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Studies on corrosion resistant properties of inhibitive primed IPN coating systems in comparison with epoxy-PU systems

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An Erratum to this article was published on 17 January 2008

Abstract

Though blending polymers to obtain high performance materials is an old practice, the new trend in such an approach is the emergence of interpenetrating polymer networks (IPNs) as binders for protective coatings with improved properties. In this study, one ambient curing IPN-type polymer alloy developed out of epoxy and acrylic polyurethane systems as a high performing binder was formulated into paints and evaluated in comparison with the currently used conventional epoxy polyamide and polyurethane systems. A three-coat system consisting of a zinc phosphate primer, a micaceous iron oxide (MIO) undercoat, and a topcoat was formulated out of the IPN along with a similar system of epoxy primer, epoxy undercoat, and a PU topcoat. A two-coat system of the same primer with an IPN clear topcoat and a similar system with epoxy has also been studied. All the systems were studied under accelerated laboratory tests and field tests at a corrosive location. The results are reported and conclusions are drawn in this article.

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References

  1. Utraki, LA, Polymer Alloys and Blends, Thermodynamics and Rheology, Hanser Gardner Publications, Munchen (1987)

    Google Scholar 

  2. Sperling, LH, “Source-Based Nomenclature for Polymer Blends, IPNs and Related Materials.” Division of Polymer Chemistry Nomenclature Committee Document (1984)

  3. Lipatov, YS, Nesterov, AY, Ignatova, TD, Gudima, NP, Gritseriko, DT, Influence of Solid Surface on Equilibria in Polymer Mixtures, Eur. Polym. J., 22 83–87 (1986)

    Article  CAS  Google Scholar 

  4. Sperling, LH, Interpenetrating Polymer Networks and Related Materials, Plenum Press, USA (1981)

    Google Scholar 

  5. Klempner, D, Frisch, HL, Topologically Interpenetrating Elastomeric Networks, J. Polym. Sci., A-2(8) 921–935 (1970)

    Google Scholar 

  6. Sperling, LH et al., Synthesis and Mechanical Behavior of Interpenetrating Polymer Networks: Poly(ethyl acrylate) and Polystyrene J. Polym. Sci., A-2(7) 425–427 (1960)

    Google Scholar 

  7. Klempner, D, Frisch, HL, Thermal Analysis of Polyacrylate-poly (urethane-urea) Interpenetrating Polymer Networks J. Polym. Sci., B-8 525–527 (1970)

    Google Scholar 

  8. Sperling, LH et al., Viscoelastic Behavior of Interpenetrating Polymer Networks: Poly(ethyl acrylate)-poly(methyl methacrylate) J. Appl. Polym. Sci., 14 2815–2824 (1970)

    Article  CAS  Google Scholar 

  9. Thompson, MS, Gum Plastics, Reinhold Publishing Corp., NY (1958)

    Google Scholar 

  10. Keskkula, H, Polymer Modification of Rubbers and Plastics, Wiley Interscience, NY (1987)

    Google Scholar 

  11. Bruins, PF, Polymer Blends and Composites, Wiley Interscience, NY (1970)

    Google Scholar 

  12. Shah, J, Ryntz, RA, Gunn, VE, Xiao, HX, Frisch, KC, Feldpausch, A, Kordomenos, PI, Poly(Epoxy-Urethane Acrylic) Interpenetrating Polymer Networks (IPNs) for Primer ApplicationsJ. Coat. Technol., 61(772) 61–69 (1989)

    CAS  Google Scholar 

  13. Shah, A, Ryntz, RA, Gunn, VE, Xiao, HX, Frisch, KC, Poly(Epoxy-Urethane-Acrylic) Interpenetrating Polymer Networks (IPNs) for Primer Applications, J. Coat. Technol., 62(785) 63–73 (1990)

    CAS  Google Scholar 

  14. Kordomenos, PI, Frisch, KC, Xiao, HX, Sabbah, N, Coating Compositions Based on Acrylic-Polyurethane Interpenetrating Polymer NetworksJ. Coat. Technol., 57(723) 23–28 (1985)

    CAS  Google Scholar 

  15. Tehranisa, M, Ryntz, RA, Xiao, HX, Kordomenos, PI, Frisch, KC, Urethane Acrylic Interpenetrating Polymer Networks (IPNs) for Coating ApplciationsJ. Coat. Technol., 59(746) 43–50 (1987)

    CAS  Google Scholar 

  16. Chromy, L, Kaminska, E, Non-Toxic Anticorrosive PigmentsProg. Org. Coat., 18 319–324 (1980)

    Article  Google Scholar 

  17. Harrison, JB, J. Oil Colour Chem. Assoc., 62 18–22 (1979)

    CAS  Google Scholar 

  18. Clay, MF, Cox, JH, J. Oil Colour Chem. Assoc., 56 13–16 (1973)

    CAS  Google Scholar 

  19. Anandarajan, T, Mohan, PS, Krishnan, SM, Balakrishnan, K, “Studies on Interpenetrating Polymer Network Based Coatings for Corrosion Protection.” In: Khanna, AS, Totlani, MK, Singh, SK (eds.) Corrosion and Its Control, vol 1, pp. 375–389. Elsevier (1997)

  20. Krishnan, SM, Mohan, PS, Anandarajan, T, Balakrishnan, K, CSIR (India) Patent 699/Del/2000

  21. Krishnan, SM, Mohan, PS, Anandarajan, T, Balakrishnan, K, CSIR (India) Patent 698/Del/2000

  22. Anandaraj, T, Mohan, PS, Krishnan, SM, Balakrishnan, K, Raghavan, M, “Studies on characterization of high performance coatings based on polymer alloys of interpenetrating polymer networks.” Paint India, 51(6) 35–52 (2001)

    CAS  Google Scholar 

  23. Munger, CG, Corrosion Prevention by Protective Coatings, NACE International, Houston, TX, pp. 317–320 (1999)

    Google Scholar 

  24. Burrel, H, The Glass Transition in Coating FormulationsOfficial Digest, 34(445) 131 (1962)

    Google Scholar 

  25. Corcoran, EM (Ed.), Paint and Coating Testing Manual: Thirteenth Edition of the Gardner-Sward Handbook (ASTM Manual Series), ASTM, Philadelphia, PA (1972)

Download references

Acknowledgment

The authors wish to thank the Director, CECRI, Karaikudi, India, for the encouragement and support provided for carrying out this work and its publication.

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Correspondence to SM. Krishnan.

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An erratum to this article can be found at http://dx.doi.org/10.1007/s11998-007-9079-z

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Krishnan, S., Mohan, P.S. Studies on corrosion resistant properties of inhibitive primed IPN coating systems in comparison with epoxy-PU systems. J Coat Technol Res 4, 89–100 (2007). https://doi.org/10.1007/s11998-007-9004-5

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