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Vanadium-doping effects on magnetic and magnetocaloric efficiency of La0.7Sr0.2(CaLi)0.05Mn1−xVxO3 [x = 0.00 and x = 0.05] manganites

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Abstract

The La0.7Sr0.2Ca0.05Li0.05Mn1−xVxO3 [S1(x = 0) and S2(x = 0.05)] polycrystalline compounds are found to exhibit a ferromagnetic—paramagnetic transition (FM–PM) when temperature increases with a decrease of Curie temperature TC when substituting Mn with V from TC = 271 K to TC = 266 K. The Arrott plots near Curie temperature show positive slopes under an applied magnetic field varying from 0 to 5 T showing a second order magnetic transition for our samples. Basing on the magnetic-field dependences of magnetization measured around TC, maximum magnetic-entropy changes \(\left| {\Delta S_{M}^{{\hbox{max} }}} \right|,\) under the applied field of 5 T, are about 5.4 and 4.8 J kg−1 K−1 for S1 and S2 respectively. The efficiency of our samples for magnetic refrigeration application has been evaluated throw calculating the relative cooling power (RCP) values, which were equal to 211.5 J kg−1 for S1 and 195.5 J kg−1 for S2. The study of the universal curves show that the rescaled magnetic entropy change curves for different applied fields collapse onto a same curve confirming that both S1 and S2 reveal a second order transition.

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Acknowledgements

The authors acknowledge the Tunisian Ministry of Scientific Research and Technology and Group of Nanomagnetism CIC nanoGUNE – San Sebastain-Spain.

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Authors and Affiliations

  1. LT2S Lab, Digital Research Center of Sfax, Sfax Technopark, B.P. 275, 3021, Sakiet-Ezzit, Tunisia

    M. Mansouri, H. Omrani, W. Cheikhrouhou-Koubaa & A. Cheikhrouhou

  2. Center for Functionalized Magnetic Materials, Immanuel Kant Baltic Federal University, Kaliningrad, Russia, 236041

    M. Mansouri

  3. Unité de recherche Matériaux Avancés et Nanotechnologies (URMAN), Institut Supérieur des Sciences Appliquées et de Technologie de Kasserine, Kairouan University, BP 471, 1200, Kasserine, Tunisia

    R. M’nassri

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Mansouri, M., Omrani, H., M’nassri, R. et al. Vanadium-doping effects on magnetic and magnetocaloric efficiency of La0.7Sr0.2(CaLi)0.05Mn1−xVxO3 [x = 0.00 and x = 0.05] manganites. J Mater Sci: Mater Electron 29, 14239–14247 (2018). https://doi.org/10.1007/s10854-018-9557-3

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