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Corrosion protection of carbon steel using hydrotalcite/graphene oxide nanohybrid

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Abstract

Zinc aluminum hydrotalcite/graphene oxide (HTC-GO) nanohybrid as inhibition additive for organic coatings was prepared using the co-precipitation method. The synthesized HTC-GO was characterized using Fourier-transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy (SEM), transmission electron microscopy, and thermogravimetric analysis. Surface charge properties of HTC-GO were evaluated with zeta potential measurement. The corrosion inhibition effect of HTC-GO on carbon steel in NaCl solution was investigated using electrochemical methods, energy-dispersive X-ray, and SEM. The effect of HTC-GO on corrosion resistance of epoxy coating applied on carbon steel was evaluated by salt spray test. It was shown that hydrotalcite structures were formed on GO surface, subsequently becoming hydrotalcite/graphene oxide nanohybrid. The results obtained by electrochemical measurements indicate that HTC-GO is an anodic corrosion inhibitor with an inhibition efficiency of about 92% at 1 g/L concentration. The presence of intercalated GO improved the barrier properties and adsorption of HTC-GO on steel surface. The corrosion resistance of epoxy coatings was improved with 1 wt% HTC-GO.

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References

  1. Wan, YJ, Tang, LC, Gong, LX, Yan, D, Li, YB, Wu, LB, Jiang, JX, Lai, GQ, “Grafting of Epoxy Chains onto Graphene Oxide for Epoxy Composites with Improved Mechanical and Thermal Properties.” Carbon, 69 467–480 (2014)

    Article  Google Scholar 

  2. Li, Z, Wang, R, Young, RJ, Deng, L, Yang, F, Hao, L, Jiao, W, Liu, W, “Control of the Functionality of Graphene Oxide for its Application in Epoxy Nanocomposites.” Polymer, 54 6437–6446 (2013)

    Article  Google Scholar 

  3. Lin, J, Zhang, P, Zheng, C, Wu, X, Mao, T, Zhu, M, Wang, H, Feng, D, Qian, S, Ca, X, “Reduced Silanized Graphene Oxide/Epoxy-Polyurethane Composites with Enhanced Thermal and Mechanical Properties.” Appl. Surf. Sci., 316 114–123 (2014)

    Article  Google Scholar 

  4. Zhang, W, Ma, J, Gao, D, Zhou, Y, Li, C, Zha, J, Zhang, J, “Preparation of Amino-Functionalized Graphene Oxide by Hoffman Rearrangement and Its Performances on Polyacrylate Coating Latex.” Prog. Org. Coat., 94 9–17 (2016)

    Article  Google Scholar 

  5. Ramezanzadeh, B, Ghasemi, E, Mahdavian, M, Changizi, E, Mohamadzadeh Moghadam, MH, “Covalently-Grafted Graphene Oxide Nanosheets to Improve Barrier and Corrosion Protection Properties of Polyurethane Coatings.” Carbon, 93 555–573 (2015)

    Article  Google Scholar 

  6. Ramezanzadeh, B, Niroumandrad, S, Ahmadi, A, Mahdavian, M, Mohamadzadeh Moghadam, MH, “Enhancement of Barrier and Corrosion Protection Performance of an Epoxy Coating Through Wet Transfer of Amino Functionalized Graphene Oxide.” Corros. Sci., 103 283–304 (2016)

    Article  Google Scholar 

  7. Ramezanzadeh, B, Bahlakeh, G, Mohamadzadeh Moghadam, MH, Miraftab, R, “Impact of Size-Controlled p-Phenylenediamine (PPDA)-Functionalized Graphene Oxide Nanosheets on the GO-PPDA/Epoxy Anti-corrosion, Interfacial Interactions and Mechanical Properties Enhancement: Experimental and Quantum Mechanics Investigations.” Chem. Eng. J., 335 737–755 (2018)

    Article  Google Scholar 

  8. Sari, MG, Shamshiri, M, Ramezanzadeh, B, “Fabricating an Epoxy Composite Coating with Enhanced Corrosion Resistance Through Impregnation of Functionalized Graphene Oxide-co-montmorillonite Nanoplatelet.” Corros. Sci., 129 38–53 (2017)

    Article  Google Scholar 

  9. Nikpoura, B, Ramezanzadeh, B, Bahlakeh, G, Mahdavian, M, “Synthesis of Graphene Oxide Nanosheets Functionalized by Green Corrosion Inhibitive Compounds to Fabricate a Protective System.” Corros. Sci., 127 240–259 (2017)

    Article  Google Scholar 

  10. Zhang, F, Liu, ZG, Zeng, RC, Li, SQ, Cui, HZ, Song, L, Han, EH, “Corrosion Resistance of Mg–Al-LDH Coating on Magnesium Alloy AZ31.” Surf. Coat. Technol., 258 1152–1158 (2014)

    Article  Google Scholar 

  11. Poznyak, SK, Tedim, J, Rodrigues, LM, Salak, AN, Zheludkevich, ML, Dick, LFP, Ferreira, MGS, “Novel Inorganic Host Layered Double Hydroxides Intercalated with Guest Organic Inhibitors for Anticorrosion Applications.” Appl. Mater. Interfaces, 1 (10) 2353–2362 (2009)

    Article  Google Scholar 

  12. Buchheit, RG, Guan, H, “Formation and Characteristics of Al − Zn Hydrotalcite Coatings on Galvanized Steel.” J. Coat. Technol. Res., 1 277–290 (2004)

    Article  Google Scholar 

  13. Williams, G, McMurray, HN, “Inhibition of Filiform Corrosion on Polymer Coated AA2024-T3 by Hydrotalcite-Like Pigments Incorporating Organic Anions.” Electrochem. Solid State Lett., 7 B13–B15 (2004)

    Article  Google Scholar 

  14. Mahajanam, PV, Buchheit, RG, “Characterization of Inhibitor Release from Zn-Al-[V10O28]6− Hydrotalcite Pigments and Corrosion Protection from Hydrotalcite-Pigmented Epoxy Coatings.” Corrosion, 64 230–240 (2008)

    Article  Google Scholar 

  15. Zheludkevich, ML, Poznyak, SK, Rodrigues, LM, Raps, D, Hack, T, Dick, LFP, Nunes, T, Ferreira, MGS, “Active Protection Coatings with Layered Double Hydroxide Nanocontainers of Corrosion Inhibitor.” Corros. Sci., 52 602–611 (2010)

    Article  Google Scholar 

  16. Li, D, Wang, F, Yu, X, Wang, J, Liua, Q, Yang, P, He, Y, Wang, Y, Zhang, M, “Anticorrosion Organic Coating with Layered Double Hydroxide Loaded with Corrosion Inhibitor of Tungstate.” Prog. Org. Coat., 71 302–309 (2011)

    Article  Google Scholar 

  17. Tedim, J, Kuznetsova, A, Salak, AN, Montemor, F, Snihirova, D, Pilz, M, Zheludkevich, ML, Ferreira, MGS, “Zn–Al Layered Double Hydroxides as Chloride Nanotraps in Active Protective Coatings.” Corros. Sci., 55 1–4 (2012)

    Article  Google Scholar 

  18. Alibakhshi, E, Ghasemi, E, Mahdavian, M, Ramezanzadeh, B, “A Comparative Study on Corrosion Inhibitive Effect of Nitrate and Phosphate Intercalated Zn–Al-Layered Double Hydroxides (LDHs) Nanocontainers Incorporated into a Hybrid Silane Layer and Their Effect on Cathodic Delamination of Epoxy Topcoat.” Corros. Sci., 115 159–174 (2017)

    Article  Google Scholar 

  19. Alibakhshi, E, Ghasemi, E, Mahdavian, M, Ramezanzadeh, B, Farashi, S, “Active Corrosion Protection of Mg–Al–PO4 3− LDH Nanoparticle in Silane Primer Coated with Epoxy on Mild Steel.” J. Taiwan Inst. Chem. Eng., 75 248–262 (2017)

    Article  Google Scholar 

  20. Edenharter, A, Feicht, P, Diar-Bakerly, B, Beyer, G, Breu, J, “Superior Flame Retardant by Combining High Aspect Ratio Layered Double Hydroxide and Graphene Oxide.” Polymer, 91 41–49 (2016)

    Article  Google Scholar 

  21. Yu, D, Wen, S, Yang, J, Wang, J, Chen, Y, Luo, J, Wu, Y, “RGO Modified ZnAl-LDH as Epoxy Nanostructure Filler: A Novel Synthetic Approach to Anticorrosive Waterborne Coating.” Surf. Coat. Technol., 326 207–215 (2017)

    Article  Google Scholar 

  22. Hang, TTX, Truc, TA, Duong, NT, Pebere, N, Olivier, MG, “Layered Double Hydroxides as Containers of Inhibitors in Organic Coatings for Corrosion Protection of Carbon Steel.” Prog. Org. Coat., 74 343–348 (2012)

    Article  Google Scholar 

  23. Hang, TTX, Truc, TA, Duong, NT, Vu, PG, Hoang, T, “Preparation and Characterization of Nanocontainers of Corrosion Inhibitor Based on Layered Double Hydroxides.” Appl. Clay Sci., 67–68 18–25 (2012)

    Article  Google Scholar 

  24. Hang, TTX, Truc, TA, Duong, NT, Truc, TA, Hoang, T, Thanh, DTM, Daopiset, S, Boonplean, A, “Effects of Hydrotalcite Intercalated with Corrosion Inhibitor on Cathodic Disbonding of Epoxy Coatings.” J. Coat. Technol. Res., 12 (2) 375–383 (2015)

    Article  Google Scholar 

  25. Hang, TTX, Anh, NT, Truc, TA, Truoc, BV, Hoang, T, Thanh, DTM, Daopiset, S, “Synthesis of 3-Glycidoxypropyltrimethoxysilane Modified Hydrotalcite Bearing Molybdate as Corrosion Inhibitor for Waterborne Epoxy Coating.” J. Coat. Technol. Res., 13 (5) 805–813 (2016)

    Article  Google Scholar 

  26. Esmaeili, A, Entezari, MH, “Facile and Fast Synthesis of Graphene Oxide Nanosheets Via Bath Ultrasonic Irradiation.” J. Colloid Interface Sci., 432 19–25 (2014)

    Article  Google Scholar 

  27. Stimpfling, T, Leroux, F, Hintze-Bruening, H, “Unraveling EDTA Corrosion Inhibition When Interleaved into Layered Double Hydroxide Epoxy Filler System Coated onto Aluminum AA 2024.” Appl. Clay Sci., 83–84 32–41 (2013)

    Article  Google Scholar 

  28. Xu, ZP, Braterman, PS, “Synthesis, Structure and Morphology of Organic Layered Double Hydroxide (LDH) Hybrids: Comparison Between Aliphatic Anions and Their Oxygenated Analogs.” Appl. Clay Sci., 48 235–242 (2010)

    Article  Google Scholar 

  29. Wang, Y, Wang, Z, Wu, X, Liu, X, Li, M, “Synergistic Effect Between Strongly Coupled CoAl Layered Double Hydroxides and Graphene for the Electrocatalytic Reduction of Oxygen.” Electrochim. Acta, 192 196–204 (2016)

    Article  Google Scholar 

  30. Lonkar, SP, Raquez, JM, Dubois, P, “One-pot Microwave-assisted Synthesis of Graphene/Layered Double Hydroxide (LDH) Nanohybrids.” Nano-Micro Lett., 7 (4) 332–340 (2015)

    Article  Google Scholar 

  31. Theiss, F, Ayoko, G, Frost, R, “Thermogravimetric Analysis of Selected Layered Double Hydroxides.” J. Therm. Anal. Calorim., 112 (2) 649–657 (2013)

    Article  Google Scholar 

  32. Nguyen, TD, To, TXH, Gervasi, J, Paint, Y, Maurice, G, Olivier, MG, “Corrosion Inhibition of Carbon Steel by Hydrotalcites Modified with Different Organic Carboxylic Acids for Organic Coatings.” Prog. Org. Coat., 124 256–266 (2018). https://doi.org/10.1016/j.porgcoat.2017.12.006

    Article  Google Scholar 

  33. Hsu, CH, Mansfeld, F, “Technical Note: Concerning the Conversion of the Constant Phase Element Parameter Y0 into a Capacitance.” Corrosion, 57 747–748 (2001)

    Article  Google Scholar 

  34. Outirite, M, Lagrenee, M, Lebrini, M, Traisnel, M, Jama, C, Vezin, H, Bentiss, F, “Ac Impedance, X-ray Photoelectron Spectroscopy and Density Functional Theory Studies of 3,5-bis(n-pyridyl)-1,2,4-oxadiazoles as Efficient Corrosion Inhibitors for Carbon Steel Surface in Hydrochloric acid Solution.” Electrochim. Acta, 55 1670–1681 (2010)

    Article  Google Scholar 

  35. Legrenee, M, Mernari, B, Bouanis, M, Traisnel, M, Bentiss, F, “Study of the Mechanism and Inhibiting Efficiency of 3,5-bis(4-methylthiophenyl)-4H-1,2,4-triazole on Mild Steel Corrosion in Acidic Media.” Corros. Sci., 44 573–582 (2002)

    Article  Google Scholar 

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Acknowledgments

This research is funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) under Grant Number 104.01-2016.06.

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Authors and Affiliations

  1. Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam

    Thuy Duong Nguyen, Ke Oanh Vu, Anh Son Nguyen, Anh Truc Trinh, Gia Vu Pham & Thi Xuan Hang To

  2. Institute of Chemical Technology, Vietnam Academy of Science and Technology, 1 Mac Dinh Chi, District 1, Ho Chi Minh City, Vietnam

    Boi An Tran, Minh Vuong Phan & Thanh Thao Phan

  3. Graduate University of Science and Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam

    Thi Xuan Hang To

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  1. Thuy Duong Nguyen
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Correspondence to Thi Xuan Hang To.

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Nguyen, T.D., Tran, B., Vu, K. et al. Corrosion protection of carbon steel using hydrotalcite/graphene oxide nanohybrid. J Coat Technol Res 16, 585–595 (2019). https://doi.org/10.1007/s11998-018-0139-3

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  • DOI: https://doi.org/10.1007/s11998-018-0139-3

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