Conclusions
Mechanical interlocking of topcoat with the nonpolar TPO surface can be achieved through the use of an adhesion promoter, namely a chlorinated poly(olefin). The type of CPO used, in addition to the types of solvents and heat effects used, can substantially influence the degree of adhesion/cohesion obtained within the CPO.TPO system. Heat histories, TPO molding variations, CPO types, including solvent and resin variations, and topcoat (basecoat/clearcoat) chemistries were all found to influence the adhesion/cohesion of the painted TPO assembly.
Surface damage resistance was found to mirror the effects of adhesion as described earlier. Control of the interphase formed between the TPO substrate and the subsequent topcoat layers becomes increasingly important if one wishes to maintain damage resistance within the painted composite. Testing methodology development, namely “gouge” chip, abrasion, and scratch resistance, is paramount in predicting performance under specified loads. Through interpretation of data received in the various testing methodologies, the mechanical properties of the topcoat/substrate combination may be varied to obtain the performance required in a variety of applications.
References
Williams, K.A., Proc. of the 6th Annual Coatings for Plastics Symposium, Troy, MI, 2003.
Clemens, R.J., Batts, G.N., Lawniczak, J.E., Middleton, K.P., and Saas, C., Proc. XIXth Conf. Org. Coat. Sci. Tech., p. 105, Athens. Greece, 1993.
Grundke K. and Jacobasch, H.J., Farbe und Lacke, 98, 934 (1992).
Aoki, Y., J. Polym. Sci.: Part C, 23, 855 (1968).
Prater, T.J., Kaberline, S.L., Holubka, J.W., and Ryntz, R.A., “Examination of the Distribution of TPO Adhesion Promoter Material in a Painted TPO System’, Journal of Coatings Technology, 68, No. 857, 83 (1996).
Waddington, S. and Briggs, D., Polym. Commun., 32 (16), 506 (1991).
Ryntz, R.A., Xie, Q., and Ramamurthy, A.C., “Effects of Coating Solvents on the Morphology of Thermoplastic Polyolefins (TPO),” Journal of Coatings Technology, 67, No. 843, 45 (1995).
Ryntz, R.A., Prog. Org. Coat., 27, 241 (1996).
Li, L., Sosnowski, S., Chaffey, C., Balke, S., and Winnik, W., Langmuir, 10 (8), 2495 (1994).
Komatsu, Y., Kamimura, J., Aoki, O., Chung, D., and Wiseman, M., “SAE Technical Paper #940187” (1994).
Fujimoto, F., Paint and Resin, 36, February (1986).
Ryntz, R.A., Advanced Coating Technology Conference Proc., Engineering Society of Detroit, Detroit, MI, 1997.
Ryntz, R.A. and Buzdon, B., Prog. Org. Coat., 32, 167 (1997).
Fujiyama, M. and Kimura, S., Kobunshi Kobunshu (English Edition), 4, (10), 777 (1975).
Kantz, M.R., Newman, H.D., and Stigale, F.H., J. Appl. Polym. Sci., 16, 1249 (1972).
Fitchmun, D.R. and Newman, S.J., J. Polym. Sci.: Part A 2, 8, 1545 (1970).
Ryntz, R.A., Everson, M., and Pollano, G., Prog. Org. Coat., 31, 281 (1997).
Buzdon, B. and Ryntz, R.A., “Friction Induced Paint Damage: The Role of Coating Attributes”, SAE Paper, presented at SAE Conference Detroit, MI (1996).
Shinto, K., Beseche, S., and Sato, S., Proc. PRA Fourth Asia-Pacific Conference, Paint Research Association International Center for Coatings Technology, paper 4, Hong Kong, 1994.
Chen, M.J., Osterholtz, F.D., Phol, E.R., and Ramdatt, P.E., Proc. 23rd Annual Intl. Waterborne, High-Solids and Powder Coatings Symposium, 23, 222, New Orleans, LA, 1996.
Tonge, J.S., Blizzard, J.D., Schmidt, S.M., and Washer, T.R., Proc. 22nd Annual Intl. Waterborne, High-Solids and Powder Coatings Symposium, 22, 432, New Orleans, LA, 1995.
Lin, L. and Blackman, G., Proc. Adv. Coatings Technology Conference, International Body Engineering Conference, SAE/ESD, Detroit, MI, 1998.
Jardret, V., Lucas, B.N., Oliver, W., and Ramamurthy, A.C., “Scratch Durability of Automotive Clear Coatings: A quantitative, Reliable and Robust Methodology”, Journal of Coatings Technology, 72, No. 907, 79 (2000).
Shen, W., Ji, C., Jones, F.N., Everson, M.P., and Ryntz, R.A., Polym. Mater. Sci. Eng., 74, 346 (1996).
Courter, J.L. and Kamenetzky, E.A., “Micro- and Nano-Indentation and Scratching for Evaluating the Mar Resistance of Automotive Clearcoats”, presented at the 5th Nurnburg Congress on Creating Advances in Coating Technology, Nurnburg, Germany, April 1999.
Briscoe, B.J., Evans, P.D., Pelillo, E., and Sinha, S.K., “Scratching Maps for Polymers”, Wear, 47, 200 and 137 (1996).
Jardret, V., Lucas, B.N., Oliver, W., and Ramamurthy, A.C., “Scratch Durability of Automotive Clear Coatings: A Quantitative, Reliable and Robust Methodology,” Journal of Coatings Technology, 72, No. 907, 79 (2000).
Bucaille, J.L., Felder, E., and Hochstetter, G., “Identification of the Viscoplastic Behavior of a Polycarbonate Based on Experiments and Numerical Modeling of the Nanoindentation Test,” J. Mater. Sci., 37, 3999–4011 (2002).
Bucaille, J.L. Ph.D. Thesis, ENISE, France, 2002.
Jardret, V., Proc. of the Athens Coatings Conference, Athens, Greece, July 2002.
Ramamurthy, A.C., Ryntz, R.A., and Mihora, D., “Thermal and Impact Induced Stress Failure in Painted TPO: The Role of Surface Morphology,” Journal of Coatings Technology, 67, No. 840, 35 (1995).
Ryntz, R.A. and Buzdon, B., “SAE Paper #950801” (1995).
Ryntz, R.A., Ramamurthy, A.C., and Holubka, J.W., “Stone Impact of Damage to Painted Plastic Substrates,” Journal of Coatings Technology., 67, No. 723, 43 (1995).
Ryntz, R.A., Proc. of SPE TPO in Automotive, Dearborn, MI, 2003.
Additional information
The Roy W. Tess Award in Coatings is presented annually by the Division of Polymeric Materials: Science and Engineering (PMSE) in recognition of outstanding contributions to coatings science and technology. Funded by a grant to the Division by Dr. and Mrs. Roy W. Tess, the purpose of the award is to encourage interest and progress in coatings and recognize significant contributions to the field. Dr. Rose Ryntz, Manager and Staff Technical Fellow with Visteon Corporatiom, Dearborn, MI, received the award from Dr. Paul Valint, Jr., Chair of the PMSE Division in September 2003 during the 226th meeting of the American Chemical Society in New York, NY. Dr. Ryntz's award address followed the Award Symposium. The following papers were presented at that symposium.
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Ryntz, R.A. 2003 Roy W. Tess Award. J Coat. Technol. Res. 2, 350–360 (2005). https://doi.org/10.1007/s11998-005-0003-0
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DOI: https://doi.org/10.1007/s11998-005-0003-0