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Photocatalytic treatments on dental mirror surfaces using hydrolysis of titanium alkoxide

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Abstract

Anatase titanium dioxide (TiO2) photocatalytic thin films were directly formed on glass slide and commercial dental mirror substrate surfaces by a hydrolysis of titanium alkoxide, and the hydrophilicity, the degree of oxidizing power and the transparency of the anatase TiO2-coated substrate surfaces. The contact angles of water and the decomposition rates of methylene blue on the anatase TiO2 photocatalytic thin films improved with the increasing duration of a tetraethyl orthotitanate (TEOT) hydrolysis, but they hardly changed for the longer duration. The reflectance of anatase TiO2 photocatalytic thin films coated on glass slide substrate surfaces was higher as the duration of a TEOT hydrolysis increased. Similar tendencies concerning hydrophilicity and transparency were recognized in cases of commercial dental mirror substrate surfaces. A hydrolysis of titanium alkoxide obtained superhydrophilic and antibacterial treatments with excellent transparency on commercial dental mirror substrate surfaces.

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References

  1. Fujishima A, Honda K, Electrochemical Photolysis of Water at Semiconductor Electrode Nature, 238, 37–38 (1972)

    Article  CAS  Google Scholar 

  2. Wang R, Hashimoto K, Fujishima A, Chikuni M, Kojima E, Kitamura A, Shimohigashi M, Watanabe T, Light-Induced Amphiphilic Surfaces Nature, 388, 431–432(1997)

    Article  CAS  Google Scholar 

  3. Dumitriu D, Bally AR, Ballif C, Hones P, Schmid PE, Sanjines R, Levy F, Parvulescu VI, Photocatalytic Degradation of Phenol by TiO2 Thin Films Prepared by Sputtering Appl. Catal. B: Environ. 25, 83–92(2000)

    Article  CAS  Google Scholar 

  4. Takagi K, Makimoto T, Hiraiwa H, Negishi T Photocatalytic Antifogging Mirror J. Vac. Sci. Technol. A 19, 2931–2935(2001)

    Article  CAS  Google Scholar 

  5. Battiston GA, Gerbasi R, Porchia M Influences of Substrate on Structural Properties of TiO2 Thin Films Obtained via MOCVD Thin Solid Films, 239 186–191 (1994)

    Article  CAS  Google Scholar 

  6. Takahashi Y, Matsuoka Y Dip-Coating of TiO2 Films Using a Sol Derived from Ti(O-I-Pr)4-Diethanolamine-H2O-i-PrOH System J. Mater. Sci. 23, 2259–2266(1988)

    Article  CAS  Google Scholar 

  7. Yoko T, Yuasa A, Kamiya K, Sakka S Sol-Gel-Derived TiO2 Film Semiconductor Electrode for Photocleavage of Water J. Electrochem. Soc. 138, 2279–2285(1991)

    Article  CAS  Google Scholar 

  8. Tsuzuki A, Murakami H, Kani K, Kawakami S, Torii Y Preparation of Nb-Doped TiO2 Films by the Sol-Gel Method J. Mater. Sci. Lett. 9, 624–626 (1990)

    Article  CAS  Google Scholar 

  9. Selvaraj U, Prasadatao AV, Komarneni S, Roy R, Sol-Gel Fabrication of Epitaxial and Oriented TiO2 Thin Films J. Am. Ceram. Soc. 75, 1167–1170(1992)

    Article  CAS  Google Scholar 

  10. Takahashi M, Mita K, Toyuki H, Kume M, Pt-TiO2 Thin Films on Glass Substrates as Effective Photocatalysts J. Mater. Sci. 24, 243–246 (1989)

    Article  CAS  Google Scholar 

  11. Wang R, Hashimoto K, Fujishima A, Chikuni M, Kojima E, Kitamura A, Shimohigoshi M, Watanabe T Photogeneration of Highly Amphiphilic TiO2 Surfaces Adv. Mater. 10, 135–138 (1998)

    Article  Google Scholar 

  12. Anast M, Jamting A, Bell JM, Ben-Nissan B Surface Morphology Examination of Sol-Gel Deposited TiO2 Films Thin Solid Films, 253, 303–307 (1994)

    Article  CAS  Google Scholar 

  13. Okudera H, Yokogawa Y, Formation of TiO2 Thin Films by Hydrolysis of Ti-Tetraethoxide in Ethanol: Kinetics Surface Morphology, Constituent Phases and Their Formation Mechanism Thin Solid Films 401, 124–130 (2001)

    Article  CAS  Google Scholar 

  14. Okudera H, Yokogawa Y Fabrication of Titania-Coated Silica Fibers and Effect of Substrate Shape on Coating Growth Rate Thin Solid Films 423, 119–124 (2001)

    Article  Google Scholar 

  15. Funakoshi K, Nonami T Preparation of Superhydrophilic Thin Film on Glass Substrate Surfaces with Titanium Alkoxide Solution J. Am. Ceram. Soc. 89, 2782–2786 (2006)

    Article  CAS  Google Scholar 

  16. Matsumoto, A, Kojima, S, Shigesato, Y, Hashimoto, K, “Manufacturing Methods of Products Coated with Functional Thin Films and Products Coated with Functional Thin Films.” Japan Patent 2001-253007, 2001

  17. Matsumoto, A, Kojima, S, Shigesato, Y, Hashimoto, K, “Substrates Formed Layers Including Photocatalysts on Their Surfaces and Formation Methods of Layers Including Photocatalysts on Substrate Surfaces.” Japan Patent 2001-246265, 2001

  18. Niimi, Y, Nagai, H, Matsumoto, A, Kakuya, T, Kinoshita, S, Oonishi, M, “Polyester Films Coated with Photocatalysts.” Japan Patent 2001-47581, 2001

  19. Ireland JC, Klostermann P, Rice EW, Clark RM, Inactivation of Escherichia coli by Titanium-Dioxide Photocatalytic Oxidation Appl. Environ. Microbiol., 59, 1668–1670 (1993)

    CAS  Google Scholar 

  20. Madrid PA, Moorillon GVN, Borunda EO, Yoshida MM, Photoinduced Bactericidal Activity Against Pseudomonas aeruginosa by TiO2 Based Thin Films FEMS Microbiol. 211, 183–188 (2002)

    Google Scholar 

  21. Saito, T, Hasegawa, H, “Houseroom, Aseptic Rooms Using Their Houserooms and Sterilizing Methods.” Japan Patent 2001-245960, 2001

  22. Fujishima A, Hashimoto K, Watanabe T, TiO2 Photocatalysis: Fundamentals and Applications, BKC, Inc., Tokyo, 1999

    Google Scholar 

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Correspondence to Kunio Funakoshi.

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Funakoshi, K., Nonami, T. Photocatalytic treatments on dental mirror surfaces using hydrolysis of titanium alkoxide. J Coat Technol Res 4, 327–333 (2007). https://doi.org/10.1007/s11998-007-9030-3

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