution-processability, which provides a promising solution to address the toxicity and stability challenges in organolead- and organotin-based perovskite solar cells. We also demonstrated that trivalent metal cation-based organic–inorganic hybrid materials can exhibit photovoltaic effect, which may inspire more research work on developing and applying organic-inorganic hybrid materials beyond divalent metal cations (Pb (II) and Sn (II)) for solar energy applications.

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Authors and Affiliations

  1. Nanomaterials Centre, School of Chemical Engineering and AIBN, The University of Queensland, St Lucia, Brisbane, QLD, 4072, Australia

    Miaoqiang Lyu, Jung-Ho Yun, Meng Zhang, Qiong Wang & Lianzhou Wang

  2. School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, Brisbane, QLD, 4001, Australia

    Molang Cai, Yalong Jiao, Aijun Du & Hongxia Wang

  3. School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, 4072, Australia

    Paul V. Bernhardt

  4. Advanced Carbon Division, Institute of Metal Research Chinese Academy of Sciences (IMR CAS), 72 Wenhua Road, Shenyang, 110016, China

    Gang Liu

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  1. Miaoqiang Lyu
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  2. Jung-Ho Yun
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  3. Molang Cai
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  6. Meng Zhang
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  7. Qiong Wang
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  9. Hongxia Wang
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  10. Gang Liu
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  11. Lianzhou Wang
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Correspondence to Lianzhou Wang.

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Lyu, M., Yun, JH., Cai, M. et al. Organic–inorganic bismuth (III)-based material: A lead-free, air-stable and solution-processable light-absorber beyond organolead perovskites. Nano Res. 9, 692–702 (2016). https://doi.org/10.1007/s12274-015-0948-y

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  • DOI: https://doi.org/10.1007/s12274-015-0948-y

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