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Syntheses and Characterization of 2D and 3D Organotin Polymers with Phenylsuccinic Acid and Trimethyltin Chloride Under Different Conditions

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Abstract

Two types of di- and trimethyltin(IV) polymers [(Me2Sn)4O2(C10H8O4)4] n 1 and [(Me3Sn)2(C10H8O4)] n ·DMF 2 have been synthesized by the reaction of trimethyltin chloride with (±)-phenylsuccinic acid under two different experimental conditions. Both of the complexes are characterized by elemental analysis, IR, NMR (1H, 13C, 119Sn) spectroscopy and X-ray crystallographic diffraction analysis. The structural analyses show that complex 1 is a two-dimensional corrugated sheet polymer consisting of dimeric tetraorganodistannoxane units and bridging ligands. Complex 2 is a 3D corrugated polymer in which the deprotoned acid occurs as a tetradentate ligand and is bonded by the four oxygen atoms. It is worth noting that the X-ray diffraction study reveals that complex 2 crystallizes in the orthorhombic space group P212121, which is chiral space group.

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Acknowledgment

We thank the National Natural Science Foundation of China (20971096) for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Liaocheng University, 252059, Liaocheng, People’s Republic of China

    Rufen Zhang, Yun Ren & Chunlin Ma

  2. Taishan University, 271021, Taian, People’s Republic of China

    Qingfeng Wang & Chunlin Ma

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  1. Rufen Zhang
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  2. Yun Ren
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  3. Qingfeng Wang
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  4. Chunlin Ma
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Correspondence to Chunlin Ma.

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Zhang, R., Ren, Y., Wang, Q. et al. Syntheses and Characterization of 2D and 3D Organotin Polymers with Phenylsuccinic Acid and Trimethyltin Chloride Under Different Conditions. J Inorg Organomet Polym 20, 399–404 (2010). https://doi.org/10.1007/s10904-010-9330-4

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