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Crosslinked main-chain-type polybenzoxazine coatings for corrosion protection of mild steel

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Abstract

Bisphenol A/diaminodiphenylmethane (BA-ddm)-based polybenzoxazine precursor was synthesized from 4,4′-diaminodiphenylmethane, bisphenol A, and paraformaldehyde. The curing behavior of BA-ddm was studied by using differential scanning calorimeter and Fourier transform infrared spectrometer techniques. To verify the anticorrosion property, cured polybenzoxazine (PBA-ddm) coatings were prepared on mild steel (MS) through dip-coating and thermal curing methods. The surface properties of cured PBA-ddm coatings were characterized by microscopy and contact angle measurement. The electrochemical measurements were carried out to investigate the corrosion properties of PBA-ddm-coated MS. The results showed that PBA-ddm-coated MS samples exhibited high anticorrosive performance with the corrosion current reduced by two orders of magnitude than that of pristine MS.

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Acknowledgments

This work was financially supported by National Natural Science Foundation of China (21506062), Fundamental Research Funds for the Central Universities (22A201514015), China Postdoctoral Science Foundation (2015M571509), and Shanghai Key Laboratory of Multiphase Materials Chemical Engineering (MMCE2015004).

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Authors and Affiliations

  1. Shanghai Key Laboratory of Multiphase Materials Chemical Engineering, Department of Product Engineering, School of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237, People’s Republic of China

    Xin Lu, Yan Liu, Wenfei Zhang, Xueying Zhang, Changlu Zhou & Zhong Xin

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  1. Xin Lu
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  2. Yan Liu
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  3. Wenfei Zhang
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  4. Xueying Zhang
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  5. Changlu Zhou
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  6. Zhong Xin
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Correspondence to Zhong Xin.

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Lu, X., Liu, Y., Zhang, W. et al. Crosslinked main-chain-type polybenzoxazine coatings for corrosion protection of mild steel. J Coat Technol Res 14, 937–944 (2017). https://doi.org/10.1007/s11998-016-9902-5

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