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Recent advances in Ni−Al bimetallic catalysis for unreactive bond transformation

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Abstract

Ni−Al bimetallic catalysis proves to be an efficient catalytic strategy for unreactive bond transformations. Recently, chiral bifunctional ligands, especially amphoteric secondary phosphine oxide (SPO) ligand, are used for a more powerful synergistic effect in the bimetal-catalyzed reactions, providing not only milder reaction conditions and higher reactivity but also excellent reaction selectivity. Herein, we give a brief review on the development of Ni−Al bimetallic catalytic system and highlight recent advances in enantioselective Ni−Al bimetallic catalysis for unreactive bond transformation.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (21672107) and the “1000-Youth Talents Plan”.

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  1. State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, China

    Yin-Xia Wang & Mengchun Ye

  2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300071, China

    Mengchun Ye

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Wang, YX., Ye, M. Recent advances in Ni−Al bimetallic catalysis for unreactive bond transformation. Sci. China Chem. 61, 1004–1013 (2018). https://doi.org/10.1007/s11426-018-9333-x

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