Abstract
Though blending polymers to obtain high performance materials is an old practice, the new trend in such an approach is the emergence of interpenetrating polymer networks (IPNs) as binders for protective coatings with improved properties. In this study, one ambient curing IPN-type polymer alloy developed out of epoxy and acrylic polyurethane systems as a high performing binder was formulated into paints and evaluated in comparison with the currently used conventional epoxy polyamide and polyurethane systems. A three-coat system consisting of a zinc phosphate primer, a micaceous iron oxide (MIO) undercoat, and a topcoat was formulated out of the IPN along with a similar system of epoxy primer, epoxy undercoat, and a PU topcoat. A two-coat system of the same primer with an IPN clear topcoat and a similar system with epoxy has also been studied. All the systems were studied under accelerated laboratory tests and field tests at a corrosive location. The results are reported and conclusions are drawn in this article.
Similar content being viewed by others
References
Utraki, LA, Polymer Alloys and Blends, Thermodynamics and Rheology, Hanser Gardner Publications, Munchen (1987)
Sperling, LH, “Source-Based Nomenclature for Polymer Blends, IPNs and Related Materials.” Division of Polymer Chemistry Nomenclature Committee Document (1984)
Lipatov, YS, Nesterov, AY, Ignatova, TD, Gudima, NP, Gritseriko, DT, Influence of Solid Surface on Equilibria in Polymer Mixtures, Eur. Polym. J., 22 83–87 (1986)
Sperling, LH, Interpenetrating Polymer Networks and Related Materials, Plenum Press, USA (1981)
Klempner, D, Frisch, HL, Topologically Interpenetrating Elastomeric Networks, J. Polym. Sci., A-2(8) 921–935 (1970)
Sperling, LH et al., Synthesis and Mechanical Behavior of Interpenetrating Polymer Networks: Poly(ethyl acrylate) and Polystyrene J. Polym. Sci., A-2(7) 425–427 (1960)
Klempner, D, Frisch, HL, Thermal Analysis of Polyacrylate-poly (urethane-urea) Interpenetrating Polymer Networks J. Polym. Sci., B-8 525–527 (1970)
Sperling, LH et al., Viscoelastic Behavior of Interpenetrating Polymer Networks: Poly(ethyl acrylate)-poly(methyl methacrylate) J. Appl. Polym. Sci., 14 2815–2824 (1970)
Thompson, MS, Gum Plastics, Reinhold Publishing Corp., NY (1958)
Keskkula, H, Polymer Modification of Rubbers and Plastics, Wiley Interscience, NY (1987)
Bruins, PF, Polymer Blends and Composites, Wiley Interscience, NY (1970)
Shah, J, Ryntz, RA, Gunn, VE, Xiao, HX, Frisch, KC, Feldpausch, A, Kordomenos, PI, Poly(Epoxy-Urethane Acrylic) Interpenetrating Polymer Networks (IPNs) for Primer ApplicationsJ. Coat. Technol., 61(772) 61–69 (1989)
Shah, A, Ryntz, RA, Gunn, VE, Xiao, HX, Frisch, KC, Poly(Epoxy-Urethane-Acrylic) Interpenetrating Polymer Networks (IPNs) for Primer Applications, J. Coat. Technol., 62(785) 63–73 (1990)
Kordomenos, PI, Frisch, KC, Xiao, HX, Sabbah, N, Coating Compositions Based on Acrylic-Polyurethane Interpenetrating Polymer NetworksJ. Coat. Technol., 57(723) 23–28 (1985)
Tehranisa, M, Ryntz, RA, Xiao, HX, Kordomenos, PI, Frisch, KC, Urethane Acrylic Interpenetrating Polymer Networks (IPNs) for Coating ApplciationsJ. Coat. Technol., 59(746) 43–50 (1987)
Chromy, L, Kaminska, E, Non-Toxic Anticorrosive PigmentsProg. Org. Coat., 18 319–324 (1980)
Harrison, JB, J. Oil Colour Chem. Assoc., 62 18–22 (1979)
Clay, MF, Cox, JH, J. Oil Colour Chem. Assoc., 56 13–16 (1973)
Anandarajan, T, Mohan, PS, Krishnan, SM, Balakrishnan, K, “Studies on Interpenetrating Polymer Network Based Coatings for Corrosion Protection.” In: Khanna, AS, Totlani, MK, Singh, SK (eds.) Corrosion and Its Control, vol 1, pp. 375–389. Elsevier (1997)
Krishnan, SM, Mohan, PS, Anandarajan, T, Balakrishnan, K, CSIR (India) Patent 699/Del/2000
Krishnan, SM, Mohan, PS, Anandarajan, T, Balakrishnan, K, CSIR (India) Patent 698/Del/2000
Anandaraj, T, Mohan, PS, Krishnan, SM, Balakrishnan, K, Raghavan, M, “Studies on characterization of high performance coatings based on polymer alloys of interpenetrating polymer networks.” Paint India, 51(6) 35–52 (2001)
Munger, CG, Corrosion Prevention by Protective Coatings, NACE International, Houston, TX, pp. 317–320 (1999)
Burrel, H, The Glass Transition in Coating FormulationsOfficial Digest, 34(445) 131 (1962)
Corcoran, EM (Ed.), Paint and Coating Testing Manual: Thirteenth Edition of the Gardner-Sward Handbook (ASTM Manual Series), ASTM, Philadelphia, PA (1972)
Acknowledgment
The authors wish to thank the Director, CECRI, Karaikudi, India, for the encouragement and support provided for carrying out this work and its publication.
Author information
Authors and Affiliations
Corresponding author
Additional information
An erratum to this article can be found at http://dx.doi.org/10.1007/s11998-007-9079-z
Rights and permissions
About this article
Cite this article
Krishnan, S., Mohan, P.S. Studies on corrosion resistant properties of inhibitive primed IPN coating systems in comparison with epoxy-PU systems. J Coat Technol Res 4, 89–100 (2007). https://doi.org/10.1007/s11998-007-9004-5
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11998-007-9004-5