Skip to main content
Log in

Influences of Cr content and heat treatment on the optical property of the green mica-nano Cr2O3 pearlescent pigment

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

In the present work, green nano Cr2O3-coated mica pigments were prepared by homogeneous precipitation. Structure, morphology, and optical properties were investigated by X-ray diffraction, thermogravimetric and differential thermal analysis, scanning electron microscopy, and colorimetric analysis. The results showed that an amorphous coating was synthesized and crystallized to Cr2O3 after heat treatment at 800°C. Average particle size of the coating was about 100 nm. The optical properties of the final pigment depended on the Cr content and heat-treatment temperature. The pearlescent index increased as chromium nitrate content increased and then decreased. Lower calcination temperature can cause lower L* value and pearlescent index.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Maisch, R, Stahlecker, O, Kieser, M, “Mica Pigments in Solvent Free Coatings Systems.” Prog. Org. Coat., 27 145–152 (1996)

    Article  Google Scholar 

  2. Levis, PA, Pigment Handbook. Wiley, New York (1998)

    Google Scholar 

  3. Junru, T, Yunfang, H, Wenxiang, H, Xiuzeng, C, Xiansong, F, “The Preparation and Characteristics of Cobalt Blue Mica Coated Titania Pearlescent Pigment.” Dyes Pigment., 52 215–222 (2002)

    Article  Google Scholar 

  4. Smith, HM, High Performance Pigments. Wiley, New York (2002)

    Google Scholar 

  5. Cavalcante, PMT, Dondi, M, Guarini, G, Barros, FM, Luz, AB, “Ceramic Application of Mica Titania Pearlescent Pigments.” Dyes Pigment., 74 1–8 (2007)

    Article  Google Scholar 

  6. Hildenbrand, VD, Doyle, S, Fuess, H, Pfaff, G, Reynders, P, “Crystallisation of Thin Anatase Coatings on Muscovite.” Thin Solid Films, 304 204–211 (1997)

    Article  Google Scholar 

  7. Bayat, N, Baghshahi, S, Alizadeh, P, “Synthesis of White Pearlescent Pigments Using the Surface Response Method of Statistical Analysis.” Ceram. Int., 34 (8) 2029–2035 (2008)

    Article  Google Scholar 

  8. Cho, JH, Lim, SH, “Internal Structure Analysis of Mica Particles Coated with Metal Oxide by Transmission Electron Microscopy.” Dyes Pigment., 69 192–195 (2006)

    Article  Google Scholar 

  9. Cho, JH, Tark, YD, Kim, WY, Lim, SH, “Room-Temperature Synthesis and Characteristics of Nanocrystalline TiO2 on Mica by Homogeneous Precipitation.” Met. Mater. Int., 15 1001–1005 (2009)

    Article  Google Scholar 

  10. Jing, C, Hanbing, SX, “The Preparation and Characteristics of Cobalt Blue Colored Mica Titania Pearlescent Pigment by Microemulsions.” Dyes Pigment., 75 766–769 (2007)

    Article  Google Scholar 

  11. Tohidifar, MR, Taheri-Nassaj, E, Alizadeh, P, “Precursor Content Assessment and Its Influence on the Optical Interference of a Nano-Sized Mica-Hematite Pearlescent Pigment.” Powder Technol., 204 194–197 (2010)

    Article  Google Scholar 

  12. Stengl, V, Subrt, J, Bakardjieva, S, Kalendova, A, Kalenda, P, “The Preparation and Characteristics of Pigments Based on Mica Coated with Metal Oxides.” Dyes Pigment., 58 239–244 (2003)

    Article  Google Scholar 

  13. Hassanzadeh-Tabrizi, SA, Taheri-Nassaj, E, Sarpoolaky, H, “Synthesis of an Alumina–YAG Nanopowder Via Sol–Gel Method.” J. Alloy Compd., 456 282–285 (2008)

    Article  Google Scholar 

  14. Chen, D, Gao, L, “Novel Synthesis of Well-Dispersed Crystalline SnO2 Nanoparticles by Water-in-Oil Microemulsion-Assisted Hydrothermal Process.” J. Colloid Interface Sci., 279 137–142 (2004)

    Article  Google Scholar 

  15. Suárez, M, Garcia-Romero, E, “FTIR Spectroscopic Study of Palygorskite: Influence of the Composition of the Octahedral Sheet.” Appl. Clay Sci., 31 154–163 (2006)

    Article  Google Scholar 

  16. Vicente-Rodríguez, MA, Suarez, M, Bañares-Muñoz, MA, Lopez-Gonzalez, JD, “Comparative FT-IR Study of the Removal of Octahedral Cátions and Structural Modifications During Acid Treatment of Several Silicates.” Spectrochim. Acta A, 52 1685–1694 (1996)

    Article  Google Scholar 

  17. Palimi, MJ, Rostami, M, Mahdavian, M, Ramezanzadeh, B, “Surface Modification of Cr2O3 Nanoparticles with 3-Amino Propyl Trimethoxy Silane (APTMS). Part 1: Studying the Mechanical Properties of Polyurethane/Cr2O3 Nanocomposites.” Prog. Org. Coat., 77 1663–1673 (2014)

    Article  Google Scholar 

  18. Soler-Illia, G, Jobbagy, M, Candal, RJ, Regazzoni, AE, Blesa, MA, “Synthesis of Metal Oxide Particles from Aqueous Media: The Homogeneous Alkalinization Method.” J. Disper. Sci. Technol., 19 207–228 (1998)

    Article  Google Scholar 

  19. Subrt, J, Bohacek, J, Stengl, V, Grygar, T, Bezdick, P, “Uniform Particles with a Large Surface Area Formed by Hydrolysis of Fe2(SO4)3 with Urea.” Mater. Res. Bull., 34 905–914 (1999)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. A. Hassanzadeh-Tabrizi.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hassanzadeh-Tabrizi, S.A. Influences of Cr content and heat treatment on the optical property of the green mica-nano Cr2O3 pearlescent pigment. J Coat Technol Res 12, 751–756 (2015). https://doi.org/10.1007/s11998-015-9664-5

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-015-9664-5

Keywords

Navigation