Abstract
In the present study, attempts were made to enhance conductivity of electrocoats (based on epoxy amine adduct) containing NH2-multiwalled carbon nanotubes (MWCNTs). The weight percent of incorporated MWCNTS into the electrocoat matrix varied in the range of 0.6–3.6 wt% to obtain a series of electrocoatings. These were then applied on steel substrates by a cathodic electrodeposition technique. Electrocoated films were characterized utilizing scanning electron microscopy and optical microscopy. The results illustrated that electrical conductivity was enhanced by increasing of the MWCNT load. At the percolation threshold, throwing power was dropped while the recoating ability was enhanced. Mechanical behavior of nanocomposites containing MWCNTs in the range of 0–2.8 wt% was investigated by dynamic mechanical thermal analysis (DMTA) and nanoindentation test methods. DMTA analysis revealed that the width of tan δ was increased by the addition of nanotubes up to 2.8 (wt%). Also, the results obtained from the nanoindentation test showed that the elastic modulus and hardness of the nanocomposites were decreased by the addition of MWCNTs.
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References
Hu, Z, Jie, X, Lu, G, “Corrosion Resistance of Pb–Sn Composite Coatings Reinforced by Carbon Nanotubes.” J. Coat. Technol. Res., 7 809–814 (2010)
Geng, HZ, Kim, KK, So, KP, Lee, YS, Chang, Y, Lee, YH, “Effect of Acid Treatment on Carbon Nanotube-Based Flexible Transparent Conducting Films.” J. Am. Chem. Soc., 129 7758–7759 (2007)
Carroll, DL, Czerw, R, Webster, S, “Polymer–Nanotube Composites for Transparent, Conducting Thin Films.” Synth. Met., 155 694–697 (2005)
Funchini, G, Miller, S, Parekh, BB, Chhowalla, M, “Optical Anisotropy in Single-Walled Carbon Nanotube Thin Films: Implications for Transparent and Conducting Electrodes in Organic Photovoltaics.” Nano Lett., 8 2176–2179 (2008)
Johnson, JA, Barbato, MJ, Hopkins, SR, O’Malley, MUJ, “Dispersion and Film Properties of Carbon Nanofiber Pigmented Conductive Coatings.” Prog. Org. Coat., 47 198–206 (2003)
Sandler, JKW, Kirk, JE, Kinloch, IA, Shaffer, MSP, Windle, AH, “Ultra-Low Electrical Percolation Threshold in Carbon-Nanotube-Epoxy Composites.” Polymer, 44 5893–5899 (2003)
Nilsson, S, Wetterhall, M, Bergquist, J, Nyholm, L, Markides, KE, “A Simple and Robust Conductive Graphite Coating for Sheathless Electrospray Emitters Used in Capillary Electrophoresis/Mass Spectrometry.” Rapid Commun. Mass Spectrom., 15 1997–2000 (2001)
Afshar, A, Ghorbani, M, Mazaheri, M, “Electrodeposition of Graphite/Bronze Composite Coatings and Study of Electroplating Characteristics.” Surf. Coat. Technol., 187 293–300 (2004)
Peulon, S, Lincot, D, “Mechanistic Study of Cathodic Electrodeposition of Zinc Oxide and Zinc Hydroxychloride Films from Oxygenated Aqueous Zinc Chloride Solutions.” J. Electrochem. Soc., 145 864–874 (1998)
Hamid, ZA, “Review Article: Composite and Nanocomposite Coatings.” Metall. Eng., 3 29–42 (2014)
Gojny, FH, Wichmann, MHG, Fiedler, B, Schulte, K, “Influence of Different Carbon Nanotubes on the Mechanical Properties of Epoxy Matrix Composites—A Comparative Study.” Compos. Sci. Technol., 65 2300–2313 (2005)
Guo, P, Chen, X, Gao, X, Song, H, Shen, H, “Fabrication and Mechanical Properties of Well-Dispersed Multiwalled Carbon Nanotubes/Epoxy Composites.” Compos. Sci. Technol., 67 3331–3337 (2007)
Chen, H, Muthuraman, H, Stokes, P, Zou, J, Liu, X, Wang, J, Huo, Q, Khondaker, SI, Zhai, L, “Dispersion of Carbon Nanotubes and Polymer Nanocomposite Fabrication Using Trifluoroacetic Acid as a Co-solvent.” Nanotechnology, 18 415606 (2007)
Blanchet, GB, Fincher, CR, Gao, F, “Polyaniline Nanotube Composites: A High-Resolution Printable Conductor.” Appl. Phys. Lett., 82 1290–1292 (2003)
Qunaies, Z, Park, C, Wise, KE, Siochi, EJ, Harrison, JS, “Electrical Properties of Single Wall Carbon Nanotube Reinforced Polyimide Composites.” Compos. Sci. Technol., 63 (11) 1637–1646 (2003)
Jiang, X, Bin, Y, Matsuo, M, “Electrical and Mechanical Properties of Polyimide–Carbon Nanotubes Composites Fabricated by In Situ Polymerization.” Polymer, 46 7418–7424 (2005)
Zhu, B-K, Xie, S-H, Xu, Z-K, Xu, Y-Y, “Preparation and Properties of the Polyimide/Multi-walled Carbon Nanotubes (MWNTs) Nanocomposites.” Compos. Sci. Technol., 66 548–554 (2006)
Kim, YJ, An, KJ, Suh, K-S, Choi, H-D, Kwon, J-H, Chung, Y-C, Kim, WN, Lee, A-K, Choi, J-I, Yoon, HG, “Hybridization of Oxidized MWNT and Silver Powder in Polyurethane Matrix for Electromagnetic Interference Shielding Application.” IEEE Trans. Electromagn. Compat., 47 872–879 (2005)
Koerner, H, Liu, W, Alexander, M, Mirau, P, Dowty, H, Vaia, RA, “Deformation—Morphology Correlations in Electrically Conductive Carbon Nanotube—Thermoplastic Polyurethane Nanocomposites.” Polymer, 46 4405–4420 (2005)
Seo, M-K, Park, S-J, “Electrical Resistivity and Rheological Behaviors of Carbon Nanotubes-Filled Polypropylene Composites.” Chem. Phys. Lett., 395 44–48 (2004)
Gorrasi, G, Romeo, V, Sannino, D, Sarno, M, Ciambelli, P, Vittoria, V, Vivo, BD, Tucci, V, “Carbon Nanotube Induced Structural and Physical Property Transitions of Syndiotactic Polypropylene.” Nanotechnology, 18 275703 (2007)
Tjong, SC, Liang, GD, Bao, SP, “Electrical Behavior of Polypropylene/Multiwalled Carbon Nanotube Nanocomposites with Low Percolation Threshold.” Scr. Mater., 57 461–464 (2007)
Ma, P-C, Siddiqui, NA, Marom, G, Kim, J-K, “Dispersion and Functionalization of Carbon Nanotubes for Polymer-Based Nanocomposites: A Review.” Compos. Part A., 41 1345–1367 (2010)
Zhou, YX, Wu, PX, “Improvement in Electrical, Thermal and Mechanical Properties of Epoxy by Filling Carbon Nanotube.” Polym. Lett., 2 40–48 (2008)
Li, J, Ma, PC, Chow, WS, To, CK, Tang, BZ, Kim, J-K, “Correlations Between Percolation Threshold, Dispersion State, and Aspect Ratio of Carbon Nanotubes.” Adv. Funct. Mater., 17 3207–3215 (2007)
Austin, DW, Puretzky, AA, Geohegan, DB, Britt, PF, Guillorn, MA, Simpson, ML, “The Electrodeposition of Metal at Metal/Carbon Nanotube Junctions.” Chem. Phys. Lett., 361 525–529 (2002)
Eda, G, Solution-Processed Thin Films for Electronics Single-Walled Carbon Nanotubes and Graphene. New Brunswick, New Jersey (2009)
Frankland, SJV, Caglar, A, Brenner, DW, Griebel, M, “Molecular Simulation of the Influence of Chemical Cross-Links on the Shear Strength of Carbon Nanotube–Polymer Interfaces.” J. Phys. Chem. B, 106 3046–3048 (2002)
Krylova, I, “Painting by Electrodeposition on the Eve of the 21st Century.” Prog. Org. Coat., 42 119–131 (2001)
Kim, S-K, Oh, T-S, “Electrodeposition Behavior and Characteristics of Ni-Carbon Nanotube Composite Coatings.” Trans. Nonferr. Met. Soc., 21 68–72 (2011)
Zanganeh, N, Rajabi, A, Torabi, M, Allahkarami, M, Moghaddas, A, Sadrnezhaad, SK, “Growth and Microstructural Investigation of Multiwall Carbon Nanotubes Fabricated Using Electrodeposited Nickel Nanodeposits and Chemical Vapor Deposition Method.” J. Mol. Struct., 1074 250–254 (2014)
Furuno, N, Ohyabu, Y, “Methods for Measuring Throwing Power in Electro-deposition Coating.” Prog. Org. Coat., 5 201–217 (1977)
Muller, B, Poth, U, Coatings Formulation, p. 237. Vincentz, Hannover (2006)
Jafari, S, Rozati, SM, “Characterization of Black Chrome Films Prepared by Electroplating Technique.” Solar Therm. Appl., 3999–4005 (2011)
Blackley, DC, Polymer Latices. Springer Science & Business Media, Dordrecht (1997)
Stauffer, D, Aharony, A, Introduction to Percolation Theory. Francis and Taylor, London (1991)
Barrau, S, Demont, P, Peigney, A, Laurent, C, Lacabanne, C, “DC and AC Conductivity of Carbon Nanotubes–Polyepoxy Composites.” Macromolecules, 36 5187–5194 (2003)
Bauhofer, W, Kovacs, JZ, “A Review and Analysis of Electrical Percolation in Carbon Nanotube Polymer Composites.” Compos. Sci. Technol., 69 1486–1498 (2009)
Huang, YY, Terentjev, EM, “Tailoring the Electrical Properties of Carbon Nanotube-Polymer Composites.” Adv. Funct. Mater., 20 4062–4068 (2010)
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Zabet, M., Moradian, S., Ranjbar, Z. et al. Effect of carbon nanotubes on electrical and mechanical properties of multiwalled carbon nanotubes/epoxy coatings. J Coat Technol Res 13, 191–200 (2016). https://doi.org/10.1007/s11998-015-9723-y
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DOI: https://doi.org/10.1007/s11998-015-9723-y