Abstract
The development of effective anticorrosion pretreatments for metallic substrates is an issue of great importance for durability of metal structures and components. In this work for improved corrosion protection properties of sol–gel derived hybrid coatings, encapsulated corrosion inhibitors [2-mercaptobenzothiazole (MBT) and 2-mercaptobenzimidazole (MBI)] in the presence of β-cyclodextrin (β-CD) have been incorporated into hybrid coatings. Inclusion complex formation of MBI or MBT with β-CD led to encapsulated corrosion inhibitors which became active in corrosive electrolytes, and could slowly diffuse out of the host material to ensure continuous delivery of the inhibitors to corrosion sites and long-term corrosion protection. Structural characterization of the hybrid coatings were performed using EIS, SEM coupled with EDX, and FTIR.
Similar content being viewed by others
References
Wu, Y, Meure, S, Solomon, D, “Self-healing Polymeric Materials: A Review of Recent Developments.” Prog. Polym. Sci., 33 (5) 479–522 (2008)
Wool, RP, “Self-healing Materials: A Review.” Soft Matter, 4 (3) 400–418 (2008)
Ghosh, S, Self-healing Materials: Fundamentals, Design Strategies, and Applications. Wiley-VCH, Weinheim, 2009
Syrett, J, Becer, C, Haddleton, D, “Self-healing and Self-mendable Polymers.” Polym. Chem., 1 (7) 978–987 (2010)
Pirhady Tavandashti, N, Sanjabi, S, “Corrosion Study of Hybrid Sol–Gel Coatings Containing Boehmite Nanoparticles Loaded with Cerium Nitrate Corrosion Inhibitor.” Prog. Org. Coat., 69 (4) 384–391 (2010)
Zandi-zand, R, Ershad-langroudi, A, Rahimi, A, “Silica Based Organic–Inorganic Hybrid Nanocomposite Coatings for Corrosion Protection.” Prog. Org. Coat., 53 (4) 286–291 (2005)
Khramov, AN, Voevodin, NN, Balbyshev, VN, Donley, MS, “Hybrid Organo-ceramic Corrosion Protection Coatings with Encapsulated Organic Corrosion Inhibitors.” Thin Solid Films, 447 –448 549–557 (2004)
Shchuki, DG, Helmuth, M, “Self-repairing Coatings Containing Active Nanoreservoirs.” Smart Mater., 3 (6) 926–943 (2007)
Khramova, AN, Voevodinb, NN, Balbysheva, VN, Mantzc, RA, “Sol–Gel-Derived Corrosion-Protective Coatings with Controllable Release of Incorporated Organic Corrosion Inhibitors.” Thin Solid Films, 483 (1–2) 191–196 (2005)
Mingxing, H, Zhang, H, Yang, J, “Synthesis of Organic Silane Microcapsules for Self-healing Corrosion Resistant Polymer Coatings.” Corros. Sci., 65 (16) 561–566 (2012)
Zheludkevich, ML, Shchukin, DG, Yasakau, KA, Mohwald, H, Ferreira, MGS, “Anticorrosion Coatings with Self-healing Effect Based on Nanocontainers Impregnated with Corrosion Inhibitor.” Chem. Mater., 19 (3) 402–411 (2007)
Semsarzadeh, MA, Amiri, S, “Preparation and Characterization of Inclusion Complexes of Poly(dimethylsiloxane)s with gamma-Cyclodextrin Without Sonic Energy.” Silicon, 4 (3) 151–156 (2012)
Semsarzadeh, MA, Amiri, S, “Preparation and Properties of Polyrotaxane from α-Cyclodextrin and Poly(ethylene glycol) with Poly(vinyl alcohol).” Bull. Mater. Sci., 36 (6) 989–996 (2013)
Amiri, S, Rahimi, A, “Preparation of Supramolecular Corrosion Inhibitor Nanocontainers for Self-protective Hybrid Nanocomposite Coatings.” J. Polym. Res., (2014). doi:10.1007/s10965-014-0566-5
Zandi-zand, R, Ershad-langroudi, A, Rahimi, A, “Synthesis and Characterization of Nanocomposite Hybrid Coatings Based on 3-Glycidoxypropyl-trimethoxysilane and Bisphenol A.” Iran. Polym. J., 14 (4) 371–377 (2005)
Zandi-zand, R, Ershad-langroudi, A, Rahimi, A, “Improvement of Corrosiom Resistance of Organic-Inorganic Hybride Coating Based on Epoxy-Silica via Aromatic Diol Curing Agent.” Iran. J. Polym. Sci. Technol., 17 (6) 359–367 (2005)
Rule, J, Sottos, N, White, S, “Effect of Microcapsule Size on the Performance of Self-healing Polymers.” Polymer, 48 (12) 3520–3529 (2007)
Rahimi, A, Gharazi, S, Ershad-Langroudi, A, Ghasemi, D, “Synthesis and Characterization of Hydrophilic Nanocomposite Coating on Glass Substrate.” J. Appl. Polym. Sci., 102 (6) 5322–5329 (2006)
Zheludkevich, ML, Shchukin, DG, Yasakau, KA, Mohwald, H, Ferreira, MGS, “Anticorrosion Coatings with Self-healing Effect Based on Nanocontainers Impregnated with Corrosion Inhibitor.” Chem. Mater., 19 (3) 402–411 (2007)
Kartsonakis, IA, Balaskas, AC, Koumoulos, EP, Charitidis, CA, Kordas, GC, “Incorporation of Ceramic Nanocontainers into Epoxy Coatings for the Corrosion Protection of Hot Dip Galvanized Steel.” Corros. Sci., 57 (26) 30–41 (2012)
Acknowledgments
Acknowledgments Financial support from IPPI nano-technology committee (Grant No. 24711149) is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rahimi, A., Amiri, S. Anticorrosion hybrid nanocomposite coatings with encapsulated organic corrosion inhibitors. J Coat Technol Res 12, 587–593 (2015). https://doi.org/10.1007/s11998-015-9657-4
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11998-015-9657-4